Enabling multi-electron reaction of ε-VOPO4 to reach theoretical capacity for lithium-ion batteries

Carrie Siu; Ieuan D. Seymour; Sylvia Britto; Hanlei Zhang; Jatinkumar Rana; Jun Feng; Fredrick O. Omenya; Hui Zhou; Natasha A. Chernova; Guangwen Zhou; Clare P. Grey; Louis F.J. Piper; M. Stanley Whittingham

doi:10.1039/c8cc02386g

Enabling multi-electron reaction of ε-VOPO₄ to reach theoretical capacity for lithium-ion batteries

Carrie Siu, Ieuan D. Seymour, Sylvia Britto, Hanlei Zhang, Jatinkumar Rana, Jun Feng, Fredrick O. Omenya, Hui Zhou, Natasha A. Chernova, Guangwen Zhou, Clare P. Grey, Louis F.J. Piper, M. Stanley Whittingham^* (Corresponding Author)

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

By controlling the morphology and particle size of the epsilon polymorph of vanadyl phosphate, ε-VOPO₄, it can fully reversibly intercalate two Li-ions and reach the theoretical capacity of 305 mA h g^-1 over two voltage plateaus at about 4.0 and 2.5 V.

Original language	English
Pages (from-to)	7802-7805
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	56
DOIs	https://doi.org/10.1039/c8cc02386g
Publication status	Published - 18 Jun 2018

Bibliographical note

Funding Information:
This work was supported as part of NECCES, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0012583. Use of the Advanced Photon Source at Argonne National Laboratory was supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357.

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Cite this

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title = "Enabling multi-electron reaction of ε-VOPO4 to reach theoretical capacity for lithium-ion batteries",

abstract = "By controlling the morphology and particle size of the epsilon polymorph of vanadyl phosphate, ε-VOPO4, it can fully reversibly intercalate two Li-ions and reach the theoretical capacity of 305 mA h g-1 over two voltage plateaus at about 4.0 and 2.5 V.",

author = "Carrie Siu and Seymour, {Ieuan D.} and Sylvia Britto and Hanlei Zhang and Jatinkumar Rana and Jun Feng and Omenya, {Fredrick O.} and Hui Zhou and Chernova, {Natasha A.} and Guangwen Zhou and Grey, {Clare P.} and Piper, {Louis F.J.} and Whittingham, {M. Stanley}",

note = "Funding Information: This work was supported as part of NECCES, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0012583. Use of the Advanced Photon Source at Argonne National Laboratory was supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357.",

year = "2018",

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doi = "10.1039/c8cc02386g",

language = "English",

volume = "54",

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journal = "Chemical Communications",

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T1 - Enabling multi-electron reaction of ε-VOPO4 to reach theoretical capacity for lithium-ion batteries

AU - Siu, Carrie

AU - Seymour, Ieuan D.

AU - Britto, Sylvia

AU - Zhang, Hanlei

AU - Rana, Jatinkumar

AU - Feng, Jun

AU - Omenya, Fredrick O.

AU - Zhou, Hui

AU - Chernova, Natasha A.

AU - Zhou, Guangwen

AU - Grey, Clare P.

AU - Piper, Louis F.J.

AU - Whittingham, M. Stanley

N1 - Funding Information: This work was supported as part of NECCES, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0012583. Use of the Advanced Photon Source at Argonne National Laboratory was supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357.

PY - 2018/6/18

Y1 - 2018/6/18

N2 - By controlling the morphology and particle size of the epsilon polymorph of vanadyl phosphate, ε-VOPO4, it can fully reversibly intercalate two Li-ions and reach the theoretical capacity of 305 mA h g-1 over two voltage plateaus at about 4.0 and 2.5 V.

AB - By controlling the morphology and particle size of the epsilon polymorph of vanadyl phosphate, ε-VOPO4, it can fully reversibly intercalate two Li-ions and reach the theoretical capacity of 305 mA h g-1 over two voltage plateaus at about 4.0 and 2.5 V.

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DO - 10.1039/c8cc02386g

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