fac-(2-Amido­ethyl-κ2C1,O)aqua­tri­chlorido­tin(IV) 1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)

Solange M. S. V. Wardell; William T. A. Harrison; Edward R. T. Tiekink; Geraldo M. de Lima; James L. Wardell

doi:10.1107/S1600536810005908

fac-(2-Amidoethyl-κ2C1,O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1)

Solange M. S. V. Wardell, William T. A. Harrison, Edward R. T. Tiekink, Geraldo M. de Lima, James L. Wardell

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds.

Original language	English
Pages (from-to)	m312-m313
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	3
DOIs	https://doi.org/10.1107/S1600536810005908
Publication status	Published - Mar 2010

Keywords

ray crystal-structure
crown ethers
TIN(IV)
complexes
chemistry
adduct

Access to Document

10.1107/S1600536810005908

Cite this

@article{82a0abcb4b46419583e456d124f825dd,

title = "fac-(2-Amidoethyl-κ2C1,O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1)",

abstract = "The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds.",

keywords = "ray crystal-structure, crown ethers, TIN(IV), complexes, chemistry, adduct",

author = "Wardell, {Solange M. S. V.} and Harrison, {William T. A.} and Tiekink, {Edward R. T.} and {de Lima}, {Geraldo M.} and Wardell, {James L.}",

year = "2010",

month = mar,

doi = "10.1107/S1600536810005908",

language = "English",

volume = "66",

pages = "m312--m313",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "3",

}

TY - JOUR

T1 - fac-(2-Amidoethyl-κ2C1,O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1)

AU - Wardell, Solange M. S. V.

AU - Harrison, William T. A.

AU - Tiekink, Edward R. T.

AU - de Lima, Geraldo M.

AU - Wardell, James L.

PY - 2010/3

Y1 - 2010/3

N2 - The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds.

AB - The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds.

KW - ray crystal-structure

KW - crown ethers

KW - TIN(IV)

KW - complexes

KW - chemistry

KW - adduct

U2 - 10.1107/S1600536810005908

DO - 10.1107/S1600536810005908

M3 - Article

SN - 1600-5368

VL - 66

SP - m312-m313

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -