fac-(2-Amido­ethyl-κ2C1,O)aqua­tri­chlorido­tin(IV) 1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)

Solange M. S. V. Wardell, William T. A. Harrison, Edward R. T. Tiekink, Geraldo M. de Lima, James L. Wardell

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds.

Original languageEnglish
Pages (from-to)m312-m313
Number of pages2
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number3
DOIs
Publication statusPublished - Mar 2010

Keywords

  • ray crystal-structure
  • crown ethers
  • TIN(IV)
  • complexes
  • chemistry
  • adduct

Cite this

fac-(2-Amido­ethyl-κ2C1,O)aqua­tri­chlorido­tin(IV) 1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1). / Wardell, Solange M. S. V.; Harrison, William T. A.; Tiekink, Edward R. T.; de Lima, Geraldo M.; Wardell, James L.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 3, 03.2010, p. m312-m313.

Research output: Contribution to journalArticle

Wardell, Solange M. S. V. ; Harrison, William T. A. ; Tiekink, Edward R. T. ; de Lima, Geraldo M. ; Wardell, James L. / fac-(2-Amido­ethyl-κ2C1,O)aqua­tri­chlorido­tin(IV) 1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1). In: Acta Crystallographica Section E: Structure Reports Online. 2010 ; Vol. 66, No. 3. pp. m312-m313.
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abstract = "The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds.",
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T1 - fac-(2-Amido­ethyl-κ2C1,O)aqua­tri­chlorido­tin(IV) 1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)

AU - Wardell, Solange M. S. V.

AU - Harrison, William T. A.

AU - Tiekink, Edward R. T.

AU - de Lima, Geraldo M.

AU - Wardell, James L.

PY - 2010/3

Y1 - 2010/3

N2 - The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds.

AB - The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds.

KW - ray crystal-structure

KW - crown ethers

KW - TIN(IV)

KW - complexes

KW - chemistry

KW - adduct

U2 - 10.1107/S1600536810005908

DO - 10.1107/S1600536810005908

M3 - Article

VL - 66

SP - m312-m313

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 3

ER -