Factors regulating the spatial and temporal distribution of solute concentrations in a major river system in NE Scotland

R. P. Smart*, C. Soulsby, C. Neal, A. Wade, M. S. Cresser, M. F. Billett, S. J. Langan, A. C. Edwards, H. P. Jarvie, R. Owen

*Corresponding author for this work

Research output: Contribution to journalArticle

59 Citations (Scopus)

Abstract

The River Dee in NE Scotland, an oligotrophic soft water system, has a catchment area of approx. 2100 km2, its source in the Cairngorm mountains being approx. 140 km from its outlet to the North Sea at Aberdeen. A comprehensive sampling strategy and analytical programme, commensurate with the size and nature of the Dee system, have been established for major water quality determinands to identify the controls on, and origins of, dissolved species throughout the system at a range of catchment scales and over a range of flow regimes. Fifty-nine sites covering a range of catchment types and scales were therefore sampled bi-weekly for 1 year. At the basin scale, there is a general downstream increase in determinand concentrations. This produces strong linear relationships between many determinands which are unrelated in terms of a common terrestrial process or origin. At the sub-catchment scale, however, specific hydrochemical processes control streamwater chemistry. The Dee basin divides into two distinct geographic regions in terms of land use (upland and lowland) which produce clear differences in water chemistry. Individual sub-catchments can also be grouped in terms of temporal variations in streamwater chemistry. The strength of the relationship between weathering-derived ionic concentrations and flow in the upland sub-catchments has lead to the identification of specific concentration limits in sub-catchments which can be used as characteristics of soil water and groundwater end-members. This provides a basis for the prediction of upland weathering-derived component concentrations for each sub-catchment at a range of flows. Copyright (C) 1998 Published by Elsevier Science B.V. All rights reserved.

Original languageEnglish
Pages (from-to)93-110
Number of pages18
JournalScience of the Total Environment
Volume221
Issue number2-3
DOIs
Publication statusPublished - 8 Oct 1998

Fingerprint

temporal distribution
Catchments
river system
solute
Rivers
catchment
spatial distribution
streamwater
Weathering
weathering
Water
basin
water chemistry
Land use
temporal variation
Water quality
Process control
soil water
Groundwater
water quality

Keywords

  • Acidification
  • End-members
  • Scaling
  • Spatial and temporal variation
  • Weathering

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Chemistry
  • Waste Management and Disposal
  • Pollution

Cite this

Factors regulating the spatial and temporal distribution of solute concentrations in a major river system in NE Scotland. / Smart, R. P.; Soulsby, C.; Neal, C.; Wade, A.; Cresser, M. S.; Billett, M. F.; Langan, S. J.; Edwards, A. C.; Jarvie, H. P.; Owen, R.

In: Science of the Total Environment, Vol. 221, No. 2-3, 08.10.1998, p. 93-110.

Research output: Contribution to journalArticle

Smart, RP, Soulsby, C, Neal, C, Wade, A, Cresser, MS, Billett, MF, Langan, SJ, Edwards, AC, Jarvie, HP & Owen, R 1998, 'Factors regulating the spatial and temporal distribution of solute concentrations in a major river system in NE Scotland', Science of the Total Environment, vol. 221, no. 2-3, pp. 93-110. https://doi.org/10.1016/S0048-9697(98)00196-X
Smart, R. P. ; Soulsby, C. ; Neal, C. ; Wade, A. ; Cresser, M. S. ; Billett, M. F. ; Langan, S. J. ; Edwards, A. C. ; Jarvie, H. P. ; Owen, R. / Factors regulating the spatial and temporal distribution of solute concentrations in a major river system in NE Scotland. In: Science of the Total Environment. 1998 ; Vol. 221, No. 2-3. pp. 93-110.
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N2 - The River Dee in NE Scotland, an oligotrophic soft water system, has a catchment area of approx. 2100 km2, its source in the Cairngorm mountains being approx. 140 km from its outlet to the North Sea at Aberdeen. A comprehensive sampling strategy and analytical programme, commensurate with the size and nature of the Dee system, have been established for major water quality determinands to identify the controls on, and origins of, dissolved species throughout the system at a range of catchment scales and over a range of flow regimes. Fifty-nine sites covering a range of catchment types and scales were therefore sampled bi-weekly for 1 year. At the basin scale, there is a general downstream increase in determinand concentrations. This produces strong linear relationships between many determinands which are unrelated in terms of a common terrestrial process or origin. At the sub-catchment scale, however, specific hydrochemical processes control streamwater chemistry. The Dee basin divides into two distinct geographic regions in terms of land use (upland and lowland) which produce clear differences in water chemistry. Individual sub-catchments can also be grouped in terms of temporal variations in streamwater chemistry. The strength of the relationship between weathering-derived ionic concentrations and flow in the upland sub-catchments has lead to the identification of specific concentration limits in sub-catchments which can be used as characteristics of soil water and groundwater end-members. This provides a basis for the prediction of upland weathering-derived component concentrations for each sub-catchment at a range of flows. Copyright (C) 1998 Published by Elsevier Science B.V. All rights reserved.

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