Fast-and-Giant Photorheological Effect in a Liquid Crystal Dimer

Satoshi Aya, Péter Salamon, Daniel A. Paterson, John M. D. Storey, Corrie T. Imrie, Fumito Araoka (Corresponding Author), Antal Jákli (Corresponding Author), Ágnes Buka

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Mechanically responsive organic materials can change their viscoelastic properties in response to external stimuli. However, materials that exhibit highly contrasting viscoelastic properties coupled with fast and reversible switching between the states involved have remained elusive. Here, it is shown that a nonsymmetric photoresponsive liquid crystal dimer exhibits photoswitching of its viscoelastic properties (shear viscosity, storage, and loss moduli) with remarkable contrast of up to 106 while transitioning between crystal and nematic phases. This switching is reversible and takes less than 100 s for both forward (trans-cis photoisomerization) and backward (cis-trans photoisomerization) reactions due to the coexistence of two allotropes containing two types of stereoisomers. This combination of highly contrasting viscoelastic behavior with fast and reversible switching establishes a whole new performance level for mechanically responsive organic materials and offers very considerable application potential in such diverse areas as photoswitchable adhesives, in vibration control, and as novel brakes.
Original languageEnglish
Article number1802032
Number of pages7
JournalAdvanced Materials Interfaces
Volume6
Issue number9
Early online date8 Apr 2019
DOIs
Publication statusPublished - May 2019

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Dimers
Liquid crystals
Photoisomerization
Shear viscosity
Vibration control
Brakes
Adhesives
Crystals

Keywords

  • Azo
  • liquid crystals
  • photoresponse
  • rheology
  • soft matter

Cite this

Fast-and-Giant Photorheological Effect in a Liquid Crystal Dimer. / Aya, Satoshi; Salamon, Péter; Paterson, Daniel A.; Storey, John M. D.; Imrie, Corrie T.; Araoka, Fumito (Corresponding Author); Jákli, Antal (Corresponding Author); Buka, Ágnes.

In: Advanced Materials Interfaces, Vol. 6, No. 9, 1802032, 05.2019.

Research output: Contribution to journalArticle

Aya, Satoshi ; Salamon, Péter ; Paterson, Daniel A. ; Storey, John M. D. ; Imrie, Corrie T. ; Araoka, Fumito ; Jákli, Antal ; Buka, Ágnes. / Fast-and-Giant Photorheological Effect in a Liquid Crystal Dimer. In: Advanced Materials Interfaces. 2019 ; Vol. 6, No. 9.
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abstract = "Mechanically responsive organic materials can change their viscoelastic properties in response to external stimuli. However, materials that exhibit highly contrasting viscoelastic properties coupled with fast and reversible switching between the states involved have remained elusive. Here, it is shown that a nonsymmetric photoresponsive liquid crystal dimer exhibits photoswitching of its viscoelastic properties (shear viscosity, storage, and loss moduli) with remarkable contrast of up to 106 while transitioning between crystal and nematic phases. This switching is reversible and takes less than 100 s for both forward (trans-cis photoisomerization) and backward (cis-trans photoisomerization) reactions due to the coexistence of two allotropes containing two types of stereoisomers. This combination of highly contrasting viscoelastic behavior with fast and reversible switching establishes a whole new performance level for mechanically responsive organic materials and offers very considerable application potential in such diverse areas as photoswitchable adhesives, in vibration control, and as novel brakes.",
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