Formation of dioxygen adducts of cobalt(II) amine complexes in a cation exchange resin

S M  DAVIS; Russell Francis Howe; J H  LUNSFORD

doi:10.1016/0022-1902(77)80266-2

Formation of dioxygen adducts of cobalt(II) amine complexes in a cation exchange resin

S M DAVIS, Russell Francis Howe, J H LUNSFORD

Chemistry

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5 Citations (Scopus)

Abstract

The formation of monomeric dioxygen adducts of cobalt(II) complexes with ammonia, methylamine and ethylenediamine in an Amberlyst A-15 cation exchange resin is demonstrated by EPR. The EPR spectra are compared with those of the corresponding adducts formed in zeolite Y. The enhanced stability of the monomeric adducts in Amerlyst is attributed to the interaction of the complexes with sulfonate anion sites in the resin. The total amounts of oxygen adsorbed are greater than the spin concentrations of the monomeric adducts and this discrepancy is attributed to the formation of diamagnetic µ-peroxodicobalt adducts as well as a slow irreversible oxidation of the Co(II) to Co(III). A paramagnetic µ-superoxodicobalt adduct is observed only with methylamine and then only in very low concentrations.

Original language	English
Pages (from-to)	1069-1072
Number of pages	4
Journal	Journal of Inorganic Biochemistry
Volume	39
Issue number	6
DOIs	https://doi.org/10.1016/0022-1902(77)80266-2
Publication status	Published - 1977

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@article{0391ae43c20045bd930c937347c511fd,

title = "Formation of dioxygen adducts of cobalt(II) amine complexes in a cation exchange resin",

abstract = "The formation of monomeric dioxygen adducts of cobalt(II) complexes with ammonia, methylamine and ethylenediamine in an Amberlyst A-15 cation exchange resin is demonstrated by EPR. The EPR spectra are compared with those of the corresponding adducts formed in zeolite Y. The enhanced stability of the monomeric adducts in Amerlyst is attributed to the interaction of the complexes with sulfonate anion sites in the resin. The total amounts of oxygen adsorbed are greater than the spin concentrations of the monomeric adducts and this discrepancy is attributed to the formation of diamagnetic µ-peroxodicobalt adducts as well as a slow irreversible oxidation of the Co(II) to Co(III). A paramagnetic µ-superoxodicobalt adduct is observed only with methylamine and then only in very low concentrations.",

author = "DAVIS, {S M} and Howe, {Russell Francis} and LUNSFORD, {J H}",

year = "1977",

doi = "10.1016/0022-1902(77)80266-2",

language = "English",

volume = "39",

pages = "1069--1072",

journal = "Journal of Inorganic Biochemistry",

publisher = "Elsevier Inc.",

number = "6",

}

TY - JOUR

T1 - Formation of dioxygen adducts of cobalt(II) amine complexes in a cation exchange resin

AU - DAVIS, S M

AU - Howe, Russell Francis

AU - LUNSFORD, J H

PY - 1977

Y1 - 1977

N2 - The formation of monomeric dioxygen adducts of cobalt(II) complexes with ammonia, methylamine and ethylenediamine in an Amberlyst A-15 cation exchange resin is demonstrated by EPR. The EPR spectra are compared with those of the corresponding adducts formed in zeolite Y. The enhanced stability of the monomeric adducts in Amerlyst is attributed to the interaction of the complexes with sulfonate anion sites in the resin. The total amounts of oxygen adsorbed are greater than the spin concentrations of the monomeric adducts and this discrepancy is attributed to the formation of diamagnetic µ-peroxodicobalt adducts as well as a slow irreversible oxidation of the Co(II) to Co(III). A paramagnetic µ-superoxodicobalt adduct is observed only with methylamine and then only in very low concentrations.

AB - The formation of monomeric dioxygen adducts of cobalt(II) complexes with ammonia, methylamine and ethylenediamine in an Amberlyst A-15 cation exchange resin is demonstrated by EPR. The EPR spectra are compared with those of the corresponding adducts formed in zeolite Y. The enhanced stability of the monomeric adducts in Amerlyst is attributed to the interaction of the complexes with sulfonate anion sites in the resin. The total amounts of oxygen adsorbed are greater than the spin concentrations of the monomeric adducts and this discrepancy is attributed to the formation of diamagnetic µ-peroxodicobalt adducts as well as a slow irreversible oxidation of the Co(II) to Co(III). A paramagnetic µ-superoxodicobalt adduct is observed only with methylamine and then only in very low concentrations.

U2 - 10.1016/0022-1902(77)80266-2

DO - 10.1016/0022-1902(77)80266-2

M3 - Article

VL - 39

SP - 1069

EP - 1072

JO - Journal of Inorganic Biochemistry

JF - Journal of Inorganic Biochemistry

IS - 6

ER -

Formation of dioxygen adducts of cobalt(II) amine complexes in a cation exchange resin

Abstract

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