Further study of tris(cyclochexyl)stannane compounds, Cy3SnX. Syntheses of the compounds with X = Br, I, N3 and NCS and redetermination of the crystal structures of Cy3SnX (X = Br and I).

Robert Alan Howie, M. V. H. Moura, J. L. Wardell, S. M. S. V. Wardell

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3 Citations (Scopus)

Abstract

Methods of preparation and far IR data are presented for various Cy3SnX compounds. The synthesis of tris(cyclohexyl)tin hydroxide, Cy3SnOH, is also described. Redeterminations of the crystal structures of tris(cyclohexyl)tin bromide and iodide, Cy3SnBr and Cy3SnI, confirm their molecular nature and improve considerably upon the results reported earlier [S. Calogero, P. Ganis, V. Peruzzo, G. Tagliavini, G. Valle, J. Organomet. Chem. 220 (1981) 11] providing, in both cases, lower R-factors and, in particular, a revised estimate of the Sn-I bond length, now 2.7463(6) Angstrom. (C) 2004 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)2331-2336
Number of pages5
JournalPolyhedron
Volume23
DOIs
Publication statusPublished - 2004

Keywords

  • tris(cyclohexyl)tin
  • halostannanes
  • crystal structure
  • = CL
  • CHLORIDE
  • HALIDES
  • RAY

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