H3N(CH2)(3)NH3 center dot Zn(HPO3)(2) containing four-ring chains of ZnO4 tetrahedra and HPO3 pseudo pyramids

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Abstract

The solution-mediated synthesis and single-crystal structure of H3N(CH2)(3)NH3. Zn(HPO3)(2) are reported. This phase is built up from chains of vertex-linked ZnO4 and HPO3 building units crosslinked by 1,3-diammonium propane cations. The relationship of the title compound to known zinc phosphate phases is briefly discussed. Crystal data for H3N(CH2)(3)NH3. Zn(HPO3)(2): ZnP2O6N2C3H14, M-r=301.49, ortholhombic, Pbcm (No. 57), a=8.6924 (4) Angstrom, b=7.8926 (4) Angstrom, c=16.6224 (8) Angstrom, V=1140.4 (2) Angstrom (3), Z=4, rho (calc)=1.756 g/cm(3), mu =24.4 cm(-1), T=298 (2) K, R=0.025, R-w=0.037 (calculated w(i)). (C) 2001 Elsevier Science Ltd. AH rights reserved.

Original languageEnglish
Pages (from-to)187-189
Number of pages3
JournalInternational Journal of Inorganic Materials
Volume3
Publication statusPublished - 2001

Keywords

  • PHOSPHATES
  • PHOSPHITES
  • HYDROGEN
  • LAYERS

Cite this

@article{f774670fc45048e8b344ebfe62546a07,
title = "H3N(CH2)(3)NH3 center dot Zn(HPO3)(2) containing four-ring chains of ZnO4 tetrahedra and HPO3 pseudo pyramids",
abstract = "The solution-mediated synthesis and single-crystal structure of H3N(CH2)(3)NH3. Zn(HPO3)(2) are reported. This phase is built up from chains of vertex-linked ZnO4 and HPO3 building units crosslinked by 1,3-diammonium propane cations. The relationship of the title compound to known zinc phosphate phases is briefly discussed. Crystal data for H3N(CH2)(3)NH3. Zn(HPO3)(2): ZnP2O6N2C3H14, M-r=301.49, ortholhombic, Pbcm (No. 57), a=8.6924 (4) Angstrom, b=7.8926 (4) Angstrom, c=16.6224 (8) Angstrom, V=1140.4 (2) Angstrom (3), Z=4, rho (calc)=1.756 g/cm(3), mu =24.4 cm(-1), T=298 (2) K, R=0.025, R-w=0.037 (calculated w(i)). (C) 2001 Elsevier Science Ltd. AH rights reserved.",
keywords = "PHOSPHATES, PHOSPHITES, HYDROGEN, LAYERS",
author = "Harrison, {W T A}",
year = "2001",
language = "English",
volume = "3",
pages = "187--189",
journal = "International Journal of Inorganic Materials",
issn = "1466-6049",
publisher = "Elsevier BV",

}

TY - JOUR

T1 - H3N(CH2)(3)NH3 center dot Zn(HPO3)(2) containing four-ring chains of ZnO4 tetrahedra and HPO3 pseudo pyramids

AU - Harrison, W T A

PY - 2001

Y1 - 2001

N2 - The solution-mediated synthesis and single-crystal structure of H3N(CH2)(3)NH3. Zn(HPO3)(2) are reported. This phase is built up from chains of vertex-linked ZnO4 and HPO3 building units crosslinked by 1,3-diammonium propane cations. The relationship of the title compound to known zinc phosphate phases is briefly discussed. Crystal data for H3N(CH2)(3)NH3. Zn(HPO3)(2): ZnP2O6N2C3H14, M-r=301.49, ortholhombic, Pbcm (No. 57), a=8.6924 (4) Angstrom, b=7.8926 (4) Angstrom, c=16.6224 (8) Angstrom, V=1140.4 (2) Angstrom (3), Z=4, rho (calc)=1.756 g/cm(3), mu =24.4 cm(-1), T=298 (2) K, R=0.025, R-w=0.037 (calculated w(i)). (C) 2001 Elsevier Science Ltd. AH rights reserved.

AB - The solution-mediated synthesis and single-crystal structure of H3N(CH2)(3)NH3. Zn(HPO3)(2) are reported. This phase is built up from chains of vertex-linked ZnO4 and HPO3 building units crosslinked by 1,3-diammonium propane cations. The relationship of the title compound to known zinc phosphate phases is briefly discussed. Crystal data for H3N(CH2)(3)NH3. Zn(HPO3)(2): ZnP2O6N2C3H14, M-r=301.49, ortholhombic, Pbcm (No. 57), a=8.6924 (4) Angstrom, b=7.8926 (4) Angstrom, c=16.6224 (8) Angstrom, V=1140.4 (2) Angstrom (3), Z=4, rho (calc)=1.756 g/cm(3), mu =24.4 cm(-1), T=298 (2) K, R=0.025, R-w=0.037 (calculated w(i)). (C) 2001 Elsevier Science Ltd. AH rights reserved.

KW - PHOSPHATES

KW - PHOSPHITES

KW - HYDROGEN

KW - LAYERS

M3 - Article

VL - 3

SP - 187

EP - 189

JO - International Journal of Inorganic Materials

JF - International Journal of Inorganic Materials

SN - 1466-6049

ER -