Hexagonal ammonium zinc phosphate, (NH4)ZnPO4, at 10 K

W T A Harrison, A N Sobolev, M L F Phillips

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The title compound, (NH4)ZnPO4-HEX, is built up from a three-dimensional network of ZnO4 and PO4 tetrahedra [d(av) (Zn-O) = 1.9400 (7) Angstrom and d(av) (P-O) = 1.5396 (7) Angstrom], fused together via Zn-O-P links [theta (av) = 133.47 (4)degrees]. An undisordered linear Zn-O-P bond occurs (all three atoms lie on a threefold axis). Extra-framework NH4+ cations, which interact with the [ZnPO4](-) framework by hydrogen bonds, complete the crystal structure.

Original languageEnglish
Pages (from-to)508-509
Number of pages2
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume57
Publication statusPublished - 2001

Keywords

  • ZEOLITE ABW
  • ZINCOPHOSPHATE

Cite this

Hexagonal ammonium zinc phosphate, (NH4)ZnPO4, at 10 K. / Harrison, W T A ; Sobolev, A N ; Phillips, M L F .

In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 57, 2001, p. 508-509.

Research output: Contribution to journalArticle

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T1 - Hexagonal ammonium zinc phosphate, (NH4)ZnPO4, at 10 K

AU - Harrison, W T A

AU - Sobolev, A N

AU - Phillips, M L F

PY - 2001

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N2 - The title compound, (NH4)ZnPO4-HEX, is built up from a three-dimensional network of ZnO4 and PO4 tetrahedra [d(av) (Zn-O) = 1.9400 (7) Angstrom and d(av) (P-O) = 1.5396 (7) Angstrom], fused together via Zn-O-P links [theta (av) = 133.47 (4)degrees]. An undisordered linear Zn-O-P bond occurs (all three atoms lie on a threefold axis). Extra-framework NH4+ cations, which interact with the [ZnPO4](-) framework by hydrogen bonds, complete the crystal structure.

AB - The title compound, (NH4)ZnPO4-HEX, is built up from a three-dimensional network of ZnO4 and PO4 tetrahedra [d(av) (Zn-O) = 1.9400 (7) Angstrom and d(av) (P-O) = 1.5396 (7) Angstrom], fused together via Zn-O-P links [theta (av) = 133.47 (4)degrees]. An undisordered linear Zn-O-P bond occurs (all three atoms lie on a threefold axis). Extra-framework NH4+ cations, which interact with the [ZnPO4](-) framework by hydrogen bonds, complete the crystal structure.

KW - ZEOLITE ABW

KW - ZINCOPHOSPHATE

M3 - Article

VL - 57

SP - 508

EP - 509

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

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