Hexagonal ammonium zinc phosphate, (NH4)ZnPO4, at 10 K

W T A  Harrison; A N  Sobolev; M L F  Phillips

Hexagonal ammonium zinc phosphate, (NH4)ZnPO4, at 10 K

W T A Harrison, A N Sobolev, M L F Phillips

Chemistry

Research output: Contribution to journal › Article

12 Citations (Scopus)

Abstract

The title compound, (NH4)ZnPO4-HEX, is built up from a three-dimensional network of ZnO4 and PO4 tetrahedra [d(av) (Zn-O) = 1.9400 (7) Angstrom and d(av) (P-O) = 1.5396 (7) Angstrom], fused together via Zn-O-P links [theta (av) = 133.47 (4)degrees]. An undisordered linear Zn-O-P bond occurs (all three atoms lie on a threefold axis). Extra-framework NH4+ cations, which interact with the [ZnPO4](-) framework by hydrogen bonds, complete the crystal structure.

Original language	English
Pages (from-to)	508-509
Number of pages	2
Journal	Acta Crystallographica Section C, Crystal Structure Communications
Volume	57
Publication status	Published - 2001

Keywords

ZEOLITE ABW
ZINCOPHOSPHATE

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title = "Hexagonal ammonium zinc phosphate, (NH4)ZnPO4, at 10 K",

abstract = "The title compound, (NH4)ZnPO4-HEX, is built up from a three-dimensional network of ZnO4 and PO4 tetrahedra [d(av) (Zn-O) = 1.9400 (7) Angstrom and d(av) (P-O) = 1.5396 (7) Angstrom], fused together via Zn-O-P links [theta (av) = 133.47 (4)degrees]. An undisordered linear Zn-O-P bond occurs (all three atoms lie on a threefold axis). Extra-framework NH4+ cations, which interact with the [ZnPO4](-) framework by hydrogen bonds, complete the crystal structure.",

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author = "Harrison, {W T A} and Sobolev, {A N} and Phillips, {M L F}",

year = "2001",

language = "English",

volume = "57",

pages = "508--509",

journal = "Acta Crystallographica Section C, Crystal Structure Communications",

issn = "0108-2701",

publisher = "Wiley-Blackwell ",

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TY - JOUR

T1 - Hexagonal ammonium zinc phosphate, (NH4)ZnPO4, at 10 K

AU - Harrison, W T A

AU - Sobolev, A N

AU - Phillips, M L F

PY - 2001

Y1 - 2001

N2 - The title compound, (NH4)ZnPO4-HEX, is built up from a three-dimensional network of ZnO4 and PO4 tetrahedra [d(av) (Zn-O) = 1.9400 (7) Angstrom and d(av) (P-O) = 1.5396 (7) Angstrom], fused together via Zn-O-P links [theta (av) = 133.47 (4)degrees]. An undisordered linear Zn-O-P bond occurs (all three atoms lie on a threefold axis). Extra-framework NH4+ cations, which interact with the [ZnPO4](-) framework by hydrogen bonds, complete the crystal structure.

AB - The title compound, (NH4)ZnPO4-HEX, is built up from a three-dimensional network of ZnO4 and PO4 tetrahedra [d(av) (Zn-O) = 1.9400 (7) Angstrom and d(av) (P-O) = 1.5396 (7) Angstrom], fused together via Zn-O-P links [theta (av) = 133.47 (4)degrees]. An undisordered linear Zn-O-P bond occurs (all three atoms lie on a threefold axis). Extra-framework NH4+ cations, which interact with the [ZnPO4](-) framework by hydrogen bonds, complete the crystal structure.

KW - ZEOLITE ABW

KW - ZINCOPHOSPHATE

M3 - Article

SN - 0108-2701

VL - 57

SP - 508

EP - 509

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

ER -

Hexagonal ammonium zinc phosphate, (NH4)ZnPO4, at 10 K

Abstract

Keywords

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