(H3N(CH2)3NH3).Be3(HPO4)4, a three-dimensional framework beryllophosphate containing tetrahedral 10-rings and 12-rings

William Thomas Alexander Harrison

doi:10.1016/S1466-6049(00)00101-X

(H₃N(CH₂)₃NH₃).Be₃(HPO₄)₄, a three-dimensional framework beryllophosphate containing tetrahedral 10-rings and 12-rings

William Thomas Alexander Harrison

Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The solution-mediated synthesis and single crystal structure of [H3N(CH2)(3)NH3]. Be-3(HPO4)(4) are reported. This phase is built up from vertex-linked BeO4 and HPO4 building units encapsulating the extra-framework 1,3-diammonium propane cations. A new type of three-dimensional network containing 4-, 6-, 8-, 10-, and 12-rings results for the inorganic framework. The structure is stabilised by template-to-framework and framework-to-framework hydrogen bonding networks. Crystal data: [H3N(CH2)(3)NH3]. Be-3(HPO4)(4), M= 487.10, monoclinic, space group P2(1)/n (No. 14). a=7.4219 (3) Angstrom. b=31.5289 (14) Angstrom, c=13.6682 (6) Angstrom. beta =91.807 (I)degrees, V=3196.8 Angstrom (3) Z=8, T=298 (2) K, R(F)=0.053, wR(F)=0.049. (C) 2001 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	17-22
Number of pages	5
Journal	International Journal of Inorganic Materials
Volume	3
DOIs	https://doi.org/10.1016/S1466-6049(00)00101-X
Publication status	Published - 2001

Keywords

inorganic compounds
crystal structure
PHOSPHATES

Access to Document

10.1016/S1466-6049(00)00101-X

Cite this

@article{7816bdccf8a24bf994930db067b90fe9,

title = "(H3N(CH2)3NH3).Be3(HPO4)4, a three-dimensional framework beryllophosphate containing tetrahedral 10-rings and 12-rings",

abstract = "The solution-mediated synthesis and single crystal structure of [H3N(CH2)(3)NH3]. Be-3(HPO4)(4) are reported. This phase is built up from vertex-linked BeO4 and HPO4 building units encapsulating the extra-framework 1,3-diammonium propane cations. A new type of three-dimensional network containing 4-, 6-, 8-, 10-, and 12-rings results for the inorganic framework. The structure is stabilised by template-to-framework and framework-to-framework hydrogen bonding networks. Crystal data: [H3N(CH2)(3)NH3]. Be-3(HPO4)(4), M= 487.10, monoclinic, space group P2(1)/n (No. 14). a=7.4219 (3) Angstrom. b=31.5289 (14) Angstrom, c=13.6682 (6) Angstrom. beta =91.807 (I)degrees, V=3196.8 Angstrom (3) Z=8, T=298 (2) K, R(F)=0.053, wR(F)=0.049. (C) 2001 Elsevier Science Ltd. All rights reserved.",

keywords = "inorganic compounds, crystal structure, PHOSPHATES",

author = "Harrison, {William Thomas Alexander}",

year = "2001",

doi = "10.1016/S1466-6049(00)00101-X",

language = "English",

volume = "3",

pages = "17--22",

journal = "International Journal of Inorganic Materials",

issn = "1466-6049",

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TY - JOUR

T1 - (H3N(CH2)3NH3).Be3(HPO4)4, a three-dimensional framework beryllophosphate containing tetrahedral 10-rings and 12-rings

AU - Harrison, William Thomas Alexander

PY - 2001

Y1 - 2001

N2 - The solution-mediated synthesis and single crystal structure of [H3N(CH2)(3)NH3]. Be-3(HPO4)(4) are reported. This phase is built up from vertex-linked BeO4 and HPO4 building units encapsulating the extra-framework 1,3-diammonium propane cations. A new type of three-dimensional network containing 4-, 6-, 8-, 10-, and 12-rings results for the inorganic framework. The structure is stabilised by template-to-framework and framework-to-framework hydrogen bonding networks. Crystal data: [H3N(CH2)(3)NH3]. Be-3(HPO4)(4), M= 487.10, monoclinic, space group P2(1)/n (No. 14). a=7.4219 (3) Angstrom. b=31.5289 (14) Angstrom, c=13.6682 (6) Angstrom. beta =91.807 (I)degrees, V=3196.8 Angstrom (3) Z=8, T=298 (2) K, R(F)=0.053, wR(F)=0.049. (C) 2001 Elsevier Science Ltd. All rights reserved.

AB - The solution-mediated synthesis and single crystal structure of [H3N(CH2)(3)NH3]. Be-3(HPO4)(4) are reported. This phase is built up from vertex-linked BeO4 and HPO4 building units encapsulating the extra-framework 1,3-diammonium propane cations. A new type of three-dimensional network containing 4-, 6-, 8-, 10-, and 12-rings results for the inorganic framework. The structure is stabilised by template-to-framework and framework-to-framework hydrogen bonding networks. Crystal data: [H3N(CH2)(3)NH3]. Be-3(HPO4)(4), M= 487.10, monoclinic, space group P2(1)/n (No. 14). a=7.4219 (3) Angstrom. b=31.5289 (14) Angstrom, c=13.6682 (6) Angstrom. beta =91.807 (I)degrees, V=3196.8 Angstrom (3) Z=8, T=298 (2) K, R(F)=0.053, wR(F)=0.049. (C) 2001 Elsevier Science Ltd. All rights reserved.

KW - inorganic compounds

KW - crystal structure

KW - PHOSPHATES

U2 - 10.1016/S1466-6049(00)00101-X

DO - 10.1016/S1466-6049(00)00101-X

M3 - Article

VL - 3

SP - 17

EP - 22

JO - International Journal of Inorganic Materials

JF - International Journal of Inorganic Materials

SN - 1466-6049