Hydrogen-bonded sheets in (E)-2-nitrobenzaidehyde 4-nitrophenylhydrazone and a hydrogen-bonded framework structure in (E)-4-nitrobenzaldehyde 4-nitrophenylhydrazone

J L Wardell, J M S Skakle, J N Low, C Glidewell

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Molecules of (E)-2-nitrobenzaldehyde 4-nitrophenylhydrazone, C13H10N4O4, exhibit a strongly polarized molecular - electronic structure. The molecules are linked into sheets of some complexity, where pairs of hydrogen bonds act co-operatively to generate two independent substructures, each in the form of a chain of rings. In the isomeric compound ( E)- 4-nitrobenzaldehyde 4-nitrophenylhydrazone, the molecules exhibit orientational disorder; an extensive series of hydrogen bonds links the molecules into a continuous three-dimensional framework, whose formation is independent of the disorder.

Original languageEnglish
Number of pages5
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume61
DOIs
Publication statusPublished - 2005

Keywords

  • X-RAY
  • DIFFRACTION
  • HYDRAZONE

Cite this

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title = "Hydrogen-bonded sheets in (E)-2-nitrobenzaidehyde 4-nitrophenylhydrazone and a hydrogen-bonded framework structure in (E)-4-nitrobenzaldehyde 4-nitrophenylhydrazone",
abstract = "Molecules of (E)-2-nitrobenzaldehyde 4-nitrophenylhydrazone, C13H10N4O4, exhibit a strongly polarized molecular - electronic structure. The molecules are linked into sheets of some complexity, where pairs of hydrogen bonds act co-operatively to generate two independent substructures, each in the form of a chain of rings. In the isomeric compound ( E)- 4-nitrobenzaldehyde 4-nitrophenylhydrazone, the molecules exhibit orientational disorder; an extensive series of hydrogen bonds links the molecules into a continuous three-dimensional framework, whose formation is independent of the disorder.",
keywords = "X-RAY, DIFFRACTION, HYDRAZONE",
author = "Wardell, {J L} and Skakle, {J M S} and Low, {J N} and C Glidewell",
year = "2005",
doi = "10.1107/S0108270104028483",
language = "English",
volume = "61",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

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TY - JOUR

T1 - Hydrogen-bonded sheets in (E)-2-nitrobenzaidehyde 4-nitrophenylhydrazone and a hydrogen-bonded framework structure in (E)-4-nitrobenzaldehyde 4-nitrophenylhydrazone

AU - Wardell, J L

AU - Skakle, J M S

AU - Low, J N

AU - Glidewell, C

PY - 2005

Y1 - 2005

N2 - Molecules of (E)-2-nitrobenzaldehyde 4-nitrophenylhydrazone, C13H10N4O4, exhibit a strongly polarized molecular - electronic structure. The molecules are linked into sheets of some complexity, where pairs of hydrogen bonds act co-operatively to generate two independent substructures, each in the form of a chain of rings. In the isomeric compound ( E)- 4-nitrobenzaldehyde 4-nitrophenylhydrazone, the molecules exhibit orientational disorder; an extensive series of hydrogen bonds links the molecules into a continuous three-dimensional framework, whose formation is independent of the disorder.

AB - Molecules of (E)-2-nitrobenzaldehyde 4-nitrophenylhydrazone, C13H10N4O4, exhibit a strongly polarized molecular - electronic structure. The molecules are linked into sheets of some complexity, where pairs of hydrogen bonds act co-operatively to generate two independent substructures, each in the form of a chain of rings. In the isomeric compound ( E)- 4-nitrobenzaldehyde 4-nitrophenylhydrazone, the molecules exhibit orientational disorder; an extensive series of hydrogen bonds links the molecules into a continuous three-dimensional framework, whose formation is independent of the disorder.

KW - X-RAY

KW - DIFFRACTION

KW - HYDRAZONE

U2 - 10.1107/S0108270104028483

DO - 10.1107/S0108270104028483

M3 - Article

VL - 61

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -