Hydrogen-bonded sheets in (E)-2-nitrobenzaidehyde 4-nitrophenylhydrazone and a hydrogen-bonded framework structure in (E)-4-nitrobenzaldehyde 4-nitrophenylhydrazone

J L Wardell, J M S Skakle, J N Low, C Glidewell

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14 Citations (Scopus)

Abstract

Molecules of (E)-2-nitrobenzaldehyde 4-nitrophenylhydrazone, C13H10N4O4, exhibit a strongly polarized molecular - electronic structure. The molecules are linked into sheets of some complexity, where pairs of hydrogen bonds act co-operatively to generate two independent substructures, each in the form of a chain of rings. In the isomeric compound ( E)- 4-nitrobenzaldehyde 4-nitrophenylhydrazone, the molecules exhibit orientational disorder; an extensive series of hydrogen bonds links the molecules into a continuous three-dimensional framework, whose formation is independent of the disorder.

Original languageEnglish
Number of pages5
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume61
DOIs
Publication statusPublished - 2005

Keywords

  • X-RAY
  • DIFFRACTION
  • HYDRAZONE

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