Hydrogen bonding in 2-(hydroxymethyl)-1,3-propanediol and N,N'-bis[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]malonamide

C. Fernandes, J. L. Wardell, Janet Mabel Scott Skakle

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The molecule of 2-(hydroxymethyl)-1,3-propanediol, C4H10O3, lies across a mirror plane in space group P2(1)/m, with disorder of both terminal hydroxyl H atoms. The molecules are linked by three O-H...O hydrogen bonds which combine to form sheets; in each O-H...O bond, the H atom resonates between the two O atoms. In the crystal structure of N,N'-bis[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]malonamide, C11H22N2O8, the molecule lies about a twofold axis and has four strong hydrogen bonds which form a mixture of chains and dimers; these combine to give a three-dimensional supramolecular framework.

Original languageEnglish
Pages (from-to)o499-o502
Number of pages4
JournalActa Crystallographica Section C, Crystal Structure Communications
VolumeC58
DOIs
Publication statusPublished - 2002

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Hydrogen Bonding
Hydrogen
Hydrogen bonds
Atoms
Molecules
Hydroxyl Radical
Dimers
Mirrors
Crystal structure
malonamide
1,3-propanediol

Keywords

  • X-ray-diffraction
  • pentaerythritol
  • generate

Cite this

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title = "Hydrogen bonding in 2-(hydroxymethyl)-1,3-propanediol and N,N'-bis[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]malonamide",
abstract = "The molecule of 2-(hydroxymethyl)-1,3-propanediol, C4H10O3, lies across a mirror plane in space group P2(1)/m, with disorder of both terminal hydroxyl H atoms. The molecules are linked by three O-H...O hydrogen bonds which combine to form sheets; in each O-H...O bond, the H atom resonates between the two O atoms. In the crystal structure of N,N'-bis[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]malonamide, C11H22N2O8, the molecule lies about a twofold axis and has four strong hydrogen bonds which form a mixture of chains and dimers; these combine to give a three-dimensional supramolecular framework.",
keywords = "X-ray-diffraction, pentaerythritol, generate",
author = "C. Fernandes and Wardell, {J. L.} and Skakle, {Janet Mabel Scott}",
year = "2002",
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language = "English",
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journal = "Acta Crystallographica Section C, Crystal Structure Communications",
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publisher = "Wiley-Blackwell",

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TY - JOUR

T1 - Hydrogen bonding in 2-(hydroxymethyl)-1,3-propanediol and N,N'-bis[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]malonamide

AU - Fernandes, C.

AU - Wardell, J. L.

AU - Skakle, Janet Mabel Scott

PY - 2002

Y1 - 2002

N2 - The molecule of 2-(hydroxymethyl)-1,3-propanediol, C4H10O3, lies across a mirror plane in space group P2(1)/m, with disorder of both terminal hydroxyl H atoms. The molecules are linked by three O-H...O hydrogen bonds which combine to form sheets; in each O-H...O bond, the H atom resonates between the two O atoms. In the crystal structure of N,N'-bis[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]malonamide, C11H22N2O8, the molecule lies about a twofold axis and has four strong hydrogen bonds which form a mixture of chains and dimers; these combine to give a three-dimensional supramolecular framework.

AB - The molecule of 2-(hydroxymethyl)-1,3-propanediol, C4H10O3, lies across a mirror plane in space group P2(1)/m, with disorder of both terminal hydroxyl H atoms. The molecules are linked by three O-H...O hydrogen bonds which combine to form sheets; in each O-H...O bond, the H atom resonates between the two O atoms. In the crystal structure of N,N'-bis[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]malonamide, C11H22N2O8, the molecule lies about a twofold axis and has four strong hydrogen bonds which form a mixture of chains and dimers; these combine to give a three-dimensional supramolecular framework.

KW - X-ray-diffraction

KW - pentaerythritol

KW - generate

U2 - 10.1107/S0108270102011800

DO - 10.1107/S0108270102011800

M3 - Article

VL - C58

SP - o499-o502

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -