Hydrogen bonding in substituted nitroanilines

isolated nets in 1,3-diamino-4-nitrobenzene and continuously interwoven nets in 3,5-dinitroaniline

C Glidewell, D Cannon, A Quesada, J N Low, S A McWilliam, Jan Skakle, J L Wardell

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Abstract

Molecules of 1,3-diamino-4-nitrobenzene, C6H7N3O2, are linked by N-H . . .O hydrogen bonds [N . . .O 2.964 (2) and 3.021 (2) Angstrom; N-H . . .O 155 and 149 degrees] into (4,4) nets. In 3,5-dinitroaniline, C6H5N3O4, where Z' = 2, the molecules are linked by three N-H . . .O hydrogen bonds [N . . .O 3.344 (2)-3.433 (2) Angstrom and N-H . . .O 150-167 degrees] into deeply puckered nets, each of which is interwoven with its two immediate neighbours.

Original languageEnglish
Pages (from-to)455-458
Number of pages4
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume57
Issue number4
DOIs
Publication statusPublished - 15 Apr 2001

Cite this

Hydrogen bonding in substituted nitroanilines : isolated nets in 1,3-diamino-4-nitrobenzene and continuously interwoven nets in 3,5-dinitroaniline. / Glidewell, C ; Cannon, D ; Quesada, A ; Low, J N ; McWilliam, S A ; Skakle, Jan; Wardell, J L .

In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 57, No. 4, 15.04.2001, p. 455-458.

Research output: Contribution to journalArticle

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abstract = "Molecules of 1,3-diamino-4-nitrobenzene, C6H7N3O2, are linked by N-H . . .O hydrogen bonds [N . . .O 2.964 (2) and 3.021 (2) Angstrom; N-H . . .O 155 and 149 degrees] into (4,4) nets. In 3,5-dinitroaniline, C6H5N3O4, where Z' = 2, the molecules are linked by three N-H . . .O hydrogen bonds [N . . .O 3.344 (2)-3.433 (2) Angstrom and N-H . . .O 150-167 degrees] into deeply puckered nets, each of which is interwoven with its two immediate neighbours.",
author = "C Glidewell and D Cannon and A Quesada and Low, {J N} and McWilliam, {S A} and Jan Skakle and Wardell, {J L}",
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T1 - Hydrogen bonding in substituted nitroanilines

T2 - isolated nets in 1,3-diamino-4-nitrobenzene and continuously interwoven nets in 3,5-dinitroaniline

AU - Glidewell, C

AU - Cannon, D

AU - Quesada, A

AU - Low, J N

AU - McWilliam, S A

AU - Skakle, Jan

AU - Wardell, J L

PY - 2001/4/15

Y1 - 2001/4/15

N2 - Molecules of 1,3-diamino-4-nitrobenzene, C6H7N3O2, are linked by N-H . . .O hydrogen bonds [N . . .O 2.964 (2) and 3.021 (2) Angstrom; N-H . . .O 155 and 149 degrees] into (4,4) nets. In 3,5-dinitroaniline, C6H5N3O4, where Z' = 2, the molecules are linked by three N-H . . .O hydrogen bonds [N . . .O 3.344 (2)-3.433 (2) Angstrom and N-H . . .O 150-167 degrees] into deeply puckered nets, each of which is interwoven with its two immediate neighbours.

AB - Molecules of 1,3-diamino-4-nitrobenzene, C6H7N3O2, are linked by N-H . . .O hydrogen bonds [N . . .O 2.964 (2) and 3.021 (2) Angstrom; N-H . . .O 155 and 149 degrees] into (4,4) nets. In 3,5-dinitroaniline, C6H5N3O4, where Z' = 2, the molecules are linked by three N-H . . .O hydrogen bonds [N . . .O 3.344 (2)-3.433 (2) Angstrom and N-H . . .O 150-167 degrees] into deeply puckered nets, each of which is interwoven with its two immediate neighbours.

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