Hydrothermal synthesis of catena(triaqua-(μ-2-croconato-O,O′,O′,O‴)-calcium(II)) calcium croconate trihydrate

M. John Plater; Mark R. Mark; R. Alan Howie

doi:10.1023/A:1022425429153

Hydrothermal synthesis of catena(triaqua-(μ-2-croconato-O,O′,O′,O‴)-calcium(II)) calcium croconate trihydrate

M. John Plater^*, Mark R. Mark, R. Alan Howie

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The title compound exists as a ID coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P - 1 with a = 6.642(3)Å, b = 7.793(4)Å, c = 8.854(5) Å, α = 106.97(5), β = 92.43(4), γ = 106.98(4)°, V = 415.1(4) Å³, and Z = 2.

Original language	English
Pages (from-to)	653-656
Number of pages	4
Journal	Journal of Chemical Crystallography
Volume	28
Issue number	8
DOIs	https://doi.org/10.1023/A:1022425429153
Publication status	Published - 1 Aug 1998

Keywords

Coordination polymer
Croconate
Hydrothermal

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@article{477dddc53f04496080434149a31f63ac,

title = "Hydrothermal synthesis of catena(triaqua-(μ-2-croconato-O,O′,O′,O‴)-calcium(II)) calcium croconate trihydrate",

abstract = "The title compound exists as a ID coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P - 1 with a = 6.642(3){\AA}, b = 7.793(4){\AA}, c = 8.854(5) {\AA}, α = 106.97(5), β = 92.43(4), γ = 106.98(4)°, V = 415.1(4) {\AA}3, and Z = 2.",

keywords = "Coordination polymer, Croconate, Hydrothermal",

author = "Plater, {M. John} and Mark, {Mark R.} and Howie, {R. Alan}",

note = "We are grateful for the use of the EPSRC Chemical Database Service at Daresbury and to the Leverhulme Trust for funding.",

year = "1998",

month = aug,

day = "1",

doi = "10.1023/A:1022425429153",

language = "English",

volume = "28",

pages = "653--656",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer New York",

number = "8",

}

TY - JOUR

T1 - Hydrothermal synthesis of catena(triaqua-(μ-2-croconato-O,O′,O′,O‴)-calcium(II)) calcium croconate trihydrate

AU - Plater, M. John

AU - Mark, Mark R.

AU - Howie, R. Alan

N1 - We are grateful for the use of the EPSRC Chemical Database Service at Daresbury and to the Leverhulme Trust for funding.

PY - 1998/8/1

Y1 - 1998/8/1

N2 - The title compound exists as a ID coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P - 1 with a = 6.642(3)Å, b = 7.793(4)Å, c = 8.854(5) Å, α = 106.97(5), β = 92.43(4), γ = 106.98(4)°, V = 415.1(4) Å3, and Z = 2.

AB - The title compound exists as a ID coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P - 1 with a = 6.642(3)Å, b = 7.793(4)Å, c = 8.854(5) Å, α = 106.97(5), β = 92.43(4), γ = 106.98(4)°, V = 415.1(4) Å3, and Z = 2.

KW - Coordination polymer

KW - Croconate

KW - Hydrothermal

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U2 - 10.1023/A:1022425429153

DO - 10.1023/A:1022425429153

M3 - Article

AN - SCOPUS:0041179243

VL - 28

SP - 653

EP - 656

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

SN - 1074-1542

IS - 8

ER -

Hydrothermal synthesis of catena(triaqua-(μ-2-croconato-O,O′,O′,O‴)-calcium(II)) calcium croconate trihydrate

Abstract

Keywords

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