Hydrothermal synthesis of catena(triaqua-(mu-2-croconato-O,O ',O '',O ''')-calcium(II)) calcium croconate trihydrate

M J  Plater; M R S  Foreman; R A  Howie

Hydrothermal synthesis of catena(triaqua-(mu-2-croconato-O,O ',O '',O ''')-calcium(II)) calcium croconate trihydrate

M J Plater, M R S Foreman, R A Howie

Chemistry

Research output: Contribution to journal › Article

Abstract

The title compound exists as a 1D coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P-1 with a = 6.642(3)Angstrom, b = 7.793(4)Angstrom c = 8.854(5) Angstrom, alpha = 106.97(5), beta = 92.43(4), gamma = 106.98(4)degrees, V = 415.1(4) Angstrom(3), and Z = 2.

Original language	English
Pages (from-to)	653-656
Number of pages	4
Journal	Journal of Chemical Crystallography
Volume	28
Publication status	Published - 1998

Keywords

coordination polymer
croconate
hydrothermal
CRYSTAL-STRUCTURE

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@article{5675978bef8247fca3671fac4cf5cd96,

title = "Hydrothermal synthesis of catena(triaqua-(mu-2-croconato-O,O ',O '',O ''')-calcium(II)) calcium croconate trihydrate",

abstract = "The title compound exists as a 1D coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P-1 with a = 6.642(3)Angstrom, b = 7.793(4)Angstrom c = 8.854(5) Angstrom, alpha = 106.97(5), beta = 92.43(4), gamma = 106.98(4)degrees, V = 415.1(4) Angstrom(3), and Z = 2.",

keywords = "coordination polymer, croconate, hydrothermal, CRYSTAL-STRUCTURE",

author = "Plater, {M J} and Foreman, {M R S} and Howie, {R A}",

year = "1998",

language = "English",

volume = "28",

pages = "653--656",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer New York",

}

TY - JOUR

T1 - Hydrothermal synthesis of catena(triaqua-(mu-2-croconato-O,O ',O '',O ''')-calcium(II)) calcium croconate trihydrate

AU - Plater, M J

AU - Foreman, M R S

AU - Howie, R A

PY - 1998

Y1 - 1998

N2 - The title compound exists as a 1D coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P-1 with a = 6.642(3)Angstrom, b = 7.793(4)Angstrom c = 8.854(5) Angstrom, alpha = 106.97(5), beta = 92.43(4), gamma = 106.98(4)degrees, V = 415.1(4) Angstrom(3), and Z = 2.

AB - The title compound exists as a 1D coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P-1 with a = 6.642(3)Angstrom, b = 7.793(4)Angstrom c = 8.854(5) Angstrom, alpha = 106.97(5), beta = 92.43(4), gamma = 106.98(4)degrees, V = 415.1(4) Angstrom(3), and Z = 2.

KW - coordination polymer

KW - croconate

KW - hydrothermal

KW - CRYSTAL-STRUCTURE

M3 - Article

SN - 1074-1542

VL - 28

SP - 653

EP - 656

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

ER -

Hydrothermal synthesis of catena(triaqua-(mu-2-croconato-O,O ',O '',O ''')-calcium(II)) calcium croconate trihydrate

Abstract

Keywords

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