Hydrothermal synthesis of catena(triaqua-(mu-2-croconato-O,O ',O '',O ''')-calcium(II)) calcium croconate trihydrate

M J Plater, M R S Foreman, R A Howie

Research output: Contribution to journalArticle

Abstract

The title compound exists as a 1D coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P-1 with a = 6.642(3)Angstrom, b = 7.793(4)Angstrom c = 8.854(5) Angstrom, alpha = 106.97(5), beta = 92.43(4), gamma = 106.98(4)degrees, V = 415.1(4) Angstrom(3), and Z = 2.

Original languageEnglish
Pages (from-to)653-656
Number of pages4
JournalJournal of Chemical Crystallography
Volume28
Publication statusPublished - 1998

Keywords

  • coordination polymer
  • croconate
  • hydrothermal
  • CRYSTAL-STRUCTURE

Cite this

Hydrothermal synthesis of catena(triaqua-(mu-2-croconato-O,O ',O '',O ''')-calcium(II)) calcium croconate trihydrate. / Plater, M J ; Foreman, M R S ; Howie, R A .

In: Journal of Chemical Crystallography, Vol. 28, 1998, p. 653-656.

Research output: Contribution to journalArticle

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abstract = "The title compound exists as a 1D coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P-1 with a = 6.642(3)Angstrom, b = 7.793(4)Angstrom c = 8.854(5) Angstrom, alpha = 106.97(5), beta = 92.43(4), gamma = 106.98(4)degrees, V = 415.1(4) Angstrom(3), and Z = 2.",
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AU - Plater, M J

AU - Foreman, M R S

AU - Howie, R A

PY - 1998

Y1 - 1998

N2 - The title compound exists as a 1D coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P-1 with a = 6.642(3)Angstrom, b = 7.793(4)Angstrom c = 8.854(5) Angstrom, alpha = 106.97(5), beta = 92.43(4), gamma = 106.98(4)degrees, V = 415.1(4) Angstrom(3), and Z = 2.

AB - The title compound exists as a 1D coordination polymer consisting of alternating calcium cations and croconate anions. Three water molecules complete the 7-coordination sphere of Ca in the form of a pentagonal bipyramid and form hydrogen bonds which link the polymeric chains into layers and also interconnect the layers. The structure has a triclinic space group P-1 with a = 6.642(3)Angstrom, b = 7.793(4)Angstrom c = 8.854(5) Angstrom, alpha = 106.97(5), beta = 92.43(4), gamma = 106.98(4)degrees, V = 415.1(4) Angstrom(3), and Z = 2.

KW - coordination polymer

KW - croconate

KW - hydrothermal

KW - CRYSTAL-STRUCTURE

M3 - Article

VL - 28

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JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

SN - 1074-1542

ER -