Hydrothermal synthesis of [Co-3(TPO)(2)(bipy)(2)(H2O)(6)]center dot 2.4 H2O (H3TPO = tris-(4-carboxylphenyl)phosphine oxide). A 1-D double stranded co-ordination polymer

M J  Plater; M R S  Foreman; T  Gelbrich; M B  Hursthouse

Hydrothermal synthesis of [Co-3(TPO)(2)(bipy)(2)(H2O)(6)]center dot 2.4 H2O (H3TPO = tris-(4-carboxylphenyl)phosphine oxide). A 1-D double stranded co-ordination polymer

M J Plater, M R S Foreman, T Gelbrich, M B Hursthouse

Chemistry

Research output: Contribution to journal › Article

Abstract

An improved structure determination of the title compound 1 has been accomplished. It consists of infinite double stranded chains which resemble a molecular ladder. Two different octahedral cobalt ions are present which connect the strands together. There are 8.4 water molecules per formulae unit, 2.4 of which are noncoordinating. The structure has a triclinic space group P (1) over bar with a = 10.8655(7) Angstrom,: b = 11.4362 (9) Angstrom, and c = 13.6684(9) Angstrom; alpha = 111.181(7)degrees, beta = 93.417(9)degrees and gamma = 99.542(9)degrees; V = 1548.5(2) Angstrom (3) and Z = 2.

Original language	English
Pages (from-to)	155-158
Number of pages	4
Journal	Journal of Chemical Crystallography
Volume	30
Publication status	Published - 2000

Keywords

coordination polymer
hydrothermal
METAL-ORGANIC FRAMEWORK
X-RAY-DIFFRACTION
BENZENE-1,3,5-TRICARBOXYLIC ACID
CHANNELS
NETWORK
BINDING
DESIGN
SOLIDS

Cite this

@article{89bc6630d0de4c1088640c7679a93a4d,

title = "Hydrothermal synthesis of [Co-3(TPO)(2)(bipy)(2)(H2O)(6)]center dot 2.4 H2O (H3TPO = tris-(4-carboxylphenyl)phosphine oxide). A 1-D double stranded co-ordination polymer",

abstract = "An improved structure determination of the title compound 1 has been accomplished. It consists of infinite double stranded chains which resemble a molecular ladder. Two different octahedral cobalt ions are present which connect the strands together. There are 8.4 water molecules per formulae unit, 2.4 of which are noncoordinating. The structure has a triclinic space group P (1) over bar with a = 10.8655(7) Angstrom,: b = 11.4362 (9) Angstrom, and c = 13.6684(9) Angstrom; alpha = 111.181(7)degrees, beta = 93.417(9)degrees and gamma = 99.542(9)degrees; V = 1548.5(2) Angstrom (3) and Z = 2.",

keywords = "coordination polymer, hydrothermal, METAL-ORGANIC FRAMEWORK, X-RAY-DIFFRACTION, BENZENE-1,3,5-TRICARBOXYLIC ACID, CHANNELS, NETWORK, BINDING, DESIGN, SOLIDS",

author = "Plater, {M J} and Foreman, {M R S} and T Gelbrich and Hursthouse, {M B}",

year = "2000",

language = "English",

volume = "30",

pages = "155--158",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer New York",

}

TY - JOUR

T1 - Hydrothermal synthesis of [Co-3(TPO)(2)(bipy)(2)(H2O)(6)]center dot 2.4 H2O (H3TPO = tris-(4-carboxylphenyl)phosphine oxide). A 1-D double stranded co-ordination polymer

AU - Plater, M J

AU - Foreman, M R S

AU - Gelbrich, T

AU - Hursthouse, M B

PY - 2000

Y1 - 2000

N2 - An improved structure determination of the title compound 1 has been accomplished. It consists of infinite double stranded chains which resemble a molecular ladder. Two different octahedral cobalt ions are present which connect the strands together. There are 8.4 water molecules per formulae unit, 2.4 of which are noncoordinating. The structure has a triclinic space group P (1) over bar with a = 10.8655(7) Angstrom,: b = 11.4362 (9) Angstrom, and c = 13.6684(9) Angstrom; alpha = 111.181(7)degrees, beta = 93.417(9)degrees and gamma = 99.542(9)degrees; V = 1548.5(2) Angstrom (3) and Z = 2.

AB - An improved structure determination of the title compound 1 has been accomplished. It consists of infinite double stranded chains which resemble a molecular ladder. Two different octahedral cobalt ions are present which connect the strands together. There are 8.4 water molecules per formulae unit, 2.4 of which are noncoordinating. The structure has a triclinic space group P (1) over bar with a = 10.8655(7) Angstrom,: b = 11.4362 (9) Angstrom, and c = 13.6684(9) Angstrom; alpha = 111.181(7)degrees, beta = 93.417(9)degrees and gamma = 99.542(9)degrees; V = 1548.5(2) Angstrom (3) and Z = 2.

KW - coordination polymer

KW - hydrothermal

KW - METAL-ORGANIC FRAMEWORK

KW - X-RAY-DIFFRACTION

KW - BENZENE-1,3,5-TRICARBOXYLIC ACID

KW - CHANNELS

KW - NETWORK

KW - BINDING

KW - DESIGN

KW - SOLIDS

M3 - Article

SN - 1074-1542

VL - 30

SP - 155

EP - 158

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

ER -

Hydrothermal synthesis of [Co-3(TPO)(2)(bipy)(2)(H2O)(6)]center dot 2.4 H2O (H3TPO = tris-(4-carboxylphenyl)phosphine oxide). A 1-D double stranded co-ordination polymer

Abstract

Keywords

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