Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer

M J Plater, M R S Foreman, J M S Skakle

Research output: Contribution to journalArticle

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Abstract

The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group is P-1 with a = 11.6767(8) Angstrom, b = 10.8680(8) Angstrom and c = 11.4232(8) Angstrom; alpha = 92.301(2)degrees, beta = 106.932(2)degrees and gamma = 103.2390(10)degrees; V = 1341.02(16) Angstrom (3); Z = 2.

Original languageEnglish
Pages (from-to)449-453
Number of pages5
JournalJournal of Chemical Crystallography
Volume30
Publication statusPublished - 2000

Keywords

  • coordination polymer
  • manganese
  • hydrogen bonding
  • hydrothermal synthesis
  • METAL-ORGANIC FRAMEWORK
  • COMPLEXES
  • CHANNELS
  • BINDING
  • DESIGN
  • SOLIDS
  • ACID

Cite this

@article{5b9b3a6c71c84a93817a8a39e5773337,
title = "Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer",
abstract = "The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group is P-1 with a = 11.6767(8) Angstrom, b = 10.8680(8) Angstrom and c = 11.4232(8) Angstrom; alpha = 92.301(2)degrees, beta = 106.932(2)degrees and gamma = 103.2390(10)degrees; V = 1341.02(16) Angstrom (3); Z = 2.",
keywords = "coordination polymer, manganese, hydrogen bonding, hydrothermal synthesis, METAL-ORGANIC FRAMEWORK, COMPLEXES, CHANNELS, BINDING, DESIGN, SOLIDS, ACID",
author = "Plater, {M J} and Foreman, {M R S} and Skakle, {J M S}",
year = "2000",
language = "English",
volume = "30",
pages = "449--453",
journal = "Journal of Chemical Crystallography",
issn = "1074-1542",
publisher = "Springer New York",

}

TY - JOUR

T1 - Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer

AU - Plater, M J

AU - Foreman, M R S

AU - Skakle, J M S

PY - 2000

Y1 - 2000

N2 - The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group is P-1 with a = 11.6767(8) Angstrom, b = 10.8680(8) Angstrom and c = 11.4232(8) Angstrom; alpha = 92.301(2)degrees, beta = 106.932(2)degrees and gamma = 103.2390(10)degrees; V = 1341.02(16) Angstrom (3); Z = 2.

AB - The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group is P-1 with a = 11.6767(8) Angstrom, b = 10.8680(8) Angstrom and c = 11.4232(8) Angstrom; alpha = 92.301(2)degrees, beta = 106.932(2)degrees and gamma = 103.2390(10)degrees; V = 1341.02(16) Angstrom (3); Z = 2.

KW - coordination polymer

KW - manganese

KW - hydrogen bonding

KW - hydrothermal synthesis

KW - METAL-ORGANIC FRAMEWORK

KW - COMPLEXES

KW - CHANNELS

KW - BINDING

KW - DESIGN

KW - SOLIDS

KW - ACID

M3 - Article

VL - 30

SP - 449

EP - 453

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

SN - 1074-1542

ER -