Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer

M J Plater, M R S Foreman, J M S Skakle

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Abstract

The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group is P-1 with a = 11.6767(8) Angstrom, b = 10.8680(8) Angstrom and c = 11.4232(8) Angstrom; alpha = 92.301(2)degrees, beta = 106.932(2)degrees and gamma = 103.2390(10)degrees; V = 1341.02(16) Angstrom (3); Z = 2.

Original languageEnglish
Pages (from-to)449-453
Number of pages5
JournalJournal of Chemical Crystallography
Volume30
Publication statusPublished - 2000

Keywords

  • coordination polymer
  • manganese
  • hydrogen bonding
  • hydrothermal synthesis
  • METAL-ORGANIC FRAMEWORK
  • COMPLEXES
  • CHANNELS
  • BINDING
  • DESIGN
  • SOLIDS
  • ACID

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