The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group is P-1 with a = 11.6767(8) Angstrom, b = 10.8680(8) Angstrom and c = 11.4232(8) Angstrom; alpha = 92.301(2)degrees, beta = 106.932(2)degrees and gamma = 103.2390(10)degrees; V = 1341.02(16) Angstrom (3); Z = 2.
|Number of pages||5|
|Journal||Journal of Chemical Crystallography|
|Publication status||Published - 2000|
- coordination polymer
- hydrogen bonding
- hydrothermal synthesis
- METAL-ORGANIC FRAMEWORK