Abstract
The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group is P-1 with a = 11.6767(8) Angstrom, b = 10.8680(8) Angstrom and c = 11.4232(8) Angstrom; alpha = 92.301(2)degrees, beta = 106.932(2)degrees and gamma = 103.2390(10)degrees; V = 1341.02(16) Angstrom (3); Z = 2.
| Original language | English |
|---|---|
| Pages (from-to) | 449-453 |
| Number of pages | 5 |
| Journal | Journal of Chemical Crystallography |
| Volume | 30 |
| Publication status | Published - 2000 |
Keywords
- coordination polymer
- manganese
- hydrogen bonding
- hydrothermal synthesis
- METAL-ORGANIC FRAMEWORK
- COMPLEXES
- CHANNELS
- BINDING
- DESIGN
- SOLIDS
- ACID
Cite this
Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer. / Plater, M J ; Foreman, M R S ; Skakle, J M S .
In: Journal of Chemical Crystallography, Vol. 30, 2000, p. 449-453.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer
AU - Plater, M J
AU - Foreman, M R S
AU - Skakle, J M S
PY - 2000
Y1 - 2000
N2 - The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group is P-1 with a = 11.6767(8) Angstrom, b = 10.8680(8) Angstrom and c = 11.4232(8) Angstrom; alpha = 92.301(2)degrees, beta = 106.932(2)degrees and gamma = 103.2390(10)degrees; V = 1341.02(16) Angstrom (3); Z = 2.
AB - The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group is P-1 with a = 11.6767(8) Angstrom, b = 10.8680(8) Angstrom and c = 11.4232(8) Angstrom; alpha = 92.301(2)degrees, beta = 106.932(2)degrees and gamma = 103.2390(10)degrees; V = 1341.02(16) Angstrom (3); Z = 2.
KW - coordination polymer
KW - manganese
KW - hydrogen bonding
KW - hydrothermal synthesis
KW - METAL-ORGANIC FRAMEWORK
KW - COMPLEXES
KW - CHANNELS
KW - BINDING
KW - DESIGN
KW - SOLIDS
KW - ACID
M3 - Article
VL - 30
SP - 449
EP - 453
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
SN - 1074-1542
ER -