TY - JOUR
T1 - Hydrothermal synthesis of polymeric metal carboxylates from benzene-1,2,4,5-tetracarboxylic acid and benzene-1,2,4-tricarboxylic acid
AU - Plater, Michael John
AU - Foreman, M. R. S. J.
AU - Howie, Robert Alan
AU - Skakle, Janet Mabel Scott
AU - Slawin, A. M. Z.
PY - 2001
Y1 - 2001
N2 - Crystallisation of benzene-1,2,4,5-tetracarboxylic acid or benzene-1,2,4-tricarboxylic acid with divalent metal-ions Co, Mn or Zn and 2,2-bipyridyl gives coordination solids of composition [Co-2(C10H2O8)(C10H8N2)(2)(H2O)] (1), [Co-3(C9H3O6)(2)(C10H8N2)(2)-(H2O)(2)] (2), [Mn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (3) or [Zn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (4). Each has a sheet structure with a distorted octahedral coordination environment. (C) 2001 Elsevier Science B.V. All rights reserved.
AB - Crystallisation of benzene-1,2,4,5-tetracarboxylic acid or benzene-1,2,4-tricarboxylic acid with divalent metal-ions Co, Mn or Zn and 2,2-bipyridyl gives coordination solids of composition [Co-2(C10H2O8)(C10H8N2)(2)(H2O)] (1), [Co-3(C9H3O6)(2)(C10H8N2)(2)-(H2O)(2)] (2), [Mn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (3) or [Zn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (4). Each has a sheet structure with a distorted octahedral coordination environment. (C) 2001 Elsevier Science B.V. All rights reserved.
KW - hydrothermal
KW - coordination polymers
KW - CRystal engineering
KW - BENZENE-1,3,5-TRICARBOXYLIC ACID
KW - FRAMEWORK
U2 - 10.1016/S0020-1693(01)00318-8
DO - 10.1016/S0020-1693(01)00318-8
M3 - Article
SN - 0020-1693
VL - 315
SP - 126
EP - 132
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
ER -