Hydrothermal synthesis of polymeric metal carboxylates from benzene-1,2,4,5-tetracarboxylic acid and benzene-1,2,4-tricarboxylic acid

Michael John Plater, M. R. S. J. Foreman, Robert Alan Howie, Janet Mabel Scott Skakle, A. M. Z. Slawin

Research output: Contribution to journalArticle

86 Citations (Scopus)

Abstract

Crystallisation of benzene-1,2,4,5-tetracarboxylic acid or benzene-1,2,4-tricarboxylic acid with divalent metal-ions Co, Mn or Zn and 2,2-bipyridyl gives coordination solids of composition [Co-2(C10H2O8)(C10H8N2)(2)(H2O)] (1), [Co-3(C9H3O6)(2)(C10H8N2)(2)-(H2O)(2)] (2), [Mn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (3) or [Zn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (4). Each has a sheet structure with a distorted octahedral coordination environment. (C) 2001 Elsevier Science B.V. All rights reserved.

Original languageEnglish
Pages (from-to)126-132
Number of pages6
JournalInorganica Chimica Acta
Volume315
DOIs
Publication statusPublished - 2001

Keywords

  • hydrothermal
  • coordination polymers
  • CRystal engineering
  • BENZENE-1,3,5-TRICARBOXYLIC ACID
  • FRAMEWORK

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