Hydroxonium triaquabis(biuret-kappa O-2,O ')dichloridolanthanum(III) dichloride dihydrate

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title compound, (H3O)[LaCl2(C2H5N3O2)(2)(H2O)(3)] Cl-2 center dot-2H(2)O, the La atom is bonded to seven O atoms ( arising from two O, O '- bidentate biuret molecules and three water molecules) and two chloride ions in an irregular arrangement. A network of N-H center dot center dot center dot O, N -H center dot center dot center dot Cl, O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. The La atom, one Cl atom and four O atoms lie on a crystallographic mirror plane.

Original languageEnglish
Pages (from-to)m681-m682
Number of pages2
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number5
DOIs
Publication statusPublished - May 2008

Keywords

  • lanthanide

Cite this

@article{1934a505669e4beba8b9539c98810c54,
title = "Hydroxonium triaquabis(biuret-kappa O-2,O ')dichloridolanthanum(III) dichloride dihydrate",
abstract = "In the title compound, (H3O)[LaCl2(C2H5N3O2)(2)(H2O)(3)] Cl-2 center dot-2H(2)O, the La atom is bonded to seven O atoms ( arising from two O, O '- bidentate biuret molecules and three water molecules) and two chloride ions in an irregular arrangement. A network of N-H center dot center dot center dot O, N -H center dot center dot center dot Cl, O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. The La atom, one Cl atom and four O atoms lie on a crystallographic mirror plane.",
keywords = "lanthanide",
author = "Harrison, {William T. A.}",
year = "2008",
month = "5",
doi = "10.1107/S1600536808010349",
language = "English",
volume = "64",
pages = "m681--m682",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "5",

}

TY - JOUR

T1 - Hydroxonium triaquabis(biuret-kappa O-2,O ')dichloridolanthanum(III) dichloride dihydrate

AU - Harrison, William T. A.

PY - 2008/5

Y1 - 2008/5

N2 - In the title compound, (H3O)[LaCl2(C2H5N3O2)(2)(H2O)(3)] Cl-2 center dot-2H(2)O, the La atom is bonded to seven O atoms ( arising from two O, O '- bidentate biuret molecules and three water molecules) and two chloride ions in an irregular arrangement. A network of N-H center dot center dot center dot O, N -H center dot center dot center dot Cl, O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. The La atom, one Cl atom and four O atoms lie on a crystallographic mirror plane.

AB - In the title compound, (H3O)[LaCl2(C2H5N3O2)(2)(H2O)(3)] Cl-2 center dot-2H(2)O, the La atom is bonded to seven O atoms ( arising from two O, O '- bidentate biuret molecules and three water molecules) and two chloride ions in an irregular arrangement. A network of N-H center dot center dot center dot O, N -H center dot center dot center dot Cl, O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. The La atom, one Cl atom and four O atoms lie on a crystallographic mirror plane.

KW - lanthanide

U2 - 10.1107/S1600536808010349

DO - 10.1107/S1600536808010349

M3 - Article

VL - 64

SP - m681-m682

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 5

ER -