In situ template generation for zincophosphate systhesis leading to guanylurea zinc phosphate C2H7N4O·ZnPO4, containing template-to-template N-H O hydrogen bonds

C. A. Bremner, M. Simpson, William Thomas Alexander Harrison

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Abstract

The synthesis and structure of C2H7N4O.ZnPO4 (guanylurea zinc phosphate) are reported, The cationic [C2H7N4O](+) template was prepared in situ by the slow hydrolysis of the neutral 2-cyanoguanidine starting material. The resulting structure contains an unusual, unprotonated, zincophosphate layer topology as well as N-H...O template-to-template hydrogen bonds which help to stabilize a "double sandwich" of templating cations between the inorganic sheets. Crystal data: C2H7N4O.ZnPO4, Mr = 263.48, monoclinic, P2(1)/c, a = 13.6453(9), b = 5.0716(3), c = 10.6005(7) Angstrom, beta = 95.918(2)degrees, Z = 4, V = 729.7(1) Angstrom(3), R(F) = 0.034, omegaR(F) = 0.034. (C) 2002 Editions scientifiques et medicales Elsevier SAS. All rights reserved.

Original languageEnglish
Pages (from-to)969-972
Number of pages3
JournalSolid State Sciences
Volume4
DOIs
Publication statusPublished - 2002

Keywords

  • GUANIDINIUM

Cite this

@article{9e8f75da26e143cda45c245631158bfc,
title = "In situ template generation for zincophosphate systhesis leading to guanylurea zinc phosphate C2H7N4O·ZnPO4, containing template-to-template N-H O hydrogen bonds",
abstract = "The synthesis and structure of C2H7N4O.ZnPO4 (guanylurea zinc phosphate) are reported, The cationic [C2H7N4O](+) template was prepared in situ by the slow hydrolysis of the neutral 2-cyanoguanidine starting material. The resulting structure contains an unusual, unprotonated, zincophosphate layer topology as well as N-H...O template-to-template hydrogen bonds which help to stabilize a {"}double sandwich{"} of templating cations between the inorganic sheets. Crystal data: C2H7N4O.ZnPO4, Mr = 263.48, monoclinic, P2(1)/c, a = 13.6453(9), b = 5.0716(3), c = 10.6005(7) Angstrom, beta = 95.918(2)degrees, Z = 4, V = 729.7(1) Angstrom(3), R(F) = 0.034, omegaR(F) = 0.034. (C) 2002 Editions scientifiques et medicales Elsevier SAS. All rights reserved.",
keywords = "GUANIDINIUM",
author = "Bremner, {C. A.} and M. Simpson and Harrison, {William Thomas Alexander}",
year = "2002",
doi = "10.1016/S1293-2558(02)01340-7",
language = "English",
volume = "4",
pages = "969--972",
journal = "Solid State Sciences",
issn = "1293-2558",
publisher = "Elsevier Masson SAS",

}

TY - JOUR

T1 - In situ template generation for zincophosphate systhesis leading to guanylurea zinc phosphate C2H7N4O·ZnPO4, containing template-to-template N-H O hydrogen bonds

AU - Bremner, C. A.

AU - Simpson, M.

AU - Harrison, William Thomas Alexander

PY - 2002

Y1 - 2002

N2 - The synthesis and structure of C2H7N4O.ZnPO4 (guanylurea zinc phosphate) are reported, The cationic [C2H7N4O](+) template was prepared in situ by the slow hydrolysis of the neutral 2-cyanoguanidine starting material. The resulting structure contains an unusual, unprotonated, zincophosphate layer topology as well as N-H...O template-to-template hydrogen bonds which help to stabilize a "double sandwich" of templating cations between the inorganic sheets. Crystal data: C2H7N4O.ZnPO4, Mr = 263.48, monoclinic, P2(1)/c, a = 13.6453(9), b = 5.0716(3), c = 10.6005(7) Angstrom, beta = 95.918(2)degrees, Z = 4, V = 729.7(1) Angstrom(3), R(F) = 0.034, omegaR(F) = 0.034. (C) 2002 Editions scientifiques et medicales Elsevier SAS. All rights reserved.

AB - The synthesis and structure of C2H7N4O.ZnPO4 (guanylurea zinc phosphate) are reported, The cationic [C2H7N4O](+) template was prepared in situ by the slow hydrolysis of the neutral 2-cyanoguanidine starting material. The resulting structure contains an unusual, unprotonated, zincophosphate layer topology as well as N-H...O template-to-template hydrogen bonds which help to stabilize a "double sandwich" of templating cations between the inorganic sheets. Crystal data: C2H7N4O.ZnPO4, Mr = 263.48, monoclinic, P2(1)/c, a = 13.6453(9), b = 5.0716(3), c = 10.6005(7) Angstrom, beta = 95.918(2)degrees, Z = 4, V = 729.7(1) Angstrom(3), R(F) = 0.034, omegaR(F) = 0.034. (C) 2002 Editions scientifiques et medicales Elsevier SAS. All rights reserved.

KW - GUANIDINIUM

U2 - 10.1016/S1293-2558(02)01340-7

DO - 10.1016/S1293-2558(02)01340-7

M3 - Article

VL - 4

SP - 969

EP - 972

JO - Solid State Sciences

JF - Solid State Sciences

SN - 1293-2558

ER -