N,N'-Bis[tris(hydroxymethyl)methyl]-ethanediamide: six O-H...O hydrogen bonds generate only a two-dimensional structure

J. A. Ross, C. Fernandes, J. L. Wardell, C. Glidewell

    Research output: Contribution to journalArticle

    2 Citations (Scopus)

    Abstract

    Molecules of the title compound, C10H20N2O8, adopt a conformation which is almost centrosymmetric. The molecules are disordered over two sets of sites with an occupancy ratio of 0.94:0.06. In the major form, there are two intramolecular OD H . . .O hydrogen bonds [O . . .O 2.756 (4) and 2.765 (4) Angstrom; O- H . . .O 144 and 146 degrees], in which the two amidic O atoms act as acceptors. In addition, there are four intermolecular OD H . . .O hydrogen bonds [O . . .O 2.650 (3)-2.666 (3) Angstrom; O- H . . .O 158-171 degrees]; these link each molecule to six others in a continuous sheet structure which contains five distinct ring motifs, two of the S(7) type, two of the R-3(3) (10) type and one of the R-2(2) (22) type.

    Original languageEnglish
    Pages (from-to)949-951
    Number of pages2
    JournalActa Crystallographica Section C, Crystal Structure Communications
    VolumeC57
    DOIs
    Publication statusPublished - 2001

    Keywords

    • X-RAY-DIFFRACTION
    • PENTAERYTHRITOL

    Cite this

    N,N'-Bis[tris(hydroxymethyl)methyl]-ethanediamide: six O-H...O hydrogen bonds generate only a two-dimensional structure. / Ross, J. A.; Fernandes, C.; Wardell, J. L.; Glidewell, C.

    In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. C57, 2001, p. 949-951.

    Research output: Contribution to journalArticle

    @article{a94b620fca4941779f3997621da05904,
    title = "N,N'-Bis[tris(hydroxymethyl)methyl]-ethanediamide: six O-H...O hydrogen bonds generate only a two-dimensional structure",
    abstract = "Molecules of the title compound, C10H20N2O8, adopt a conformation which is almost centrosymmetric. The molecules are disordered over two sets of sites with an occupancy ratio of 0.94:0.06. In the major form, there are two intramolecular OD H . . .O hydrogen bonds [O . . .O 2.756 (4) and 2.765 (4) Angstrom; O- H . . .O 144 and 146 degrees], in which the two amidic O atoms act as acceptors. In addition, there are four intermolecular OD H . . .O hydrogen bonds [O . . .O 2.650 (3)-2.666 (3) Angstrom; O- H . . .O 158-171 degrees]; these link each molecule to six others in a continuous sheet structure which contains five distinct ring motifs, two of the S(7) type, two of the R-3(3) (10) type and one of the R-2(2) (22) type.",
    keywords = "X-RAY-DIFFRACTION, PENTAERYTHRITOL",
    author = "Ross, {J. A.} and C. Fernandes and Wardell, {J. L.} and C. Glidewell",
    year = "2001",
    doi = "10.1107/S0108270101008940",
    language = "English",
    volume = "C57",
    pages = "949--951",
    journal = "Acta Crystallographica Section C, Crystal Structure Communications",
    issn = "0108-2701",
    publisher = "Wiley-Blackwell",

    }

    TY - JOUR

    T1 - N,N'-Bis[tris(hydroxymethyl)methyl]-ethanediamide: six O-H...O hydrogen bonds generate only a two-dimensional structure

    AU - Ross, J. A.

    AU - Fernandes, C.

    AU - Wardell, J. L.

    AU - Glidewell, C.

    PY - 2001

    Y1 - 2001

    N2 - Molecules of the title compound, C10H20N2O8, adopt a conformation which is almost centrosymmetric. The molecules are disordered over two sets of sites with an occupancy ratio of 0.94:0.06. In the major form, there are two intramolecular OD H . . .O hydrogen bonds [O . . .O 2.756 (4) and 2.765 (4) Angstrom; O- H . . .O 144 and 146 degrees], in which the two amidic O atoms act as acceptors. In addition, there are four intermolecular OD H . . .O hydrogen bonds [O . . .O 2.650 (3)-2.666 (3) Angstrom; O- H . . .O 158-171 degrees]; these link each molecule to six others in a continuous sheet structure which contains five distinct ring motifs, two of the S(7) type, two of the R-3(3) (10) type and one of the R-2(2) (22) type.

    AB - Molecules of the title compound, C10H20N2O8, adopt a conformation which is almost centrosymmetric. The molecules are disordered over two sets of sites with an occupancy ratio of 0.94:0.06. In the major form, there are two intramolecular OD H . . .O hydrogen bonds [O . . .O 2.756 (4) and 2.765 (4) Angstrom; O- H . . .O 144 and 146 degrees], in which the two amidic O atoms act as acceptors. In addition, there are four intermolecular OD H . . .O hydrogen bonds [O . . .O 2.650 (3)-2.666 (3) Angstrom; O- H . . .O 158-171 degrees]; these link each molecule to six others in a continuous sheet structure which contains five distinct ring motifs, two of the S(7) type, two of the R-3(3) (10) type and one of the R-2(2) (22) type.

    KW - X-RAY-DIFFRACTION

    KW - PENTAERYTHRITOL

    U2 - 10.1107/S0108270101008940

    DO - 10.1107/S0108270101008940

    M3 - Article

    VL - C57

    SP - 949

    EP - 951

    JO - Acta Crystallographica Section C, Crystal Structure Communications

    JF - Acta Crystallographica Section C, Crystal Structure Communications

    SN - 0108-2701

    ER -