Investigation of ZSM-5 catalysts for dimethylether conversion using inelastic neutron scattering

Andrea Zachariou, Alexander Hawkins, David Lennon, Stewart F. Parker, Suwardiyanto, Santhosh K. Matam, C. Richard A. Catlow, Paul Collier, Ali Hameed, James McGregor, Russell F. Howe* (Corresponding Author)

*Corresponding author for this work

Research output: Contribution to journalArticle

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Abstract

We report the characterisation of zeolite ZSM-5 catalysts used in the conversion of dimethylether to hydrocarbons. Inelastic neutron scattering spectroscopy, supported by solid state NMR, shows that the more rapid deactivation occurring with dimethylether compared with methanol is associated with the formation of less methylated aromatic coke species and attributed to the lower levels of water present during dimethylether conversion. The ability of inelastic neutron scattering to probe a working catalyst with no sample preparation is demonstrated.

Original languageEnglish
Pages (from-to)1-7
Number of pages7
JournalApplied Catalysis A: General
Volume569
Early online date9 Oct 2018
DOIs
Publication statusPublished - 5 Jan 2019

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Inelastic neutron scattering
Catalysts
Hydrocarbons
Coke
Methanol
Nuclear magnetic resonance
Spectroscopy
Water
ZSM-5 zeolite

Keywords

  • Coke formation
  • Dimethylether
  • Inelastic neutron scattering
  • ZSM-5

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Cite this

Investigation of ZSM-5 catalysts for dimethylether conversion using inelastic neutron scattering. / Zachariou, Andrea; Hawkins, Alexander; Lennon, David; Parker, Stewart F.; Suwardiyanto; Matam, Santhosh K.; Catlow, C. Richard A.; Collier, Paul; Hameed, Ali; McGregor, James; Howe, Russell F. (Corresponding Author).

In: Applied Catalysis A: General, Vol. 569, 05.01.2019, p. 1-7.

Research output: Contribution to journalArticle

Zachariou, A, Hawkins, A, Lennon, D, Parker, SF, Suwardiyanto, Matam, SK, Catlow, CRA, Collier, P, Hameed, A, McGregor, J & Howe, RF 2019, 'Investigation of ZSM-5 catalysts for dimethylether conversion using inelastic neutron scattering', Applied Catalysis A: General, vol. 569, pp. 1-7. https://doi.org/10.1016/j.apcata.2018.10.010
Zachariou, Andrea ; Hawkins, Alexander ; Lennon, David ; Parker, Stewart F. ; Suwardiyanto ; Matam, Santhosh K. ; Catlow, C. Richard A. ; Collier, Paul ; Hameed, Ali ; McGregor, James ; Howe, Russell F. / Investigation of ZSM-5 catalysts for dimethylether conversion using inelastic neutron scattering. In: Applied Catalysis A: General. 2019 ; Vol. 569. pp. 1-7.
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