Iron(II) hydrazinium sulfate

Krishnan Srinivasan; Subbaiah Govindarajan; William T. A. Harrison

doi:10.1107/S1600536806056509

Iron(II) hydrazinium sulfate

Krishnan Srinivasan, Subbaiah Govindarajan, William T. A. Harrison

Chemistry

Research output: Contribution to journal › Article

4 Citations (Scopus)

Abstract

The title compound, poly[[dihydraziniumiron(II)]-di-mu-sulfato- kappa(4) O:O'], [Fe(SO4)(2)(N2H5)(2)](n), contains fairly regular trans-FeN2O4 octahedra. The Fe atoms (site symmetry (1) over bar) are bridged by pairs of sulfate groups into infinite [ 100] chains, which are cross-linked by a network of N-H center dot center dot center dot O hydrogen bonds. Fe(N2H5)(2)(SO4)(2) is isostructural with its zinc, chromium(II) and cadmium-containing analogues.

Original language	English
Pages (from-to)	i41-i42
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	2
DOIs	https://doi.org/10.1107/S1600536806056509
Publication status	Published - 1 Feb 2007

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title = "Iron(II) hydrazinium sulfate",

abstract = "The title compound, poly[[dihydraziniumiron(II)]-di-mu-sulfato- kappa(4) O:O'], [Fe(SO4)(2)(N2H5)(2)](n), contains fairly regular trans-FeN2O4 octahedra. The Fe atoms (site symmetry (1) over bar) are bridged by pairs of sulfate groups into infinite [ 100] chains, which are cross-linked by a network of N-H center dot center dot center dot O hydrogen bonds. Fe(N2H5)(2)(SO4)(2) is isostructural with its zinc, chromium(II) and cadmium-containing analogues.",

author = "Krishnan Srinivasan and Subbaiah Govindarajan and Harrison, {William T. A.}",

year = "2007",

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doi = "10.1107/S1600536806056509",

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T1 - Iron(II) hydrazinium sulfate

AU - Srinivasan, Krishnan

AU - Govindarajan, Subbaiah

AU - Harrison, William T. A.

PY - 2007/2/1

Y1 - 2007/2/1

N2 - The title compound, poly[[dihydraziniumiron(II)]-di-mu-sulfato- kappa(4) O:O'], [Fe(SO4)(2)(N2H5)(2)](n), contains fairly regular trans-FeN2O4 octahedra. The Fe atoms (site symmetry (1) over bar) are bridged by pairs of sulfate groups into infinite [ 100] chains, which are cross-linked by a network of N-H center dot center dot center dot O hydrogen bonds. Fe(N2H5)(2)(SO4)(2) is isostructural with its zinc, chromium(II) and cadmium-containing analogues.

AB - The title compound, poly[[dihydraziniumiron(II)]-di-mu-sulfato- kappa(4) O:O'], [Fe(SO4)(2)(N2H5)(2)](n), contains fairly regular trans-FeN2O4 octahedra. The Fe atoms (site symmetry (1) over bar) are bridged by pairs of sulfate groups into infinite [ 100] chains, which are cross-linked by a network of N-H center dot center dot center dot O hydrogen bonds. Fe(N2H5)(2)(SO4)(2) is isostructural with its zinc, chromium(II) and cadmium-containing analogues.

U2 - 10.1107/S1600536806056509

DO - 10.1107/S1600536806056509

M3 - Article

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VL - 63

SP - i41-i42

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 2

ER -

Iron(II) hydrazinium sulfate

Abstract

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