Iron(II) hydrazinium sulfate

Krishnan Srinivasan, Subbaiah Govindarajan, William T. A. Harrison

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title compound, poly[[dihydraziniumiron(II)]-di-mu-sulfato- kappa(4) O:O'], [Fe(SO4)(2)(N2H5)(2)](n), contains fairly regular trans-FeN2O4 octahedra. The Fe atoms (site symmetry (1) over bar) are bridged by pairs of sulfate groups into infinite [ 100] chains, which are cross-linked by a network of N-H center dot center dot center dot O hydrogen bonds. Fe(N2H5)(2)(SO4)(2) is isostructural with its zinc, chromium(II) and cadmium-containing analogues.

Original languageEnglish
Pages (from-to)i41-i42
Number of pages2
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number2
DOIs
Publication statusPublished - 1 Feb 2007

Cite this

Iron(II) hydrazinium sulfate. / Srinivasan, Krishnan; Govindarajan, Subbaiah; Harrison, William T. A.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 2, 01.02.2007, p. i41-i42.

Research output: Contribution to journalArticle

Srinivasan, Krishnan ; Govindarajan, Subbaiah ; Harrison, William T. A. / Iron(II) hydrazinium sulfate. In: Acta Crystallographica Section E: Structure Reports Online. 2007 ; Vol. 63, No. 2. pp. i41-i42.
@article{71aee46a123e437eab66d7649e423df9,
title = "Iron(II) hydrazinium sulfate",
abstract = "The title compound, poly[[dihydraziniumiron(II)]-di-mu-sulfato- kappa(4) O:O'], [Fe(SO4)(2)(N2H5)(2)](n), contains fairly regular trans-FeN2O4 octahedra. The Fe atoms (site symmetry (1) over bar) are bridged by pairs of sulfate groups into infinite [ 100] chains, which are cross-linked by a network of N-H center dot center dot center dot O hydrogen bonds. Fe(N2H5)(2)(SO4)(2) is isostructural with its zinc, chromium(II) and cadmium-containing analogues.",
author = "Krishnan Srinivasan and Subbaiah Govindarajan and Harrison, {William T. A.}",
year = "2007",
month = "2",
day = "1",
doi = "10.1107/S1600536806056509",
language = "English",
volume = "63",
pages = "i41--i42",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "2",

}

TY - JOUR

T1 - Iron(II) hydrazinium sulfate

AU - Srinivasan, Krishnan

AU - Govindarajan, Subbaiah

AU - Harrison, William T. A.

PY - 2007/2/1

Y1 - 2007/2/1

N2 - The title compound, poly[[dihydraziniumiron(II)]-di-mu-sulfato- kappa(4) O:O'], [Fe(SO4)(2)(N2H5)(2)](n), contains fairly regular trans-FeN2O4 octahedra. The Fe atoms (site symmetry (1) over bar) are bridged by pairs of sulfate groups into infinite [ 100] chains, which are cross-linked by a network of N-H center dot center dot center dot O hydrogen bonds. Fe(N2H5)(2)(SO4)(2) is isostructural with its zinc, chromium(II) and cadmium-containing analogues.

AB - The title compound, poly[[dihydraziniumiron(II)]-di-mu-sulfato- kappa(4) O:O'], [Fe(SO4)(2)(N2H5)(2)](n), contains fairly regular trans-FeN2O4 octahedra. The Fe atoms (site symmetry (1) over bar) are bridged by pairs of sulfate groups into infinite [ 100] chains, which are cross-linked by a network of N-H center dot center dot center dot O hydrogen bonds. Fe(N2H5)(2)(SO4)(2) is isostructural with its zinc, chromium(II) and cadmium-containing analogues.

U2 - 10.1107/S1600536806056509

DO - 10.1107/S1600536806056509

M3 - Article

VL - 63

SP - i41-i42

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 2

ER -