Isomorphous dichloro- and dibromo(2-methyl-2-phenylpropyl)phenylstannane, both displaying the same intramolecular p-pinteraction at 120K

J. A. S. Bomfim; C. A. Filgueiras; Robert Alan Howie; Janet Mabel Scott Skakle; J. L. Wardell

doi:10.1107/S0108270103024272

Isomorphous dichloro- and dibromo(2-methyl-2-phenylpropyl)phenylstannane, both displaying the same intramolecular p-pinteraction at 120K

J. A. S. Bomfim, C. A. Filgueiras, Robert Alan Howie, Janet Mabel Scott Skakle, J. L. Wardell

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compounds, dichloro- and dibromoneophylphenyltin, [SnCl2(C6H5)(C10H13)] and [SnBr2(C6H5)(C10H13)], respectively, are remarkable for the 'U' shape of the molecules, whereby the two phenyl groups are brought face-to-face in an arrangement that permits intermolecular C-H...pi bonds to connect the molecules into layers parallel to (100). Intermolecular Sn-halide bonds are notably absent from the structures.

Original language	English
Pages (from-to)	m526-m529
Number of pages	4
Journal	Acta Crystallographica Section C, Crystal Structure Communications
Volume	C59
DOIs	https://doi.org/10.1107/S0108270103024272
Publication status	Published - 2003

Keywords

CRYSTAL STRUCTURE
SINGLE-CRYSTAL
DATABASE

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Isomorphous dichloro- and dibromo(2-methyl-2-phenylpropyl)phenylstannane, both displaying the same intramolecular p-pinteraction at 120K. / Bomfim, J. A. S.; Filgueiras, C. A.; Howie, Robert Alan et al.
In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. C59, 2003, p. m526-m529.

Research output: Contribution to journal › Article › peer-review

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title = "Isomorphous dichloro- and dibromo(2-methyl-2-phenylpropyl)phenylstannane, both displaying the same intramolecular p-pinteraction at 120K",

abstract = "The title compounds, dichloro- and dibromoneophylphenyltin, [SnCl2(C6H5)(C10H13)] and [SnBr2(C6H5)(C10H13)], respectively, are remarkable for the 'U' shape of the molecules, whereby the two phenyl groups are brought face-to-face in an arrangement that permits intermolecular C-H...pi bonds to connect the molecules into layers parallel to (100). Intermolecular Sn-halide bonds are notably absent from the structures.",

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year = "2003",

doi = "10.1107/S0108270103024272",

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T1 - Isomorphous dichloro- and dibromo(2-methyl-2-phenylpropyl)phenylstannane, both displaying the same intramolecular p-pinteraction at 120K

AU - Bomfim, J. A. S.

AU - Filgueiras, C. A.

AU - Howie, Robert Alan

AU - Skakle, Janet Mabel Scott

AU - Wardell, J. L.

PY - 2003

Y1 - 2003

N2 - The title compounds, dichloro- and dibromoneophylphenyltin, [SnCl2(C6H5)(C10H13)] and [SnBr2(C6H5)(C10H13)], respectively, are remarkable for the 'U' shape of the molecules, whereby the two phenyl groups are brought face-to-face in an arrangement that permits intermolecular C-H...pi bonds to connect the molecules into layers parallel to (100). Intermolecular Sn-halide bonds are notably absent from the structures.

AB - The title compounds, dichloro- and dibromoneophylphenyltin, [SnCl2(C6H5)(C10H13)] and [SnBr2(C6H5)(C10H13)], respectively, are remarkable for the 'U' shape of the molecules, whereby the two phenyl groups are brought face-to-face in an arrangement that permits intermolecular C-H...pi bonds to connect the molecules into layers parallel to (100). Intermolecular Sn-halide bonds are notably absent from the structures.

KW - CRYSTAL STRUCTURE

KW - SINGLE-CRYSTAL

KW - DATABASE

U2 - 10.1107/S0108270103024272

DO - 10.1107/S0108270103024272

M3 - Article

SN - 0108-2701

VL - C59

SP - m526-m529

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

ER -

Isomorphous dichloro- and dibromo(2-methyl-2-phenylpropyl)phenylstannane, both displaying the same intramolecular p-pinteraction at 120K

Abstract

Keywords

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