LiMn3(SeO3)(2)(HSeO3)(6)

Magnus George Johnston, William T. A. Harrison

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The title compound, lithium trimanganese bis[trioxoselenate(IV)] hexakis[hydrogentrioxoselenate(IV)], is built up from a vertex-sharing network of distorted (MnO6)-O-III octahedra, SeO3 and HSeO3 pyramids and unusual Li(OH)(6) octahedra, resulting in a dense three-dimensional structure. Mn, Li and one Se atom have site symmetries of (1) over bar, (3) over bar, and 3, respectively. An O - H center dot center dot center dot O hydrogen bond helps to establish the crystal packing.

Original languageEnglish
Pages (from-to)i28-i30
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume63
Issue number4
DOIs
Publication statusPublished - 1 Apr 2007

Keywords

  • crystal-structures
  • selenites
  • program
  • bond

Cite this

LiMn3(SeO3)(2)(HSeO3)(6). / Johnston, Magnus George; Harrison, William T. A.

In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 63, No. 4, 01.04.2007, p. i28-i30.

Research output: Contribution to journalArticle

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AB - The title compound, lithium trimanganese bis[trioxoselenate(IV)] hexakis[hydrogentrioxoselenate(IV)], is built up from a vertex-sharing network of distorted (MnO6)-O-III octahedra, SeO3 and HSeO3 pyramids and unusual Li(OH)(6) octahedra, resulting in a dense three-dimensional structure. Mn, Li and one Se atom have site symmetries of (1) over bar, (3) over bar, and 3, respectively. An O - H center dot center dot center dot O hydrogen bond helps to establish the crystal packing.

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