LiMn3(SeO3)(2)(HSeO3)(6)

Magnus George Johnston; William T. A. Harrison

doi:10.1107/S0108270107001588

LiMn3(SeO3)(2)(HSeO3)(6)

Magnus George Johnston, William T. A. Harrison

Chemistry

Research output: Contribution to journal › Article

4 Citations (Scopus)

Abstract

The title compound, lithium trimanganese bis[trioxoselenate(IV)] hexakis[hydrogentrioxoselenate(IV)], is built up from a vertex-sharing network of distorted (MnO6)-O-III octahedra, SeO3 and HSeO3 pyramids and unusual Li(OH)(6) octahedra, resulting in a dense three-dimensional structure. Mn, Li and one Se atom have site symmetries of (1) over bar, (3) over bar, and 3, respectively. An O - H center dot center dot center dot O hydrogen bond helps to establish the crystal packing.

Original language	English
Pages (from-to)	i28-i30
Number of pages	3
Journal	Acta Crystallographica Section C, Crystal Structure Communications
Volume	63
Issue number	4
DOIs	https://doi.org/10.1107/S0108270107001588
Publication status	Published - 1 Apr 2007

Keywords

crystal-structures
selenites
program
bond

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title = "LiMn3(SeO3)(2)(HSeO3)(6)",

abstract = "The title compound, lithium trimanganese bis[trioxoselenate(IV)] hexakis[hydrogentrioxoselenate(IV)], is built up from a vertex-sharing network of distorted (MnO6)-O-III octahedra, SeO3 and HSeO3 pyramids and unusual Li(OH)(6) octahedra, resulting in a dense three-dimensional structure. Mn, Li and one Se atom have site symmetries of (1) over bar, (3) over bar, and 3, respectively. An O - H center dot center dot center dot O hydrogen bond helps to establish the crystal packing.",

keywords = "crystal-structures, selenites, program, bond",

author = "Johnston, {Magnus George} and Harrison, {William T. A.}",

year = "2007",

month = apr,

day = "1",

doi = "10.1107/S0108270107001588",

language = "English",

volume = "63",

pages = "i28--i30",

journal = "Acta Crystallographica Section C, Crystal Structure Communications",

issn = "0108-2701",

publisher = "Wiley-Blackwell ",

number = "4",

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TY - JOUR

T1 - LiMn3(SeO3)(2)(HSeO3)(6)

AU - Johnston, Magnus George

AU - Harrison, William T. A.

PY - 2007/4/1

Y1 - 2007/4/1

N2 - The title compound, lithium trimanganese bis[trioxoselenate(IV)] hexakis[hydrogentrioxoselenate(IV)], is built up from a vertex-sharing network of distorted (MnO6)-O-III octahedra, SeO3 and HSeO3 pyramids and unusual Li(OH)(6) octahedra, resulting in a dense three-dimensional structure. Mn, Li and one Se atom have site symmetries of (1) over bar, (3) over bar, and 3, respectively. An O - H center dot center dot center dot O hydrogen bond helps to establish the crystal packing.

AB - The title compound, lithium trimanganese bis[trioxoselenate(IV)] hexakis[hydrogentrioxoselenate(IV)], is built up from a vertex-sharing network of distorted (MnO6)-O-III octahedra, SeO3 and HSeO3 pyramids and unusual Li(OH)(6) octahedra, resulting in a dense three-dimensional structure. Mn, Li and one Se atom have site symmetries of (1) over bar, (3) over bar, and 3, respectively. An O - H center dot center dot center dot O hydrogen bond helps to establish the crystal packing.

KW - crystal-structures

KW - selenites

KW - program

KW - bond

U2 - 10.1107/S0108270107001588

DO - 10.1107/S0108270107001588

M3 - Article

VL - 63

SP - i28-i30

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

IS - 4

ER -

LiMn3(SeO3)(2)(HSeO3)(6)

Abstract

Keywords

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