Li(VO2)3(TeO3)2

Magnus George Johnston; William T. A. Harrison

doi:10.1107/S010827010702954X

Li(VO2)3(TeO3)2

Magnus George Johnston, William T. A. Harrison

Chemistry

Research output: Contribution to journal › Article

17 Citations (Scopus)

Abstract

The title compound, lithium tris[dioxidovanadium(V)] bis[trioxidotellurium(IV)], contains chains of edge-sharing distorted VO₆ octahedra. The pyramidal TeO₃ groups crosslink the chains into sheets. Finally, an Li⁺ cation adopting an unusual capped trigonal-bipyramidal LiO₆ geometry bridges the layers to complete a three-dimensional structure.

Original language	English
Pages (from-to)	i57-i59
Number of pages	3
Journal	Acta Crystallographica Section C, Crystal Structure Communications
Volume	63
Issue number	8
DOIs	https://doi.org/10.1107/S010827010702954X
Publication status	Published - Aug 2007

Keywords

crystal-structure
valence
phosphate
MN
NI
CO

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Cite this

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title = "Li(VO2)3(TeO3)2",

abstract = "The title compound, lithium tris[dioxidovanadium(V)] bis[trioxidotellurium(IV)], contains chains of edge-sharing distorted VO6 octahedra. The pyramidal TeO3 groups crosslink the chains into sheets. Finally, an Li+ cation adopting an unusual capped trigonal-bipyramidal LiO6 geometry bridges the layers to complete a three-dimensional structure.",

keywords = "crystal-structure, valence, phosphate, MN, NI, CO",

author = "Johnston, {Magnus George} and Harrison, {William T. A.}",

year = "2007",

month = aug,

doi = "10.1107/S010827010702954X",

language = "English",

volume = "63",

pages = "i57--i59",

journal = "Acta Crystallographica Section C, Crystal Structure Communications",

issn = "0108-2701",

publisher = "Wiley-Blackwell ",

number = "8",

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TY - JOUR

T1 - Li(VO2)3(TeO3)2

AU - Johnston, Magnus George

AU - Harrison, William T. A.

PY - 2007/8

Y1 - 2007/8

N2 - The title compound, lithium tris[dioxidovanadium(V)] bis[trioxidotellurium(IV)], contains chains of edge-sharing distorted VO6 octahedra. The pyramidal TeO3 groups crosslink the chains into sheets. Finally, an Li+ cation adopting an unusual capped trigonal-bipyramidal LiO6 geometry bridges the layers to complete a three-dimensional structure.

AB - The title compound, lithium tris[dioxidovanadium(V)] bis[trioxidotellurium(IV)], contains chains of edge-sharing distorted VO6 octahedra. The pyramidal TeO3 groups crosslink the chains into sheets. Finally, an Li+ cation adopting an unusual capped trigonal-bipyramidal LiO6 geometry bridges the layers to complete a three-dimensional structure.

KW - crystal-structure

KW - valence

KW - phosphate

KW - MN

KW - NI

KW - CO

U2 - 10.1107/S010827010702954X

DO - 10.1107/S010827010702954X

M3 - Article

SN - 0108-2701

VL - 63

SP - i57-i59

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

IS - 8

ER -

Li(VO2)3(TeO3)2

Abstract

Keywords

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