Methane adsorption constrained by pore structure in high rank coals using FESEM, CO2 adsorption and NMRC techniques

Tingting Yin, Dameng Liu, Yidong Cai (Corresponding Author), Yingfang Zhou

Research output: Contribution to journalArticle

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Abstract

To evaluate the impacts of nanopores of high-rank coals on coalbed methane adsorption and storage, 12 anthracite and semianthracite coal samples from Yangquan and Shouyang blocks in the Qinshui Basin were investigated. Field emission scanning electron microscopy (FESEM) and CO2 adsorption combined with nuclear magnetic resonance cryoporometry (NMRC) experiments were used to evaluate the pore structure with diameters ranging from 0 to 500 nm and their impact on adsorption capacity based on qualitative and quantitative analysis. The results show that a coalification jump from semianthracite to anthracite occurred in the study area due to the magmatic intrusion. In the process, the volume of supermicropores and micropores largely increased while the volume of transition pores and mesopores decreased slightly. Additionally, vitrinite gets purified and enriched during the rapid maturation of coal reservoir, which is beneficial to the microporous structure development. The pore size distribution (PSD) of anthracite is mainly divided into two types, which are in serrated and decreasing forms, respectively. Higher vitrinite content can promote the formation of decreasing type (type II), which corresponds to a lower degree of complexity. The fractal dimensions indicate that the heterogeneity of coal samples is increasing with the decrease in pore size. Accordingly, the increase in pore heterogeneity corresponds to the lower adsorption capacity. The main pore sizes that contribute to CBM adsorption include two parts: 25-30 nm and 50-60 nm. For the supermicropores with large specific surface areas, the pore system detected by CO2 molecules is not conducive to CBM adsorption, while the increase in pore volume can improve the adsorption rate and capacity of CO2. These findings are vital for a precisely understanding of nanoscale pores as well as future CBM exploitation.
Original languageEnglish
Pages (from-to)255-271
Number of pages17
JournalEnergy Science & Engineering
Volume7
Issue number1
Early online date15 Jan 2019
DOIs
Publication statusPublished - Feb 2019

Fingerprint

coal rank
nuclear magnetic resonance
methane
scanning electron microscopy
adsorption
anthracite
vitrinite
coal
coalification
coalbed methane
qualitative analysis
quantitative analysis
maturation
surface area
basin

Keywords

  • coalbed methane
  • DFT theory
  • experiment method
  • fractal dimension
  • magmatic intrusion
  • Coalbed methane

Cite this

Methane adsorption constrained by pore structure in high rank coals using FESEM, CO2 adsorption and NMRC techniques. / Yin, Tingting; Liu, Dameng; Cai, Yidong (Corresponding Author); Zhou, Yingfang.

In: Energy Science & Engineering, Vol. 7, No. 1, 02.2019, p. 255-271.

Research output: Contribution to journalArticle

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abstract = "To evaluate the impacts of nanopores of high-rank coals on coalbed methane adsorption and storage, 12 anthracite and semianthracite coal samples from Yangquan and Shouyang blocks in the Qinshui Basin were investigated. Field emission scanning electron microscopy (FESEM) and CO2 adsorption combined with nuclear magnetic resonance cryoporometry (NMRC) experiments were used to evaluate the pore structure with diameters ranging from 0 to 500 nm and their impact on adsorption capacity based on qualitative and quantitative analysis. The results show that a coalification jump from semianthracite to anthracite occurred in the study area due to the magmatic intrusion. In the process, the volume of supermicropores and micropores largely increased while the volume of transition pores and mesopores decreased slightly. Additionally, vitrinite gets purified and enriched during the rapid maturation of coal reservoir, which is beneficial to the microporous structure development. The pore size distribution (PSD) of anthracite is mainly divided into two types, which are in serrated and decreasing forms, respectively. Higher vitrinite content can promote the formation of decreasing type (type II), which corresponds to a lower degree of complexity. The fractal dimensions indicate that the heterogeneity of coal samples is increasing with the decrease in pore size. Accordingly, the increase in pore heterogeneity corresponds to the lower adsorption capacity. The main pore sizes that contribute to CBM adsorption include two parts: 25-30 nm and 50-60 nm. For the supermicropores with large specific surface areas, the pore system detected by CO2 molecules is not conducive to CBM adsorption, while the increase in pore volume can improve the adsorption rate and capacity of CO2. These findings are vital for a precisely understanding of nanoscale pores as well as future CBM exploitation.",
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author = "Tingting Yin and Dameng Liu and Yidong Cai and Yingfang Zhou",
note = "This research was funded by the National Natural Science Fund (grant nos. 41830427, 41772160 and 41602170), the National Major Research Program for Science and Technology of China (grant no. 2016ZX05043-001), Key Research and Development Projects of The Xinjiang Uygur Autonomous Region (grant no. 2017B03019-01) and the Fundamental Research Funds for Central Universities (grant no. 2652018002).",
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