Mixed-metal coordination networks constructed from Hg(CN)2 rods and Hg⋯Naz (az = azide) secondary interactions: Syntheses and structures of Hg(CN)2·(N3)2· Cu(C5H5N)2 and NaHg(CN)2· (N3)2·Cu(N3)

William T.A. Harrison; null Ejaz; Islam Ullah Khan

doi:10.1016/j.poly.2011.05.049

Mixed-metal coordination networks constructed from Hg(CN)₂ rods and Hg⋯N_az (az = azide) secondary interactions: Syntheses and structures of Hg(CN)₂·(N₃)₂· Cu(C₅H₅N)₂ and NaHg(CN)₂· (N₃)₂·Cu(N₃)

William T.A. Harrison^*, Ejaz, Islam Ullah Khan

^*Corresponding author for this work

Chemistry

Government College University Lahore

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The syntheses and crystal structures of Hg(CN)₂·(N ₃)₂·Cu(C₅H₅N)₂ (1) and NaHg(CN)₂·(N₃)₂·Cu(N ₃)(C₃H₁₀N₂)₂ (2) are reported. The interplay between linear Hg(CN)₂ and N3- building units by way of long Hg⋯N secondary interactions leads to new types of hybrid inorganic-organic networks in these phases.

Original language	English
Pages (from-to)	2181-2185
Number of pages	5
Journal	Polyhedron
Volume	30
Issue number	13
DOIs	https://doi.org/10.1016/j.poly.2011.05.049
Publication status	Published - 23 Aug 2011

Keywords

Azide anion
Coordination network
Crystal structure
Mercury

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10.1016/j.poly.2011.05.049

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Mixed-metal coordination networks constructed from Hg(CN)₂ rods and Hg⋯N_az (az = azide) secondary interactions: Syntheses and structures of Hg(CN)₂·(N₃)₂· Cu(C₅H₅N)₂ and NaHg(CN)₂· (N₃)₂·Cu(N₃). / Harrison, William T.A.; Ejaz; Khan, Islam Ullah.
In: Polyhedron, Vol. 30, No. 13, 23.08.2011, p. 2181-2185.

Research output: Contribution to journal › Article › peer-review

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abstract = "The syntheses and crystal structures of Hg(CN)2·(N 3)2·Cu(C5H5N)2 (1) and NaHg(CN)2·(N3)2·Cu(N 3)(C3H10N2)2 (2) are reported. The interplay between linear Hg(CN)2 and N3- building units by way of long Hg⋯N secondary interactions leads to new types of hybrid inorganic-organic networks in these phases.",

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AU - Harrison, William T.A.

AU - Ejaz, null

AU - Khan, Islam Ullah

PY - 2011/8/23

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N2 - The syntheses and crystal structures of Hg(CN)2·(N 3)2·Cu(C5H5N)2 (1) and NaHg(CN)2·(N3)2·Cu(N 3)(C3H10N2)2 (2) are reported. The interplay between linear Hg(CN)2 and N3- building units by way of long Hg⋯N secondary interactions leads to new types of hybrid inorganic-organic networks in these phases.

AB - The syntheses and crystal structures of Hg(CN)2·(N 3)2·Cu(C5H5N)2 (1) and NaHg(CN)2·(N3)2·Cu(N 3)(C3H10N2)2 (2) are reported. The interplay between linear Hg(CN)2 and N3- building units by way of long Hg⋯N secondary interactions leads to new types of hybrid inorganic-organic networks in these phases.

KW - Azide anion

KW - Coordination network

KW - Crystal structure

KW - Mercury

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DO - 10.1016/j.poly.2011.05.049

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ER -

Mixed-metal coordination networks constructed from Hg(CN)₂ rods and Hg⋯N_az (az = azide) secondary interactions: Syntheses and structures of Hg(CN)₂·(N₃)₂· Cu(C₅H₅N)₂ and NaHg(CN)₂· (N₃)₂·Cu(N₃)

Abstract

Keywords

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