TY - JOUR
T1 - mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amino]methyl}phenolato)dinickel(II) chloride
AU - Tiekink, Edward R. T.
AU - Wardell, James L.
AU - Fernandes, Christiane
AU - Horn, Adolfo
AU - Skakle, Jan
PY - 2010/5
Y1 - 2010/5
N2 - The title salt, [Ni-2(C16H18ClN2O2)(2)(CH3COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyridine N and hydroxy O atoms of the 2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl) amino]methyl} phenolate ligand which is, therefore, pentadentate. The resultant N3O3 donor sets define octahedral coordination geometries. The chloride counter-anion is connected to the cation via two Ohydroxy-H center dot center dot center dot Cl hydrogen bonds.
AB - The title salt, [Ni-2(C16H18ClN2O2)(2)(CH3COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyridine N and hydroxy O atoms of the 2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl) amino]methyl} phenolate ligand which is, therefore, pentadentate. The resultant N3O3 donor sets define octahedral coordination geometries. The chloride counter-anion is connected to the cation via two Ohydroxy-H center dot center dot center dot Cl hydrogen bonds.
KW - single crystal structure analysis
U2 - 10.1107/S160053681001442X
DO - 10.1107/S160053681001442X
M3 - Article
SN - 1600-5368
VL - 66
SP - m566-,567
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
ER -