mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amino]methyl}phenolato)dinickel(II) chloride

Edward R. T. Tiekink, James L. Wardell, Christiane Fernandes, Adolfo Horn, Jan Skakle

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Abstract

The title salt, [Ni-2(C16H18ClN2O2)(2)(CH3COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyridine N and hydroxy O atoms of the 2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl) amino]methyl} phenolate ligand which is, therefore, pentadentate. The resultant N3O3 donor sets define octahedral coordination geometries. The chloride counter-anion is connected to the cation via two Ohydroxy-H center dot center dot center dot Cl hydrogen bonds.

Original languageEnglish
Pages (from-to)m566-,567
Number of pages15
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
DOIs
Publication statusPublished - May 2010

Keywords

  • single crystal structure analysis

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