N-[4-(4-Chlorobenzenesulfonamido)-phenylsulfonyl]acetamide

Islam Ullah Khan*, Ejaz, Sidra Farid, William Thomas Alexander Harrison

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

In the title compound, C14H13ClN2O 5S2, the dihedral angles between the central benzene ring and the pendant chlorobenzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the molecule approximates to a U shape. Both the C - S - N - C conformations are gauche, but with opposite senses [torsion angles = -59.29 (15) and 63.68 (16)°]. An intramolecular C - H⋯O interaction generates an S(6) ring. In the crystal, inversion dimers linked by pairs of N - H⋯O hydrogen bonds generate R2 2(20) loops. A second N - H⋯O hydrogen bond links the dimers into (101) layers.

Original languageEnglish
Article numbero1913
Number of pages8
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number6
Early online dateJun 2012
DOIs
Publication statusPublished - Jun 2012

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Dimers
Conformations
Hydrogen bonds
rings
Dihedral angle
Benzene
dimers
Torsional stress
hydrogen bonds
chlorobenzenes
Crystals
Molecules
torsion
dihedral angle
benzene
inversions
crystals
acetamide
molecules
interactions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

N-[4-(4-Chlorobenzenesulfonamido)-phenylsulfonyl]acetamide. / Khan, Islam Ullah; Ejaz; Farid, Sidra; Harrison, William Thomas Alexander.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, No. 6, o1913, 06.2012.

Research output: Contribution to journalArticle

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