New BaM2(SeO3)3·nH2O (M = Co, Ni, Mn, Mg;n ≈3) Zemannite-type frameworks: single-crystal structures of BaCo2(SeO3)3·3H2O, BaMn2(SeO3)3·3H2O and BaMg2(SeO3)3·3H2O

Magnus G. Johnston, William T. A. Harrison

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The syntheses and characterisation of a new family of isostructural mixed-metal selenites based on the zemannite-type framework are described. These BaM2(SeO3)3·3H2O phases are built up from three-dimensional networks of MO6 (M = Co, Ni, Mn, Mg) octahedra and SeO3 pyramids. The octahedral groups form isolated M2O9 face-sharing pairs, which are linked by the selenite anions into a three-dimensional anionic framework. The framework encapsulates one-dimensional 12-ring channels occupied by the barium cations and water molecules. There are two types of channels: in one, the cations and water molecules are well ordered, and the channels are fully occupied; in the other, the same species are disordered, and the channels are partially occupied. There is little if any evidence of zeolitic reversible de/rehydration and cation ion-exchange behaviour for these materials.
Original languageEnglish
Pages (from-to)2967-2974
Number of pages8
JournalEuropean Journal of Inorganic Chemistry
Volume2011
Issue number19
Early online date19 May 2011
DOIs
Publication statusPublished - 1 Jul 2011

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Selenious Acid
Cations
Crystal structure
Single crystals
Molecules
Water
Barium
Anions
Ion exchange
Metals

Keywords

  • open frameworks
  • zeolite analogues
  • zemannite
  • selenium
  • ion exchange

Cite this

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title = "New BaM2(SeO3)3·nH2O (M = Co, Ni, Mn, Mg;n ≈3) Zemannite-type frameworks: single-crystal structures of BaCo2(SeO3)3·3H2O, BaMn2(SeO3)3·3H2O and BaMg2(SeO3)3·3H2O",
abstract = "The syntheses and characterisation of a new family of isostructural mixed-metal selenites based on the zemannite-type framework are described. These BaM2(SeO3)3·3H2O phases are built up from three-dimensional networks of MO6 (M = Co, Ni, Mn, Mg) octahedra and SeO3 pyramids. The octahedral groups form isolated M2O9 face-sharing pairs, which are linked by the selenite anions into a three-dimensional anionic framework. The framework encapsulates one-dimensional 12-ring channels occupied by the barium cations and water molecules. There are two types of channels: in one, the cations and water molecules are well ordered, and the channels are fully occupied; in the other, the same species are disordered, and the channels are partially occupied. There is little if any evidence of zeolitic reversible de/rehydration and cation ion-exchange behaviour for these materials.",
keywords = "open frameworks, zeolite analogues, zemannite, selenium, ion exchange",
author = "Johnston, {Magnus G.} and Harrison, {William T. A.}",
year = "2011",
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doi = "10.1002/ejic.201100344",
language = "English",
volume = "2011",
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TY - JOUR

T1 - New BaM2(SeO3)3·nH2O (M = Co, Ni, Mn, Mg;n ≈3) Zemannite-type frameworks

T2 - single-crystal structures of BaCo2(SeO3)3·3H2O, BaMn2(SeO3)3·3H2O and BaMg2(SeO3)3·3H2O

AU - Johnston, Magnus G.

AU - Harrison, William T. A.

PY - 2011/7/1

Y1 - 2011/7/1

N2 - The syntheses and characterisation of a new family of isostructural mixed-metal selenites based on the zemannite-type framework are described. These BaM2(SeO3)3·3H2O phases are built up from three-dimensional networks of MO6 (M = Co, Ni, Mn, Mg) octahedra and SeO3 pyramids. The octahedral groups form isolated M2O9 face-sharing pairs, which are linked by the selenite anions into a three-dimensional anionic framework. The framework encapsulates one-dimensional 12-ring channels occupied by the barium cations and water molecules. There are two types of channels: in one, the cations and water molecules are well ordered, and the channels are fully occupied; in the other, the same species are disordered, and the channels are partially occupied. There is little if any evidence of zeolitic reversible de/rehydration and cation ion-exchange behaviour for these materials.

AB - The syntheses and characterisation of a new family of isostructural mixed-metal selenites based on the zemannite-type framework are described. These BaM2(SeO3)3·3H2O phases are built up from three-dimensional networks of MO6 (M = Co, Ni, Mn, Mg) octahedra and SeO3 pyramids. The octahedral groups form isolated M2O9 face-sharing pairs, which are linked by the selenite anions into a three-dimensional anionic framework. The framework encapsulates one-dimensional 12-ring channels occupied by the barium cations and water molecules. There are two types of channels: in one, the cations and water molecules are well ordered, and the channels are fully occupied; in the other, the same species are disordered, and the channels are partially occupied. There is little if any evidence of zeolitic reversible de/rehydration and cation ion-exchange behaviour for these materials.

KW - open frameworks

KW - zeolite analogues

KW - zemannite

KW - selenium

KW - ion exchange

U2 - 10.1002/ejic.201100344

DO - 10.1002/ejic.201100344

M3 - Article

VL - 2011

SP - 2967

EP - 2974

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 19

ER -