New Framework Connectivity Patterns in Templated Networks: The Creatinine Zinc Phosphites C4N3OH7·ZnHPO3, C4N3OH7·Zn(H2O)HPO3 and (C4N3OH7)2·ZnHPO3·H2O

William Thomas Alexander Harrison, R. M. Yeates, M. L. F. Phillips, T. M. Nenoff

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

The syntheses, crystal structures, and properties of C4N3OH7.ZnHPO3, C4N3OH7.Zn(H2O)HPO3, and (C4N3OH7)(2). ZnHPO3.H2O are reported. These new creatinine zinc phosphites are built up from networks of vertex-sharing HPO3 pseudopyramids and various types of ZnO2N2, ZnO3N, and ZnO2N(H2O) tetrahedra, resulting in extended structures of different dimensionalities (as sheets, clusters, and chains, respectively). They demonstrate the structural effect of incorporating "terminal" (nonnetworking) Zn-N and Zn-OH2 moieties into zinc centers. Crystal data: C4N3OH7.ZnHPO3, triclinic, P1 (No. 2), a = 8.9351(4) Angstrom, b = 9.5011(4) Angstrom, c = 9.9806(4) Angstrom, alpha = 87.451(1)degrees, beta = 85.686(1)degrees, gamma = 89.551(1)degrees, Z = 4; C4N3OH7.Zn(H2O)HPO3, monoclinic, P2(1)/c (No. 14), a = 10.1198(7) Angstrom, b = 7.2996(5) Angstrom, c = 13.7421(9) Angstrom, beta = 107.522(1)degrees, Z = 4; (C4N3OH7)(2).ZnHPO3.H2O, triclinic, P1 (No. 2), a = 10.7289(6) Angstrom, b = 10.9051(6)Angstrom, c = 13.9881(8) Angstrom, alpha = 89.508(1)degrees, beta = 74.995(1)degrees, gamma = 74.932(1)degrees, Z = 4.

Original languageEnglish
Pages (from-to)1493-1498
Number of pages5
JournalInorganic Chemistry
Volume42
DOIs
Publication statusPublished - 2003

Keywords

  • HYDROTHERMAL SYNTHESIS
  • BUILT-UP
  • PHOSPHATES
  • TETRAHEDRA
  • CLUSTER
  • SOLIDS

Cite this

New Framework Connectivity Patterns in Templated Networks: The Creatinine Zinc Phosphites C4N3OH7·ZnHPO3, C4N3OH7·Zn(H2O)HPO3 and (C4N3OH7)2·ZnHPO3·H2O. / Harrison, William Thomas Alexander; Yeates, R. M.; Phillips, M. L. F.; Nenoff, T. M.

In: Inorganic Chemistry, Vol. 42, 2003, p. 1493-1498.

Research output: Contribution to journalArticle

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title = "New Framework Connectivity Patterns in Templated Networks: The Creatinine Zinc Phosphites C4N3OH7·ZnHPO3, C4N3OH7·Zn(H2O)HPO3 and (C4N3OH7)2·ZnHPO3·H2O",
abstract = "The syntheses, crystal structures, and properties of C4N3OH7.ZnHPO3, C4N3OH7.Zn(H2O)HPO3, and (C4N3OH7)(2). ZnHPO3.H2O are reported. These new creatinine zinc phosphites are built up from networks of vertex-sharing HPO3 pseudopyramids and various types of ZnO2N2, ZnO3N, and ZnO2N(H2O) tetrahedra, resulting in extended structures of different dimensionalities (as sheets, clusters, and chains, respectively). They demonstrate the structural effect of incorporating {"}terminal{"} (nonnetworking) Zn-N and Zn-OH2 moieties into zinc centers. Crystal data: C4N3OH7.ZnHPO3, triclinic, P1 (No. 2), a = 8.9351(4) Angstrom, b = 9.5011(4) Angstrom, c = 9.9806(4) Angstrom, alpha = 87.451(1)degrees, beta = 85.686(1)degrees, gamma = 89.551(1)degrees, Z = 4; C4N3OH7.Zn(H2O)HPO3, monoclinic, P2(1)/c (No. 14), a = 10.1198(7) Angstrom, b = 7.2996(5) Angstrom, c = 13.7421(9) Angstrom, beta = 107.522(1)degrees, Z = 4; (C4N3OH7)(2).ZnHPO3.H2O, triclinic, P1 (No. 2), a = 10.7289(6) Angstrom, b = 10.9051(6)Angstrom, c = 13.9881(8) Angstrom, alpha = 89.508(1)degrees, beta = 74.995(1)degrees, gamma = 74.932(1)degrees, Z = 4.",
keywords = "HYDROTHERMAL SYNTHESIS, BUILT-UP, PHOSPHATES, TETRAHEDRA, CLUSTER, SOLIDS",
author = "Harrison, {William Thomas Alexander} and Yeates, {R. M.} and Phillips, {M. L. F.} and Nenoff, {T. M.}",
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T1 - New Framework Connectivity Patterns in Templated Networks: The Creatinine Zinc Phosphites C4N3OH7·ZnHPO3, C4N3OH7·Zn(H2O)HPO3 and (C4N3OH7)2·ZnHPO3·H2O

AU - Harrison, William Thomas Alexander

AU - Yeates, R. M.

AU - Phillips, M. L. F.

AU - Nenoff, T. M.

PY - 2003

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N2 - The syntheses, crystal structures, and properties of C4N3OH7.ZnHPO3, C4N3OH7.Zn(H2O)HPO3, and (C4N3OH7)(2). ZnHPO3.H2O are reported. These new creatinine zinc phosphites are built up from networks of vertex-sharing HPO3 pseudopyramids and various types of ZnO2N2, ZnO3N, and ZnO2N(H2O) tetrahedra, resulting in extended structures of different dimensionalities (as sheets, clusters, and chains, respectively). They demonstrate the structural effect of incorporating "terminal" (nonnetworking) Zn-N and Zn-OH2 moieties into zinc centers. Crystal data: C4N3OH7.ZnHPO3, triclinic, P1 (No. 2), a = 8.9351(4) Angstrom, b = 9.5011(4) Angstrom, c = 9.9806(4) Angstrom, alpha = 87.451(1)degrees, beta = 85.686(1)degrees, gamma = 89.551(1)degrees, Z = 4; C4N3OH7.Zn(H2O)HPO3, monoclinic, P2(1)/c (No. 14), a = 10.1198(7) Angstrom, b = 7.2996(5) Angstrom, c = 13.7421(9) Angstrom, beta = 107.522(1)degrees, Z = 4; (C4N3OH7)(2).ZnHPO3.H2O, triclinic, P1 (No. 2), a = 10.7289(6) Angstrom, b = 10.9051(6)Angstrom, c = 13.9881(8) Angstrom, alpha = 89.508(1)degrees, beta = 74.995(1)degrees, gamma = 74.932(1)degrees, Z = 4.

AB - The syntheses, crystal structures, and properties of C4N3OH7.ZnHPO3, C4N3OH7.Zn(H2O)HPO3, and (C4N3OH7)(2). ZnHPO3.H2O are reported. These new creatinine zinc phosphites are built up from networks of vertex-sharing HPO3 pseudopyramids and various types of ZnO2N2, ZnO3N, and ZnO2N(H2O) tetrahedra, resulting in extended structures of different dimensionalities (as sheets, clusters, and chains, respectively). They demonstrate the structural effect of incorporating "terminal" (nonnetworking) Zn-N and Zn-OH2 moieties into zinc centers. Crystal data: C4N3OH7.ZnHPO3, triclinic, P1 (No. 2), a = 8.9351(4) Angstrom, b = 9.5011(4) Angstrom, c = 9.9806(4) Angstrom, alpha = 87.451(1)degrees, beta = 85.686(1)degrees, gamma = 89.551(1)degrees, Z = 4; C4N3OH7.Zn(H2O)HPO3, monoclinic, P2(1)/c (No. 14), a = 10.1198(7) Angstrom, b = 7.2996(5) Angstrom, c = 13.7421(9) Angstrom, beta = 107.522(1)degrees, Z = 4; (C4N3OH7)(2).ZnHPO3.H2O, triclinic, P1 (No. 2), a = 10.7289(6) Angstrom, b = 10.9051(6)Angstrom, c = 13.9881(8) Angstrom, alpha = 89.508(1)degrees, beta = 74.995(1)degrees, gamma = 74.932(1)degrees, Z = 4.

KW - HYDROTHERMAL SYNTHESIS

KW - BUILT-UP

KW - PHOSPHATES

KW - TETRAHEDRA

KW - CLUSTER

KW - SOLIDS

U2 - 10.1021/ic020593+

DO - 10.1021/ic020593+

M3 - Article

VL - 42

SP - 1493

EP - 1498

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

ER -