(Nitrato-kappa O-2,O ')bis(triethanolamine-kappa N-4,O,O ',O)lanthanum(III) dinitrate

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Abstract

The title compound, [La(NO3)(C6H15NO3)(2)](NO3)(2), contains a network of [La(NO3)(C6H15NO3)(2)](2+) cations and nitrate counter-ions. The crystal packing is influenced by cation-to-anion O-H center dot center dot center dot O hydrogen bonds, resulting in a structure with one-dimensional character. The ten-coordinate La atom and a nitrate anion have site symmetry 2. The fact that triethanolamine can bind to such diverse cations as Li+ and La3+ militates against possible applications that require selective binding of ligand to metal.

Original languageEnglish
Pages (from-to)m232-m233
Number of pages2
JournalActa Crystallographica Section C, Crystal Structure Communications
VolumeC62
Issue number6
DOIs
Publication statusPublished - Jun 2006

Keywords

  • tetradentate triethanolamine ligands
  • crystal structure
  • complex
  • saccharinate

Cite this

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title = "(Nitrato-kappa O-2,O ')bis(triethanolamine-kappa N-4,O,O ',O)lanthanum(III) dinitrate",
abstract = "The title compound, [La(NO3)(C6H15NO3)(2)](NO3)(2), contains a network of [La(NO3)(C6H15NO3)(2)](2+) cations and nitrate counter-ions. The crystal packing is influenced by cation-to-anion O-H center dot center dot center dot O hydrogen bonds, resulting in a structure with one-dimensional character. The ten-coordinate La atom and a nitrate anion have site symmetry 2. The fact that triethanolamine can bind to such diverse cations as Li+ and La3+ militates against possible applications that require selective binding of ligand to metal.",
keywords = "tetradentate triethanolamine ligands, crystal structure, complex, saccharinate",
author = "A Fowkes and Harrison, {William Thomas Alexander}",
year = "2006",
month = "6",
doi = "10.1107/S0108270106011826",
language = "English",
volume = "C62",
pages = "m232--m233",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",
number = "6",

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TY - JOUR

T1 - (Nitrato-kappa O-2,O ')bis(triethanolamine-kappa N-4,O,O ',O)lanthanum(III) dinitrate

AU - Fowkes, A

AU - Harrison, William Thomas Alexander

PY - 2006/6

Y1 - 2006/6

N2 - The title compound, [La(NO3)(C6H15NO3)(2)](NO3)(2), contains a network of [La(NO3)(C6H15NO3)(2)](2+) cations and nitrate counter-ions. The crystal packing is influenced by cation-to-anion O-H center dot center dot center dot O hydrogen bonds, resulting in a structure with one-dimensional character. The ten-coordinate La atom and a nitrate anion have site symmetry 2. The fact that triethanolamine can bind to such diverse cations as Li+ and La3+ militates against possible applications that require selective binding of ligand to metal.

AB - The title compound, [La(NO3)(C6H15NO3)(2)](NO3)(2), contains a network of [La(NO3)(C6H15NO3)(2)](2+) cations and nitrate counter-ions. The crystal packing is influenced by cation-to-anion O-H center dot center dot center dot O hydrogen bonds, resulting in a structure with one-dimensional character. The ten-coordinate La atom and a nitrate anion have site symmetry 2. The fact that triethanolamine can bind to such diverse cations as Li+ and La3+ militates against possible applications that require selective binding of ligand to metal.

KW - tetradentate triethanolamine ligands

KW - crystal structure

KW - complex

KW - saccharinate

U2 - 10.1107/S0108270106011826

DO - 10.1107/S0108270106011826

M3 - Article

VL - C62

SP - m232-m233

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

IS - 6

ER -