Nitridation of MoO3/HZSM-5 and Fe-MoO3/HZSM-5

J. S. J. Hargreaves; R. F. Howe; D. McKay; E. Morrison; J. L. Rico; M. Stockenhuber

doi:10.1007/s11244-009-9288-z

Nitridation of MoO3/HZSM-5 and Fe-MoO3/HZSM-5

J. S. J. Hargreaves, R. F. Howe, D. McKay, E. Morrison, J. L. Rico, M. Stockenhuber

Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Thermal treatment and subsequent ammonolysis of MoO3/H-ZSM-5 is shown to be an effective means for the preparation of zeolite dispersed nitrided molybdenum species. However, it is unlikely that these species reflect the bulk structures formed by analogous treatment of bulk MoO3 precursor. The inclusion of low levels of Fe as a dopant does not produce any apparent effects on the Mo XPS spectra, although the amount of N incorporation is increased, and iron is shown to be reduced to Fe-0. FTIR studies evidence the migration of molybdenum oxo species into the zeolite at the temperatures employed.

Original language	English
Pages (from-to)	1559-1565
Number of pages	7
Journal	Topics in Catalysis
Volume	52
Issue number	11
DOIs	https://doi.org/10.1007/s11244-009-9288-z
Publication status	Published - Oct 2009

Keywords

nitride
zeolite
XPS
FTIR
ammonia-synthesis activity
cobalt molybdenum nitride
modified MO/HZSM-5
catalysts
methane
decomposition
conversion
reduction
benzene
naphthalene

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title = "Nitridation of MoO3/HZSM-5 and Fe-MoO3/HZSM-5",

abstract = "Thermal treatment and subsequent ammonolysis of MoO3/H-ZSM-5 is shown to be an effective means for the preparation of zeolite dispersed nitrided molybdenum species. However, it is unlikely that these species reflect the bulk structures formed by analogous treatment of bulk MoO3 precursor. The inclusion of low levels of Fe as a dopant does not produce any apparent effects on the Mo XPS spectra, although the amount of N incorporation is increased, and iron is shown to be reduced to Fe-0. FTIR studies evidence the migration of molybdenum oxo species into the zeolite at the temperatures employed.",

keywords = "nitride, zeolite, XPS, FTIR, ammonia-synthesis activity, cobalt molybdenum nitride, modified MO/HZSM-5, catalysts, methane, decomposition, conversion, reduction, benzene, naphthalene",

author = "Hargreaves, {J. S. J.} and Howe, {R. F.} and D. McKay and E. Morrison and Rico, {J. L.} and M. Stockenhuber",

year = "2009",

month = oct,

doi = "10.1007/s11244-009-9288-z",

language = "English",

volume = "52",

pages = "1559--1565",

journal = "Topics in Catalysis",

issn = "1572-9028",

publisher = "Springer Netherlands",

number = "11",

}

TY - JOUR

T1 - Nitridation of MoO3/HZSM-5 and Fe-MoO3/HZSM-5

AU - Hargreaves, J. S. J.

AU - Howe, R. F.

AU - McKay, D.

AU - Morrison, E.

AU - Rico, J. L.

AU - Stockenhuber, M.

PY - 2009/10

Y1 - 2009/10

N2 - Thermal treatment and subsequent ammonolysis of MoO3/H-ZSM-5 is shown to be an effective means for the preparation of zeolite dispersed nitrided molybdenum species. However, it is unlikely that these species reflect the bulk structures formed by analogous treatment of bulk MoO3 precursor. The inclusion of low levels of Fe as a dopant does not produce any apparent effects on the Mo XPS spectra, although the amount of N incorporation is increased, and iron is shown to be reduced to Fe-0. FTIR studies evidence the migration of molybdenum oxo species into the zeolite at the temperatures employed.

AB - Thermal treatment and subsequent ammonolysis of MoO3/H-ZSM-5 is shown to be an effective means for the preparation of zeolite dispersed nitrided molybdenum species. However, it is unlikely that these species reflect the bulk structures formed by analogous treatment of bulk MoO3 precursor. The inclusion of low levels of Fe as a dopant does not produce any apparent effects on the Mo XPS spectra, although the amount of N incorporation is increased, and iron is shown to be reduced to Fe-0. FTIR studies evidence the migration of molybdenum oxo species into the zeolite at the temperatures employed.

KW - nitride

KW - zeolite

KW - XPS

KW - FTIR

KW - ammonia-synthesis activity

KW - cobalt molybdenum nitride

KW - modified MO/HZSM-5

KW - catalysts

KW - methane

KW - decomposition

KW - conversion

KW - reduction

KW - benzene

KW - naphthalene

U2 - 10.1007/s11244-009-9288-z

DO - 10.1007/s11244-009-9288-z

M3 - Article

VL - 52

SP - 1559

EP - 1565

JO - Topics in Catalysis

JF - Topics in Catalysis

SN - 1572-9028

IS - 11

ER -

Nitridation of MoO3/HZSM-5 and Fe-MoO3/HZSM-5

Abstract

Keywords

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