N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1, 3-phenylenebis(methylene)]dibenzenesulfonamide

Tahir Ali Sheikh; null Ejaz; Islam Ullah Khan; William T A Harrison

doi:10.1107/S1600536811045478

N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1, 3-phenylenebis(methylene)]dibenzenesulfonamide

Tahir Ali Sheikh, Ejaz, Islam Ullah Khan^*, William T A Harrison

^*Corresponding author for this work

Chemistry

Government College University Lahore

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C₂₆H₂₄Cl₄N ₂O₄S₂, the dihedral angles between the central benzene ring and the pendant rings are 70.07 (12) and 59.07 (12)°. The equivalent angle between the pendant rings is 79.24 (12)°. Both sulfonamide groups lie to the same side of the central ring but the pendant chains have very different conformations, as indicated by their C-S-N-C torsion angles [104.66 (17) and -76.35 (19)°] and S-N-C-C torsion angles [129.61 (17) and 147.10 (17)°]. Both N atoms are close to planar (bond angle sums = 359.0 and 354.8°). In the crystal, inversion dimers are formed via a pair of weak C-H⋯O interactions which generate R₂ ²(22) loops.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	12
DOIs	https://doi.org/10.1107/S1600536811045478
Publication status	Published - 1 Dec 2011

Keywords

data-to-parameter ratio = 21.0
mean σ(C-C) = 0.004 Å
R factor = 0.044
single-crystal X-ray study
T = 296 K
wR factor = 0.122

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@article{e899660972e24a98bfdbd53812005304,

title = "N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1, 3-phenylenebis(methylene)]dibenzenesulfonamide",

abstract = "In the title compound, C26H24Cl4N 2O4S2, the dihedral angles between the central benzene ring and the pendant rings are 70.07 (12) and 59.07 (12)°. The equivalent angle between the pendant rings is 79.24 (12)°. Both sulfonamide groups lie to the same side of the central ring but the pendant chains have very different conformations, as indicated by their C-S-N-C torsion angles [104.66 (17) and -76.35 (19)°] and S-N-C-C torsion angles [129.61 (17) and 147.10 (17)°]. Both N atoms are close to planar (bond angle sums = 359.0 and 354.8°). In the crystal, inversion dimers are formed via a pair of weak C-H⋯O interactions which generate R2 2(22) loops.",

keywords = "data-to-parameter ratio = 21.0, mean σ(C-C) = 0.004 {\AA}, R factor = 0.044, single-crystal X-ray study, T = 296 K, wR factor = 0.122",

author = "Sheikh, {Tahir Ali} and Ejaz and Khan, {Islam Ullah} and Harrison, {William T A}",

year = "2011",

month = dec,

day = "1",

doi = "10.1107/S1600536811045478",

language = "English",

volume = "67",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1, 3-phenylenebis(methylene)]dibenzenesulfonamide

AU - Sheikh, Tahir Ali

AU - Ejaz, null

AU - Khan, Islam Ullah

AU - Harrison, William T A

PY - 2011/12/1

Y1 - 2011/12/1

N2 - In the title compound, C26H24Cl4N 2O4S2, the dihedral angles between the central benzene ring and the pendant rings are 70.07 (12) and 59.07 (12)°. The equivalent angle between the pendant rings is 79.24 (12)°. Both sulfonamide groups lie to the same side of the central ring but the pendant chains have very different conformations, as indicated by their C-S-N-C torsion angles [104.66 (17) and -76.35 (19)°] and S-N-C-C torsion angles [129.61 (17) and 147.10 (17)°]. Both N atoms are close to planar (bond angle sums = 359.0 and 354.8°). In the crystal, inversion dimers are formed via a pair of weak C-H⋯O interactions which generate R2 2(22) loops.

AB - In the title compound, C26H24Cl4N 2O4S2, the dihedral angles between the central benzene ring and the pendant rings are 70.07 (12) and 59.07 (12)°. The equivalent angle between the pendant rings is 79.24 (12)°. Both sulfonamide groups lie to the same side of the central ring but the pendant chains have very different conformations, as indicated by their C-S-N-C torsion angles [104.66 (17) and -76.35 (19)°] and S-N-C-C torsion angles [129.61 (17) and 147.10 (17)°]. Both N atoms are close to planar (bond angle sums = 359.0 and 354.8°). In the crystal, inversion dimers are formed via a pair of weak C-H⋯O interactions which generate R2 2(22) loops.

KW - data-to-parameter ratio = 21.0

KW - mean σ(C-C) = 0.004 Å

KW - R factor = 0.044

KW - single-crystal X-ray study

KW - T = 296 K

KW - wR factor = 0.122

UR - http://www.scopus.com/inward/record.url?scp=83155191049&partnerID=8YFLogxK

U2 - 10.1107/S1600536811045478

DO - 10.1107/S1600536811045478

M3 - Article

AN - SCOPUS:83155191049

SN - 1600-5368

VL - 67

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1, 3-phenylenebis(methylene)]dibenzenesulfonamide

Abstract

Keywords

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