Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate

Jun-Ying Li; William T. A. Harrison; Tian-Duo Li

doi:10.1107/S1600536807013888

Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate

Jun-Ying Li, William T. A. Harrison, Tian-Duo Li

Chemistry

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

The title compound, [Sn-4(CH3)(8)(C6H5N2O2)(4)O-2]center dot 6H(2)O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn2O2 ring. The Sn-atom coordination geometry might be regarded as very distorted SnO3C2 trigonal-bipyramidal or possibly as grossly distorted SnO3C2N octahedral. All the cluster non-H atoms, with the exception of the Sn-bonded methyl groups, lie on a mirror plane. Two of the water-molecule O atoms have m site symmetry; the other occupies a twofold rotation axis.

Original language	English
Pages (from-to)	m1246-m1248
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	5
DOIs	https://doi.org/10.1107/S1600536807013888
Publication status	Published - May 2007

Keywords

distannoxanes

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Li, J.-Y., Harrison, W. T. A., & Li, T.-D. (2007). Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate. Acta Crystallographica Section E: Structure Reports Online, 63(5), m1246-m1248. https://doi.org/10.1107/S1600536807013888

Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate. / Li, Jun-Ying; Harrison, William T. A.; Li, Tian-Duo.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 5, 05.2007, p. m1246-m1248.

Research output: Contribution to journal › Article

Li, J-Y, Harrison, WTA & Li, T-D 2007, 'Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate', Acta Crystallographica Section E: Structure Reports Online, vol. 63, no. 5, pp. m1246-m1248. https://doi.org/10.1107/S1600536807013888

Li JY, Harrison WTA, Li TD. Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate. Acta Crystallographica Section E: Structure Reports Online. 2007 May;63(5):m1246-m1248. doi: 10.1107/S1600536807013888

Li, Jun-Ying ; Harrison, William T. A. ; Li, Tian-Duo. / Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate. In: Acta Crystallographica Section E: Structure Reports Online. 2007 ; Vol. 63, No. 5. pp. m1246-m1248.

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title = "Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate",

abstract = "The title compound, [Sn-4(CH3)(8)(C6H5N2O2)(4)O-2]center dot 6H(2)O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn2O2 ring. The Sn-atom coordination geometry might be regarded as very distorted SnO3C2 trigonal-bipyramidal or possibly as grossly distorted SnO3C2N octahedral. All the cluster non-H atoms, with the exception of the Sn-bonded methyl groups, lie on a mirror plane. Two of the water-molecule O atoms have m site symmetry; the other occupies a twofold rotation axis.",

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T1 - Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate

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N2 - The title compound, [Sn-4(CH3)(8)(C6H5N2O2)(4)O-2]center dot 6H(2)O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn2O2 ring. The Sn-atom coordination geometry might be regarded as very distorted SnO3C2 trigonal-bipyramidal or possibly as grossly distorted SnO3C2N octahedral. All the cluster non-H atoms, with the exception of the Sn-bonded methyl groups, lie on a mirror plane. Two of the water-molecule O atoms have m site symmetry; the other occupies a twofold rotation axis.

AB - The title compound, [Sn-4(CH3)(8)(C6H5N2O2)(4)O-2]center dot 6H(2)O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn2O2 ring. The Sn-atom coordination geometry might be regarded as very distorted SnO3C2 trigonal-bipyramidal or possibly as grossly distorted SnO3C2N octahedral. All the cluster non-H atoms, with the exception of the Sn-bonded methyl groups, lie on a mirror plane. Two of the water-molecule O atoms have m site symmetry; the other occupies a twofold rotation axis.

KW - distannoxanes

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JO - Acta Crystallographica Section E: Structure Reports Online

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