Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate

Jun-Ying Li, William T. A. Harrison, Tian-Duo Li

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The title compound, [Sn-4(CH3)(8)(C6H5N2O2)(4)O-2]center dot 6H(2)O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn2O2 ring. The Sn-atom coordination geometry might be regarded as very distorted SnO3C2 trigonal-bipyramidal or possibly as grossly distorted SnO3C2N octahedral. All the cluster non-H atoms, with the exception of the Sn-bonded methyl groups, lie on a mirror plane. Two of the water-molecule O atoms have m site symmetry; the other occupies a twofold rotation axis.

Original languageEnglish
Pages (from-to)m1246-m1248
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number5
DOIs
Publication statusPublished - May 2007

Keywords

  • distannoxanes

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