Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate

Jun-Ying Li, William T. A. Harrison, Tian-Duo Li

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The title compound, [Sn-4(CH3)(8)(C6H5N2O2)(4)O-2]center dot 6H(2)O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn2O2 ring. The Sn-atom coordination geometry might be regarded as very distorted SnO3C2 trigonal-bipyramidal or possibly as grossly distorted SnO3C2N octahedral. All the cluster non-H atoms, with the exception of the Sn-bonded methyl groups, lie on a mirror plane. Two of the water-molecule O atoms have m site symmetry; the other occupies a twofold rotation axis.

Original languageEnglish
Pages (from-to)m1246-m1248
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number5
DOIs
Publication statusPublished - May 2007

Keywords

  • distannoxanes

Cite this

@article{5f7adb0bcb4e4e108c0f07692f3cebbd,
title = "Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate",
abstract = "The title compound, [Sn-4(CH3)(8)(C6H5N2O2)(4)O-2]center dot 6H(2)O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn2O2 ring. The Sn-atom coordination geometry might be regarded as very distorted SnO3C2 trigonal-bipyramidal or possibly as grossly distorted SnO3C2N octahedral. All the cluster non-H atoms, with the exception of the Sn-bonded methyl groups, lie on a mirror plane. Two of the water-molecule O atoms have m site symmetry; the other occupies a twofold rotation axis.",
keywords = "distannoxanes",
author = "Jun-Ying Li and Harrison, {William T. A.} and Tian-Duo Li",
year = "2007",
month = "5",
doi = "10.1107/S1600536807013888",
language = "English",
volume = "63",
pages = "m1246--m1248",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "5",

}

TY - JOUR

T1 - Octamethyl-1 kappa C-2,2 kappa C-2,3 kappa C-2,4 kappa C-2-bis(mu(2)-2-methylpyrazine-5-carboxylato)-1 : 2 kappa O-2 : O;3 : 4 kappa O-2 : O-bis(2-methylpyrazine-5-carboxylato)-1 kappa O,4 kappa O-di-mu(3)-oxido-1 : 2 : 3 kappa O-3 : O : O;2 : 3 : 4 kappa O-3 : O : O-tetratin(IV) hexa-hydrate

AU - Li, Jun-Ying

AU - Harrison, William T. A.

AU - Li, Tian-Duo

PY - 2007/5

Y1 - 2007/5

N2 - The title compound, [Sn-4(CH3)(8)(C6H5N2O2)(4)O-2]center dot 6H(2)O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn2O2 ring. The Sn-atom coordination geometry might be regarded as very distorted SnO3C2 trigonal-bipyramidal or possibly as grossly distorted SnO3C2N octahedral. All the cluster non-H atoms, with the exception of the Sn-bonded methyl groups, lie on a mirror plane. Two of the water-molecule O atoms have m site symmetry; the other occupies a twofold rotation axis.

AB - The title compound, [Sn-4(CH3)(8)(C6H5N2O2)(4)O-2]center dot 6H(2)O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn2O2 ring. The Sn-atom coordination geometry might be regarded as very distorted SnO3C2 trigonal-bipyramidal or possibly as grossly distorted SnO3C2N octahedral. All the cluster non-H atoms, with the exception of the Sn-bonded methyl groups, lie on a mirror plane. Two of the water-molecule O atoms have m site symmetry; the other occupies a twofold rotation axis.

KW - distannoxanes

U2 - 10.1107/S1600536807013888

DO - 10.1107/S1600536807013888

M3 - Article

VL - 63

SP - m1246-m1248

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 5

ER -