One-dimensional structures of manganese(II), copper(II) and cobalt(II) coordination complexes [Mn(II)(hfac)2L] (hfac = hexafluoroacetylacetonate anion; L = 4,4-bipyridyl), [Cu(II)(hfac)2L] (L = 1,3-dipyridylpropane or 4,4-bipyridyl-N,N'-dioxide) and [Co(II)(hfac)2L] (L = 4,4-bipyridyl-N,N'-dioxide)

M. John Plater; Mark R. Mark; Alexander M.Z. Slawin

doi:10.1016/S0020-1693(99)00511-3

One-dimensional structures of manganese(II), copper(II) and cobalt(II) coordination complexes [Mn(II)(hfac)₂L] (hfac = hexafluoroacetylacetonate anion; L = 4,4-bipyridyl), [Cu(II)(hfac)₂L] (L = 1,3-dipyridylpropane or 4,4-bipyridyl-N,N'-dioxide) and [Co(II)(hfac)₂L] (L = 4,4-bipyridyl-N,N'-dioxide)

M. John Plater, Mark R. Mark, Alexander M.Z. Slawin

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

Treatment of bis(hexafluoroacetylacetonato)diaquamanganese(II) [Mn(hfac)₂(H₂O)₂] with 4,4-bipyridyl gives cis-[Mn(II)(hfac)₂-(bipy)] (1), which forms zig-zag 1-D chains. The bipyridyl ligands coordinate to the Mn cations adopting a cis geometry with an N-Mn-N angle of 90°. Treatment of bis(hexafluoroacetylacetonato)diaquacopper(II) [Cu(hfac)₂(H₂O)₂] with 1,3-dipyridylpropane gives trans-[Cu(II)(hfac)₂(1,3-dipy)] (2), which forms 1-D chains that adopt a trans N-Cu-N angle of 180°. Treatment of [M(hfac)₂(H₂O)₂] (M = Co or Cu) with 4,4-bipyridyl-N,N'-dioxide gives trans-[Co(II)(hfac)₂(4,4-bipy-N,N'-dioxide)] (3) and trans-[Cu(II)(hfac)₂(4,4-bipy-N,N'-dioxide)] (4), respectively, which form isostructural linear chains with an O-M-O angle of 180°. (C) 2000 Elsevier Science S.A.

Original language	English
Pages (from-to)	132-136
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	303
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(99)00511-3
Publication status	Published - 15 May 2000

Bibliographical note

This research was supported by the Leverhulme Trust.

Keywords

Cobalt complexes
Copper complexes
Crystal structures
Manganese complexes
One-dimensional complexes

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10.1016/S0020-1693(99)00511-3

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Plater, M. J., Mark, M. R., & Slawin, A. M. Z. (2000). One-dimensional structures of manganese(II), copper(II) and cobalt(II) coordination complexes [Mn(II)(hfac)₂L] (hfac = hexafluoroacetylacetonate anion; L = 4,4-bipyridyl), [Cu(II)(hfac)₂L] (L = 1,3-dipyridylpropane or 4,4-bipyridyl-N,N'-dioxide) and [Co(II)(hfac)₂L] (L = 4,4-bipyridyl-N,N'-dioxide). Inorganica Chimica Acta, 303(1), 132-136. https://doi.org/10.1016/S0020-1693(99)00511-3

One-dimensional structures of manganese(II), copper(II) and cobalt(II) coordination complexes [Mn(II)(hfac)₂L] (hfac = hexafluoroacetylacetonate anion; L = 4,4-bipyridyl), [Cu(II)(hfac)₂L] (L = 1,3-dipyridylpropane or 4,4-bipyridyl-N,N'-dioxide) and [Co(II)(hfac)₂L] (L = 4,4-bipyridyl-N,N'-dioxide). / Plater, M. John; Mark, Mark R.; Slawin, Alexander M.Z.
In: Inorganica Chimica Acta, Vol. 303, No. 1, 15.05.2000, p. 132-136.

Research output: Contribution to journal › Article › peer-review

Plater, MJ, Mark, MR & Slawin, AMZ 2000, 'One-dimensional structures of manganese(II), copper(II) and cobalt(II) coordination complexes [Mn(II)(hfac)₂L] (hfac = hexafluoroacetylacetonate anion; L = 4,4-bipyridyl), [Cu(II)(hfac)₂L] (L = 1,3-dipyridylpropane or 4,4-bipyridyl-N,N'-dioxide) and [Co(II)(hfac)₂L] (L = 4,4-bipyridyl-N,N'-dioxide)', Inorganica Chimica Acta, vol. 303, no. 1, pp. 132-136. https://doi.org/10.1016/S0020-1693(99)00511-3

Plater MJ, Mark MR, Slawin AMZ. One-dimensional structures of manganese(II), copper(II) and cobalt(II) coordination complexes [Mn(II)(hfac)₂L] (hfac = hexafluoroacetylacetonate anion; L = 4,4-bipyridyl), [Cu(II)(hfac)₂L] (L = 1,3-dipyridylpropane or 4,4-bipyridyl-N,N'-dioxide) and [Co(II)(hfac)₂L] (L = 4,4-bipyridyl-N,N'-dioxide). Inorganica Chimica Acta. 2000 May 15;303(1):132-136. doi: 10.1016/S0020-1693(99)00511-3

Plater, M. John ; Mark, Mark R. ; Slawin, Alexander M.Z. / One-dimensional structures of manganese(II), copper(II) and cobalt(II) coordination complexes [Mn(II)(hfac)₂L] (hfac = hexafluoroacetylacetonate anion; L = 4,4-bipyridyl), [Cu(II)(hfac)₂L] (L = 1,3-dipyridylpropane or 4,4-bipyridyl-N,N'-dioxide) and [Co(II)(hfac)₂L] (L = 4,4-bipyridyl-N,N'-dioxide). In: Inorganica Chimica Acta. 2000 ; Vol. 303, No. 1. pp. 132-136.

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title = "One-dimensional structures of manganese(II), copper(II) and cobalt(II) coordination complexes [Mn(II)(hfac)2L] (hfac = hexafluoroacetylacetonate anion; L = 4,4-bipyridyl), [Cu(II)(hfac)2L] (L = 1,3-dipyridylpropane or 4,4-bipyridyl-N,N'-dioxide) and [Co(II)(hfac)2L] (L = 4,4-bipyridyl-N,N'-dioxide)",

abstract = "Treatment of bis(hexafluoroacetylacetonato)diaquamanganese(II) [Mn(hfac)2(H2O)2] with 4,4-bipyridyl gives cis-[Mn(II)(hfac)2-(bipy)] (1), which forms zig-zag 1-D chains. The bipyridyl ligands coordinate to the Mn cations adopting a cis geometry with an N-Mn-N angle of 90°. Treatment of bis(hexafluoroacetylacetonato)diaquacopper(II) [Cu(hfac)2(H2O)2] with 1,3-dipyridylpropane gives trans-[Cu(II)(hfac)2(1,3-dipy)] (2), which forms 1-D chains that adopt a trans N-Cu-N angle of 180°. Treatment of [M(hfac)2(H2O)2] (M = Co or Cu) with 4,4-bipyridyl-N,N'-dioxide gives trans-[Co(II)(hfac)2(4,4-bipy-N,N'-dioxide)] (3) and trans-[Cu(II)(hfac)2(4,4-bipy-N,N'-dioxide)] (4), respectively, which form isostructural linear chains with an O-M-O angle of 180°. (C) 2000 Elsevier Science S.A.",

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author = "Plater, {M. John} and Mark, {Mark R.} and Slawin, {Alexander M.Z.}",

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AU - Plater, M. John

AU - Mark, Mark R.

AU - Slawin, Alexander M.Z.

N1 - This research was supported by the Leverhulme Trust.

PY - 2000/5/15

Y1 - 2000/5/15

N2 - Treatment of bis(hexafluoroacetylacetonato)diaquamanganese(II) [Mn(hfac)2(H2O)2] with 4,4-bipyridyl gives cis-[Mn(II)(hfac)2-(bipy)] (1), which forms zig-zag 1-D chains. The bipyridyl ligands coordinate to the Mn cations adopting a cis geometry with an N-Mn-N angle of 90°. Treatment of bis(hexafluoroacetylacetonato)diaquacopper(II) [Cu(hfac)2(H2O)2] with 1,3-dipyridylpropane gives trans-[Cu(II)(hfac)2(1,3-dipy)] (2), which forms 1-D chains that adopt a trans N-Cu-N angle of 180°. Treatment of [M(hfac)2(H2O)2] (M = Co or Cu) with 4,4-bipyridyl-N,N'-dioxide gives trans-[Co(II)(hfac)2(4,4-bipy-N,N'-dioxide)] (3) and trans-[Cu(II)(hfac)2(4,4-bipy-N,N'-dioxide)] (4), respectively, which form isostructural linear chains with an O-M-O angle of 180°. (C) 2000 Elsevier Science S.A.

AB - Treatment of bis(hexafluoroacetylacetonato)diaquamanganese(II) [Mn(hfac)2(H2O)2] with 4,4-bipyridyl gives cis-[Mn(II)(hfac)2-(bipy)] (1), which forms zig-zag 1-D chains. The bipyridyl ligands coordinate to the Mn cations adopting a cis geometry with an N-Mn-N angle of 90°. Treatment of bis(hexafluoroacetylacetonato)diaquacopper(II) [Cu(hfac)2(H2O)2] with 1,3-dipyridylpropane gives trans-[Cu(II)(hfac)2(1,3-dipy)] (2), which forms 1-D chains that adopt a trans N-Cu-N angle of 180°. Treatment of [M(hfac)2(H2O)2] (M = Co or Cu) with 4,4-bipyridyl-N,N'-dioxide gives trans-[Co(II)(hfac)2(4,4-bipy-N,N'-dioxide)] (3) and trans-[Cu(II)(hfac)2(4,4-bipy-N,N'-dioxide)] (4), respectively, which form isostructural linear chains with an O-M-O angle of 180°. (C) 2000 Elsevier Science S.A.

KW - Cobalt complexes

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KW - Crystal structures

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KW - One-dimensional complexes

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