One-dimensional structures of nickel(II) and cobalt(II) coordination complexes {[ML2(H2O)(2)]I center dot L center dot H2O (ClO4)(2)} (M = Co or Ni; L=1,3-bis(4-pyridyl)propane)

M J Plater, M R S Foreman, T Gelbrich, M B Hursthouse

Research output: Contribution to journalArticle

Abstract

Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO4)(2) or Ni(II)(ClO4)(2) gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain an array of non-coordinated ligands are hydrogen bonded at each end to the ligated water molecules. (C) 2001 Elsevier Science B.V. All rights reserved.

Original languageEnglish
Pages (from-to)171-174
Number of pages4
JournalInorganica Chimica Acta
Volume318
Publication statusPublished - 2001

Keywords

  • crystal structure
  • nickel complexes
  • cobalt complexes
  • one-dimensional complexes
  • POLYMERS
  • CHANNELS
  • FRAMEWORK
  • CATIONS
  • SOLIDS

Cite this

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title = "One-dimensional structures of nickel(II) and cobalt(II) coordination complexes {[ML2(H2O)(2)]I center dot L center dot H2O (ClO4)(2)} (M = Co or Ni; L=1,3-bis(4-pyridyl)propane)",
abstract = "Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO4)(2) or Ni(II)(ClO4)(2) gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain an array of non-coordinated ligands are hydrogen bonded at each end to the ligated water molecules. (C) 2001 Elsevier Science B.V. All rights reserved.",
keywords = "crystal structure, nickel complexes, cobalt complexes, one-dimensional complexes, POLYMERS, CHANNELS, FRAMEWORK, CATIONS, SOLIDS",
author = "Plater, {M J} and Foreman, {M R S} and T Gelbrich and Hursthouse, {M B}",
year = "2001",
language = "English",
volume = "318",
pages = "171--174",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier BV",

}

TY - JOUR

T1 - One-dimensional structures of nickel(II) and cobalt(II) coordination complexes {[ML2(H2O)(2)]I center dot L center dot H2O (ClO4)(2)} (M = Co or Ni; L=1,3-bis(4-pyridyl)propane)

AU - Plater, M J

AU - Foreman, M R S

AU - Gelbrich, T

AU - Hursthouse, M B

PY - 2001

Y1 - 2001

N2 - Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO4)(2) or Ni(II)(ClO4)(2) gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain an array of non-coordinated ligands are hydrogen bonded at each end to the ligated water molecules. (C) 2001 Elsevier Science B.V. All rights reserved.

AB - Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO4)(2) or Ni(II)(ClO4)(2) gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain an array of non-coordinated ligands are hydrogen bonded at each end to the ligated water molecules. (C) 2001 Elsevier Science B.V. All rights reserved.

KW - crystal structure

KW - nickel complexes

KW - cobalt complexes

KW - one-dimensional complexes

KW - POLYMERS

KW - CHANNELS

KW - FRAMEWORK

KW - CATIONS

KW - SOLIDS

M3 - Article

VL - 318

SP - 171

EP - 174

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -