Optimisation of preparation method for Pd doped Cu/Al2O3 catalysts for selective acetylene hydrogenation

Alan J. McCue*, Ashley M. Shepherd, James A. Anderson

*Corresponding author for this work

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Pd doped Cu catalysts have been prepared by co-impregnation, sequential impregnation and a colloidal approach. In each case, the Cu:Pd ratio was optimised leading to catalyst activity which exceeded that offered by monometallic Cu at low temperature (393 K and below) but with a product selectivity which suggests the reaction is still taking place on a Cu surface (i.e., high ethylene selectivity). Pd is therefore thought to influence hydrogen dissociation rates and enhance spillover onto Cu sites. Catalytic testing under more demanding conditions showed differences between the preparation methods. In general, the most active of the samples appeared to be the least selective and vice-versa. Under optimised conditions, a 50:1 Cu:Pd ratio prepared by sequential impregnation showed an ethylene selectivity of 80% at 98% conversion at only 353 K. Further testing under competitive conditions suggested good ethylene selectivity could be retained under industrially relevant conditions in the absence of CO.

Original languageEnglish
Pages (from-to)2880-2890
Number of pages11
JournalCatalysis Science & Technology
Volume5
Issue number5
Early online date20 Mar 2015
DOIs
Publication statusPublished - 2015

Fingerprint

Acetylene
Impregnation
Hydrogenation
Ethylene
Catalysts
Testing
Carbon Monoxide
Hydrogen
Catalyst activity
ethylene
Temperature

ASJC Scopus subject areas

  • Catalysis

Cite this

Optimisation of preparation method for Pd doped Cu/Al2O3 catalysts for selective acetylene hydrogenation. / McCue, Alan J.; Shepherd, Ashley M.; Anderson, James A.

In: Catalysis Science & Technology, Vol. 5, No. 5, 2015, p. 2880-2890.

Research output: Contribution to journalArticle

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