TY - JOUR
T1 - Petrographic and geochemical evidence for multiphase formation of carbonates in the Martian orthopyroxenite Allan Hills 84001
AU - Moyano-Cambero, Carles E.
AU - Trigo-Rodríguez, Josep M.
AU - Benito, M. Isabel
AU - Alonso-Azcárate, Jacinto
AU - Lee, Martin R.
AU - Mestres, Narcís.
AU - Martínez-Jiménez, Marina
AU - Martín-Torres, Francisco J.
AU - Fraxedas, Jordi
N1 - This research has been funded by the Spanish Ministry of Science and Innovation (projects: AYA2011‐26,522, AYA 2015‐67175‐P, CTQ2015‐62,635‐ERC, and CTQ2014‐60,119‐P to which J.M. Trigo‐Rodríguez and C.E. Moyano‐Cambero acknowledge financial support). The UK Science and Technology Facilities Council is also thanked for funding through grants ST/H002960/1, ST/K000942/1, and ST/L002167/1. ICN2 and ICMAB acknowledge support of the Spanish MINECO through the Severo Ochoa Centers of Excellence Program under Grants SEV‐2013‐0295 and SEV‐2015‐0496, respectively. We acknowledge B. Ballesteros and M. Rosado from the ICN2 Electron Microscopy Division, and A. Fernández from the ICTS (National Center of Electronic Microscopy) for the SEM, EDS, and microprobe measurements. We also thank the NASA Meteorite Working Group, and the Johnson Space Center for providing the ALH 84001,82 section. This study was done in the frame of a PhD on Physics at the Autonomous University of Barcelona (UAB) under the direction of J. M. Trigo‐Rodríguez.
PY - 2017/6
Y1 - 2017/6
N2 - Martian meteorites can provide valuable information about past environmental conditions on Mars. Allan Hills 84001 formed more than 4 Gyr ago, and owing to its age and long exposure to the Martian environment, and this meteorite has features that may record early processes. These features include a highly fractured texture, gases trapped during one or more impact events or during formation of the rock, and spherical Fe-Mg-Ca carbonates. In this study, we have concentrated on providing new insights into the context of these carbonates using a range of techniques to explore whether they record multiple precipitation and shock events. The petrographic features and compositional properties of these carbonates indicate that at least two pulses of Mg- and Fe-rich solutions saturated the rock. Those two generations of carbonates can be distinguished by a very sharp change in compositions, from being rich in Mg and poor in Fe and Mn, to being poor in Mg and rich in Fe and Mn. Between these two generations of carbonate is evidence for fracturing and local corrosion.
AB - Martian meteorites can provide valuable information about past environmental conditions on Mars. Allan Hills 84001 formed more than 4 Gyr ago, and owing to its age and long exposure to the Martian environment, and this meteorite has features that may record early processes. These features include a highly fractured texture, gases trapped during one or more impact events or during formation of the rock, and spherical Fe-Mg-Ca carbonates. In this study, we have concentrated on providing new insights into the context of these carbonates using a range of techniques to explore whether they record multiple precipitation and shock events. The petrographic features and compositional properties of these carbonates indicate that at least two pulses of Mg- and Fe-rich solutions saturated the rock. Those two generations of carbonates can be distinguished by a very sharp change in compositions, from being rich in Mg and poor in Fe and Mn, to being poor in Mg and rich in Fe and Mn. Between these two generations of carbonate is evidence for fracturing and local corrosion.
KW - Astrophysics - Earth and Planetary Astrophysics
KW - Petrographic
KW - geochemical evidence
KW - Mars
U2 - 10.1111/maps.12851
DO - 10.1111/maps.12851
M3 - Article
VL - 52
SP - 1030
EP - 1047
JO - Meteoritics & Planetary Sciences
JF - Meteoritics & Planetary Sciences
SN - 1086-9379
IS - 6
ER -