Polyaromatic amines

Part 2. Synthesis of 4,4 ',4 ''-tris(N-aryl-N-phenylamino)triphenylamine, N,N-bis[4-(N-aryl-N phenylamino)phenyl]tolylamine and N,N,N ',N '-tetraaryl-o-phenylenediamine derivatives

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13 Citations (Scopus)

Abstract

The title compounds were synthesised and characterised as part of a study into new aromatic amines for charge transporting materials. Proton and carbon spectral data for compounds 1-6 were obtained in C6D6 as a consequence of their facile oxidation in CDCl3, Each compound was characterised by cyclic voltammetry. An estimate of the intramolecular charge mobility was deduced from the difference between the first and second oxidation potentials.

Original languageEnglish
Pages (from-to)2548-2552
Number of pages5
JournalJournal of the Chemical Society, Perkin Transactions 1
Volume20
DOIs
Publication statusPublished - 21 Oct 2001

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Amines
Derivatives
Oxidation
Cyclic voltammetry
Protons
Carbon
1,2-diaminobenzene

Keywords

  • transient nutation spectroscopy
  • palladium catalysed amination
  • organic ferromagnetic metals
  • hole-transporting materials
  • cation radicals
  • mobility
  • triphenylamine
  • precursors
  • complexes
  • polymers

Cite this

@article{d49ceb6fe5594672b3faf8e76df3e2b7,
title = "Polyaromatic amines: Part 2. Synthesis of 4,4 ',4 ''-tris(N-aryl-N-phenylamino)triphenylamine, N,N-bis[4-(N-aryl-N phenylamino)phenyl]tolylamine and N,N,N ',N '-tetraaryl-o-phenylenediamine derivatives",
abstract = "The title compounds were synthesised and characterised as part of a study into new aromatic amines for charge transporting materials. Proton and carbon spectral data for compounds 1-6 were obtained in C6D6 as a consequence of their facile oxidation in CDCl3, Each compound was characterised by cyclic voltammetry. An estimate of the intramolecular charge mobility was deduced from the difference between the first and second oxidation potentials.",
keywords = "transient nutation spectroscopy, palladium catalysed amination, organic ferromagnetic metals, hole-transporting materials, cation radicals, mobility, triphenylamine, precursors, complexes, polymers",
author = "Plater, {Michael John} and T Jackson",
year = "2001",
month = "10",
day = "21",
doi = "10.1039/b106273p",
language = "English",
volume = "20",
pages = "2548--2552",
journal = "Journal of the Chemical Society, Perkin Transactions 1",
issn = "1472-7781",
publisher = "Chemical Society",

}

TY - JOUR

T1 - Polyaromatic amines

T2 - Part 2. Synthesis of 4,4 ',4 ''-tris(N-aryl-N-phenylamino)triphenylamine, N,N-bis[4-(N-aryl-N phenylamino)phenyl]tolylamine and N,N,N ',N '-tetraaryl-o-phenylenediamine derivatives

AU - Plater, Michael John

AU - Jackson, T

PY - 2001/10/21

Y1 - 2001/10/21

N2 - The title compounds were synthesised and characterised as part of a study into new aromatic amines for charge transporting materials. Proton and carbon spectral data for compounds 1-6 were obtained in C6D6 as a consequence of their facile oxidation in CDCl3, Each compound was characterised by cyclic voltammetry. An estimate of the intramolecular charge mobility was deduced from the difference between the first and second oxidation potentials.

AB - The title compounds were synthesised and characterised as part of a study into new aromatic amines for charge transporting materials. Proton and carbon spectral data for compounds 1-6 were obtained in C6D6 as a consequence of their facile oxidation in CDCl3, Each compound was characterised by cyclic voltammetry. An estimate of the intramolecular charge mobility was deduced from the difference between the first and second oxidation potentials.

KW - transient nutation spectroscopy

KW - palladium catalysed amination

KW - organic ferromagnetic metals

KW - hole-transporting materials

KW - cation radicals

KW - mobility

KW - triphenylamine

KW - precursors

KW - complexes

KW - polymers

U2 - 10.1039/b106273p

DO - 10.1039/b106273p

M3 - Article

VL - 20

SP - 2548

EP - 2552

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

SN - 1472-7781

ER -