Poly[[diaquacadmium(II)]-mu(3)-(1-carboxybenzene-3,5dicarboxylato)]

J M S  Skakle; M R S  Foreman; M J  Plater; C  Griffin

Poly[[diaquacadmium(II)]-mu(3)-(1-carboxybenzene-3,5dicarboxylato)]

J M S Skakle, M R S Foreman, M J Plater, C Griffin

Research output: Contribution to journal › Article

Abstract

The crystal structure of the title complex, poly[[diaquacadmium(II)]-mu (3) -(1-carboxybenzene-3,5-dicarboxylato-O-1:O-3,O-3':O-5,O-5')], [Cd(C9H4O6)(H2O)(2)](n), features two-dimensional polymeric network layers which are hydrogen-bonded to one another. The Cd atom is coordinated by seven O atoms, two of which belong to water molecules arranged trans to each other, above and below the layers. Each polymeric layer is tiled with (Cd)(3)(C9O6)(3) rings formed by alternating Cd atoms and (C9O6) ligands. The layers are parallel to the (1) over bar 01 crystal plane and the neighbouring layers are separated by 3.2508 (2) Angstrom.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	57
Publication status	Published - 2001

Keywords

ACID

Cite this

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title = "Poly[[diaquacadmium(II)]-mu(3)-(1-carboxybenzene-3,5dicarboxylato)]",

abstract = "The crystal structure of the title complex, poly[[diaquacadmium(II)]-mu (3) -(1-carboxybenzene-3,5-dicarboxylato-O-1:O-3,O-3':O-5,O-5')], [Cd(C9H4O6)(H2O)(2)](n), features two-dimensional polymeric network layers which are hydrogen-bonded to one another. The Cd atom is coordinated by seven O atoms, two of which belong to water molecules arranged trans to each other, above and below the layers. Each polymeric layer is tiled with (Cd)(3)(C9O6)(3) rings formed by alternating Cd atoms and (C9O6) ligands. The layers are parallel to the (1) over bar 01 crystal plane and the neighbouring layers are separated by 3.2508 (2) Angstrom.",

keywords = "ACID",

author = "Skakle, {J M S} and Foreman, {M R S} and Plater, {M J} and C Griffin",

year = "2001",

language = "English",

volume = "57",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Poly[[diaquacadmium(II)]-mu(3)-(1-carboxybenzene-3,5dicarboxylato)]

AU - Skakle, J M S

AU - Foreman, M R S

AU - Plater, M J

AU - Griffin, C

PY - 2001

Y1 - 2001

N2 - The crystal structure of the title complex, poly[[diaquacadmium(II)]-mu (3) -(1-carboxybenzene-3,5-dicarboxylato-O-1:O-3,O-3':O-5,O-5')], [Cd(C9H4O6)(H2O)(2)](n), features two-dimensional polymeric network layers which are hydrogen-bonded to one another. The Cd atom is coordinated by seven O atoms, two of which belong to water molecules arranged trans to each other, above and below the layers. Each polymeric layer is tiled with (Cd)(3)(C9O6)(3) rings formed by alternating Cd atoms and (C9O6) ligands. The layers are parallel to the (1) over bar 01 crystal plane and the neighbouring layers are separated by 3.2508 (2) Angstrom.

AB - The crystal structure of the title complex, poly[[diaquacadmium(II)]-mu (3) -(1-carboxybenzene-3,5-dicarboxylato-O-1:O-3,O-3':O-5,O-5')], [Cd(C9H4O6)(H2O)(2)](n), features two-dimensional polymeric network layers which are hydrogen-bonded to one another. The Cd atom is coordinated by seven O atoms, two of which belong to water molecules arranged trans to each other, above and below the layers. Each polymeric layer is tiled with (Cd)(3)(C9O6)(3) rings formed by alternating Cd atoms and (C9O6) ligands. The layers are parallel to the (1) over bar 01 crystal plane and the neighbouring layers are separated by 3.2508 (2) Angstrom.

KW - ACID

M3 - Article

VL - 57

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

ER -