Poly[piperazinium(2+) [hexa-mu-hydrogen phosphito-mu-piperazine-pentazinc(II)]]

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Abstract

The title compound, {(C4H12N2)[Zn-5(HPO3)(6)(C4H10N2)]}(n) contains ZnO4, ZnO3N and HPO3 polyhedral building units linked by Zn - O - P bridges (mean Zn - O - P = 133.6 degrees). The organic species exists in two forms, i.e. as neutral molecules that bond directly to zinc as ligands via both N atoms and as diprotonated cations that interact with the framework by way of N-H center dot center dot center dot O hydrogen bonds. Both organic components lie across centres of inversion.

Original languageEnglish
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume62
DOIs
Publication statusPublished - 2006

Keywords

  • HYDROGEN PHOSPHITE
  • ZINCOPHOSPHITE

Cite this

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title = "Poly[piperazinium(2+) [hexa-mu-hydrogen phosphito-mu-piperazine-pentazinc(II)]]",
abstract = "The title compound, {(C4H12N2)[Zn-5(HPO3)(6)(C4H10N2)]}(n) contains ZnO4, ZnO3N and HPO3 polyhedral building units linked by Zn - O - P bridges (mean Zn - O - P = 133.6 degrees). The organic species exists in two forms, i.e. as neutral molecules that bond directly to zinc as ligands via both N atoms and as diprotonated cations that interact with the framework by way of N-H center dot center dot center dot O hydrogen bonds. Both organic components lie across centres of inversion.",
keywords = "HYDROGEN PHOSPHITE, ZINCOPHOSPHITE",
author = "Harrison, {W T A}",
year = "2006",
doi = "10.1107/S0108270106007657",
language = "English",
volume = "62",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - Poly[piperazinium(2+) [hexa-mu-hydrogen phosphito-mu-piperazine-pentazinc(II)]]

AU - Harrison, W T A

PY - 2006

Y1 - 2006

N2 - The title compound, {(C4H12N2)[Zn-5(HPO3)(6)(C4H10N2)]}(n) contains ZnO4, ZnO3N and HPO3 polyhedral building units linked by Zn - O - P bridges (mean Zn - O - P = 133.6 degrees). The organic species exists in two forms, i.e. as neutral molecules that bond directly to zinc as ligands via both N atoms and as diprotonated cations that interact with the framework by way of N-H center dot center dot center dot O hydrogen bonds. Both organic components lie across centres of inversion.

AB - The title compound, {(C4H12N2)[Zn-5(HPO3)(6)(C4H10N2)]}(n) contains ZnO4, ZnO3N and HPO3 polyhedral building units linked by Zn - O - P bridges (mean Zn - O - P = 133.6 degrees). The organic species exists in two forms, i.e. as neutral molecules that bond directly to zinc as ligands via both N atoms and as diprotonated cations that interact with the framework by way of N-H center dot center dot center dot O hydrogen bonds. Both organic components lie across centres of inversion.

KW - HYDROGEN PHOSPHITE

KW - ZINCOPHOSPHITE

U2 - 10.1107/S0108270106007657

DO - 10.1107/S0108270106007657

M3 - Article

VL - 62

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -