Poly[piperazinium(2+) [hexa-mu-hydrogen phosphito-mu-piperazine-pentazinc(II)]]

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Abstract

The title compound, {(C4H12N2)[Zn-5(HPO3)(6)(C4H10N2)]}(n) contains ZnO4, ZnO3N and HPO3 polyhedral building units linked by Zn - O - P bridges (mean Zn - O - P = 133.6 degrees). The organic species exists in two forms, i.e. as neutral molecules that bond directly to zinc as ligands via both N atoms and as diprotonated cations that interact with the framework by way of N-H center dot center dot center dot O hydrogen bonds. Both organic components lie across centres of inversion.

Original languageEnglish
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume62
DOIs
Publication statusPublished - 2006

Keywords

  • HYDROGEN PHOSPHITE
  • ZINCOPHOSPHITE

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