Quantitative determination of surface species and adsorption sites using Infrared spectroscopy

Alan J. McCue; Greg A. Mutch; Andrew I. McNab; Steven Campbell; James A. Anderson

doi:10.1016/j.cattod.2015.03.039

Quantitative determination of surface species and adsorption sites using Infrared spectroscopy

Alan J. McCue, Greg A. Mutch, Andrew I. McNab, Steven Campbell, James A. Anderson^*

^*Corresponding author for this work

University of Aberdeen

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

An overview of the application of FTIR to the quantification of adsorption sites on solid acids, metal particles and to hydrocarbon chains formed during Fischer Tropsch synthesis is reported. The procedures employed in obtaining molar absorption coefficients for transmittance FTIR are described along with a review of pertinent data reported for the three topic areas covered. The limitations and challenges in each case are outlined. (C) 2015 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	19-26
Number of pages	8
Journal	Catalysis Today
Volume	259
Issue number	1
Early online date	28 Apr 2015
DOIs	https://doi.org/10.1016/j.cattod.2015.03.039
Publication status	Published - 1 Jan 2016

Bibliographical note

We wish to thank organisations who have supported research related to work reported here including Royal Society (London), EPSRC, The Carnegie Trust for the Universities of Scotland, SABIC and Johnson Matthey, and to inspirational discussions over a number of years with colleagues working in this area including C.H. Rochester, F. Solymosi, F. Meunier, G. Cerrato and C. Morterra and to research students, D. Rosenberg, E. Mitchell and T. Heinz who contributed to experimental design and protocol.

Keywords

In-situ FT-IR
quantification
surface species
mechanistic/kinetic
Fischer Tropsch
reflectance FTIR spectroscopy
sulfated zirconia catalysis
in-situ
extinction coefficients
IR spectroscopy
oxide catalysts
carbon-monoxide
acid catalysts
active-sites
NOX storage

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Cite this

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title = "Quantitative determination of surface species and adsorption sites using Infrared spectroscopy",

abstract = "An overview of the application of FTIR to the quantification of adsorption sites on solid acids, metal particles and to hydrocarbon chains formed during Fischer Tropsch synthesis is reported. The procedures employed in obtaining molar absorption coefficients for transmittance FTIR are described along with a review of pertinent data reported for the three topic areas covered. The limitations and challenges in each case are outlined. (C) 2015 Elsevier B.V. All rights reserved.",

keywords = "In-situ FT-IR, quantification, surface species, mechanistic/kinetic, Fischer Tropsch, reflectance FTIR spectroscopy, sulfated zirconia catalysis, in-situ, extinction coefficients, IR spectroscopy, oxide catalysts, carbon-monoxide, acid catalysts, active-sites, NOX storage",

author = "McCue, {Alan J.} and Mutch, {Greg A.} and McNab, {Andrew I.} and Steven Campbell and Anderson, {James A.}",

note = "We wish to thank organisations who have supported research related to work reported here including Royal Society (London), EPSRC, The Carnegie Trust for the Universities of Scotland, SABIC and Johnson Matthey, and to inspirational discussions over a number of years with colleagues working in this area including C.H. Rochester, F. Solymosi, F. Meunier, G. Cerrato and C. Morterra and to research students, D. Rosenberg, E. Mitchell and T. Heinz who contributed to experimental design and protocol.",

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doi = "10.1016/j.cattod.2015.03.039",

language = "English",

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AU - McCue, Alan J.

AU - Mutch, Greg A.

AU - McNab, Andrew I.

AU - Campbell, Steven

AU - Anderson, James A.

N1 - We wish to thank organisations who have supported research related to work reported here including Royal Society (London), EPSRC, The Carnegie Trust for the Universities of Scotland, SABIC and Johnson Matthey, and to inspirational discussions over a number of years with colleagues working in this area including C.H. Rochester, F. Solymosi, F. Meunier, G. Cerrato and C. Morterra and to research students, D. Rosenberg, E. Mitchell and T. Heinz who contributed to experimental design and protocol.

PY - 2016/1/1

Y1 - 2016/1/1

N2 - An overview of the application of FTIR to the quantification of adsorption sites on solid acids, metal particles and to hydrocarbon chains formed during Fischer Tropsch synthesis is reported. The procedures employed in obtaining molar absorption coefficients for transmittance FTIR are described along with a review of pertinent data reported for the three topic areas covered. The limitations and challenges in each case are outlined. (C) 2015 Elsevier B.V. All rights reserved.

AB - An overview of the application of FTIR to the quantification of adsorption sites on solid acids, metal particles and to hydrocarbon chains formed during Fischer Tropsch synthesis is reported. The procedures employed in obtaining molar absorption coefficients for transmittance FTIR are described along with a review of pertinent data reported for the three topic areas covered. The limitations and challenges in each case are outlined. (C) 2015 Elsevier B.V. All rights reserved.

KW - In-situ FT-IR

KW - quantification

KW - surface species

KW - mechanistic/kinetic

KW - Fischer Tropsch

KW - reflectance FTIR spectroscopy

KW - sulfated zirconia catalysis

KW - in-situ

KW - extinction coefficients

KW - IR spectroscopy

KW - oxide catalysts

KW - carbon-monoxide

KW - acid catalysts

KW - active-sites

KW - NOX storage

U2 - 10.1016/j.cattod.2015.03.039

DO - 10.1016/j.cattod.2015.03.039

M3 - Article

SN - 0920-5861

VL - 259

SP - 19

EP - 26

JO - Catalysis Today

JF - Catalysis Today

IS - 1

ER -

Quantitative determination of surface species and adsorption sites using Infrared spectroscopy

Abstract

Bibliographical note

Keywords

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