Reactions of ethanol over metal oxides

H Idriss, E G Seebauer

Research output: Contribution to journalArticle

182 Citations (Scopus)

Abstract

The reaction of ethanol over a series of oxides (Fe2O3, Fe2O3/CaO, Fe3O4, TiO2, CaO, and SiO2) has been investigated. The main reaction product in all cases is acetaldehyde, with secondary products acetone and ethyl acetate. At 473 K, the rate Constant k decreases according to the series Fe2O3 > Fe3O4 > CaO > TiO2 >> SiO2. Titration of basic sites by CO2 adsorption at room temperature shows that the reaction rate can be successfully normalised by basic site density for oxides that adsorb CO2 except for CaO. Acetone production, presumably via acetate ketonization, is highest over TiO2 while ethyl acetate formation, by Tishchenko reaction, is highest over Fe2O3. (C) 2000 Elsevier Science B.V. All rights reserved.

Original languageEnglish
Pages (from-to)201-212
Number of pages12
JournalJournal of Molecular Catalysis A: Chemical
Volume152
Issue number1-2
DOIs
Publication statusPublished - 1 Mar 2000

Keywords

  • reactions
  • ethanol
  • metal oxides
  • temperature-programmed desorption
  • single-crystal surfaces
  • scanning tunneling microscopy
  • oxidative dehydrogenation
  • aliphatic-alcohols
  • probe molecules
  • MGO surfaces
  • catalysts
  • methanol
  • decomposition

Cite this

Reactions of ethanol over metal oxides. / Idriss, H; Seebauer, E G .

In: Journal of Molecular Catalysis A: Chemical, Vol. 152, No. 1-2, 01.03.2000, p. 201-212.

Research output: Contribution to journalArticle

Idriss, H ; Seebauer, E G . / Reactions of ethanol over metal oxides. In: Journal of Molecular Catalysis A: Chemical. 2000 ; Vol. 152, No. 1-2. pp. 201-212.
@article{2110039c6cd84d6fa02bf6f04930a06e,
title = "Reactions of ethanol over metal oxides",
abstract = "The reaction of ethanol over a series of oxides (Fe2O3, Fe2O3/CaO, Fe3O4, TiO2, CaO, and SiO2) has been investigated. The main reaction product in all cases is acetaldehyde, with secondary products acetone and ethyl acetate. At 473 K, the rate Constant k decreases according to the series Fe2O3 > Fe3O4 > CaO > TiO2 >> SiO2. Titration of basic sites by CO2 adsorption at room temperature shows that the reaction rate can be successfully normalised by basic site density for oxides that adsorb CO2 except for CaO. Acetone production, presumably via acetate ketonization, is highest over TiO2 while ethyl acetate formation, by Tishchenko reaction, is highest over Fe2O3. (C) 2000 Elsevier Science B.V. All rights reserved.",
keywords = "reactions, ethanol, metal oxides, temperature-programmed desorption, single-crystal surfaces, scanning tunneling microscopy, oxidative dehydrogenation, aliphatic-alcohols, probe molecules, MGO surfaces, catalysts, methanol, decomposition",
author = "H Idriss and Seebauer, {E G}",
year = "2000",
month = "3",
day = "1",
doi = "10.1016/S1381-1169(99)00297-6",
language = "English",
volume = "152",
pages = "201--212",
journal = "Journal of Molecular Catalysis A: Chemical",
issn = "1381-1169",
publisher = "Elsevier",
number = "1-2",

}

TY - JOUR

T1 - Reactions of ethanol over metal oxides

AU - Idriss, H

AU - Seebauer, E G

PY - 2000/3/1

Y1 - 2000/3/1

N2 - The reaction of ethanol over a series of oxides (Fe2O3, Fe2O3/CaO, Fe3O4, TiO2, CaO, and SiO2) has been investigated. The main reaction product in all cases is acetaldehyde, with secondary products acetone and ethyl acetate. At 473 K, the rate Constant k decreases according to the series Fe2O3 > Fe3O4 > CaO > TiO2 >> SiO2. Titration of basic sites by CO2 adsorption at room temperature shows that the reaction rate can be successfully normalised by basic site density for oxides that adsorb CO2 except for CaO. Acetone production, presumably via acetate ketonization, is highest over TiO2 while ethyl acetate formation, by Tishchenko reaction, is highest over Fe2O3. (C) 2000 Elsevier Science B.V. All rights reserved.

AB - The reaction of ethanol over a series of oxides (Fe2O3, Fe2O3/CaO, Fe3O4, TiO2, CaO, and SiO2) has been investigated. The main reaction product in all cases is acetaldehyde, with secondary products acetone and ethyl acetate. At 473 K, the rate Constant k decreases according to the series Fe2O3 > Fe3O4 > CaO > TiO2 >> SiO2. Titration of basic sites by CO2 adsorption at room temperature shows that the reaction rate can be successfully normalised by basic site density for oxides that adsorb CO2 except for CaO. Acetone production, presumably via acetate ketonization, is highest over TiO2 while ethyl acetate formation, by Tishchenko reaction, is highest over Fe2O3. (C) 2000 Elsevier Science B.V. All rights reserved.

KW - reactions

KW - ethanol

KW - metal oxides

KW - temperature-programmed desorption

KW - single-crystal surfaces

KW - scanning tunneling microscopy

KW - oxidative dehydrogenation

KW - aliphatic-alcohols

KW - probe molecules

KW - MGO surfaces

KW - catalysts

KW - methanol

KW - decomposition

U2 - 10.1016/S1381-1169(99)00297-6

DO - 10.1016/S1381-1169(99)00297-6

M3 - Article

VL - 152

SP - 201

EP - 212

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

SN - 1381-1169

IS - 1-2

ER -