@article{d9d38458a7ef425889257821b614efad,
title = "Room temperature methoxylation in zeolite H-ZSM-5: an operando DRIFTS/mass spectrometric study",
abstract = "At high loading, methanol reacts under ambient conditions with acidic hydroxyls of H-ZSM-5 to methoxylate framework oxygen; while a significant proportion remains hydrogen bonded to the framework with a protonated geometry. The findings not only explain the data which have been published so far, but also pave a way forward for potential unravelling of the initial reaction steps in the relevant chemical processes.",
author = "Matam, {Santhosh K} and Howe, {Russell F} and Adam Thetford and Catlow, {C Richard A}",
note = "The UK Catalysis Hub is thanked for resources and support provided via our membership of the UK Catalysis Hub Consortium and funded by EPSRC (grants EP/I038748/1, EP/I019693/1, EP/ K014706/1, EP/K014668/1, EP/K014854/1, EP/K014714/1 and EP/ M013219/1). Via our membership of the UK{\textquoteright}s HEC Materials Chemistry Consortium, which is funded by EPSRC (EP/L000202), this work used the ARCHER UK National Supercomputing Service (www.archer.ac.uk). Johnson Matthey plc is thanked for the provision of the ZSM5. Dr A. J. O{\textquoteright}Malley and Dr S. F. Parker are thanked for fruitful discussion.",
year = "2018",
month = nov,
day = "13",
doi = "10.1039/c8cc07444e",
language = "English",
volume = "54",
pages = "12875--12878",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "91",
}