Searching for travertines, calcretes and speleothems in deep time: Processes, appearances, predictions and the impact of plants

Common models for modern calcite precipitation in and around caves, soils, springs and streams involve CO2 supplied by thick, high pCO(2) biogenic soils which were probably thin or non-existent before vascular plants. Indeed plant-influenced chemical weathering might have caused accelerated terrestrial carbonate production from the Devonian onwards. However terrestrial carbonates have also been documented from the Archaean, Proterozoic, Cambrian, Ordovician and Silurian. Mechanisms which could have caused non-marine carbonates to precipitate without organic-rich soils are described, and some geological events likely to have influenced non-marine carbonate precipitation up to the origin of vascular plants are highlighted. As organisms have evolved, so have the petrographic characteristics of non-marine carbonates: some examples of this are also given here. (C) 2010 Elsevier B.V. All rights reserved.