Abstract
The aim of this study was to investigate the biomimetic precipitation processes that follow the chemical-garden reaction of brines of CaCl2 and sulfate salts with silicate in alkaline conditions under a Mars-type CO2-rich atmosphere. We characterize the precipitates with Environmental Scanning Electron Microscope micrography, micro-Raman spectroscopy, and X-ray diffractometry. Our analysis results indicate that self-assembled carbonate structures formed with calcium chloride can have vesicular and filamentary features. With magnesium sulfate as a reactant a tentative assignment with Raman spectroscopy indicates the presence of natroxalate in the precipitate. These morphologies and compounds appear through rapid sequestration of atmospheric CO2 by alkaline solutions of silica and salts.
Original language | English |
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Number of pages | 17 |
Journal | Astrobiology |
Volume | 22 |
Issue number | 7 |
Early online date | 25 May 2022 |
DOIs | |
Publication status | Published - 11 Jul 2022 |
Bibliographical note
AcknowledgmentsE.E.-R. acknowledges Rafael Esteso for his help and advice with the experimental setups and photography, Abhilash Vakkada Ramachandran for his help with the Mars Chamber experiment, and Carlos Pimentel for the fruitful discussion about platonic carbonates.
Funding Information
The authors acknowledge the contribution of the European COST Action CA17120 supported by the EU Framework Programme Horizon 2020 and the Spanish MINECO projects FIS2016-77692-C2 and PCIN-2017-098. M.P.Z. acknowledges the partial support of the Spanish State Research Agency (AEI) Project No. MDM-2017-0737 and of the Spanish Ministry of Science and Innovation project PID2019-104205GB-C21.
Keywords
- Mars
- Carbonate minerals
- Self-assembly
- Natroxalate
- Chemical gardens
- CO2 atmosphere
- CALCIUM-CARBONATE
- GALE CRATER
- MARS
- CRYSTALLIZATION
- MINERALS
- MAGNESIUM
- DRIVEN
- TUBES
- RAMAN
- LIFE