Silver(I)-saccharin coordination polymers with 2-pyridylmethanol and 2,6-pyridinedimethanol. Synthetic, spectroscopic, thermal and structural studies of [Ag(sac)(mu-mpy)](n) and [Ag(mu-sac)(dmpy)](n)

S Hamamci, V T Yilmaz, W T A Harrison, C Thone

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33 Citations (Scopus)

Abstract

Two new coordination polymers of saccharinato-silver(I) complexes with 2-pyridylmethanol (mpy) and 2,6-pyridinedimethanol (dmpy), [Ag(sac)(μ-mpy)](n) (1) and [Ag(μ-sac)(dmpy)](n) (2), (sac = saccharinate), have been synthesized and structurally characterized by elemental analysis, IR, thermal analysis and single crystal X-ray diffraction. Crystal data: 1, monoclinic, P2(1)/c, with a = 13.3584(14) b = 8.3040(10) c = 13.0430(14) &ANGS;, β = 106.227(3)°, Z = 4; 2, monoclinic, P2(1)/n, with a = 7.3538(1) &ANGS;, b = 13.0444(3) c = 15.7315(3) &ANGS;, β 98.8976(13)°, Z = 4. In 1, [Ag-2(sac)(2)(mpy)(2)] building blocks are connected into a two-dimensional framework by bridging OH groups of mpy, and they are further stacked by O-(HO)-O-... hydrogen bonds, and weak π(sac)(...)π(py) and π(py)(...)π(py) interactions to form a three-dimensional supramolecular framework. In 2, [Ag-2(sac)(dmpy)] units are linked by the O-sulfonyl bridges of sac, leading to one-dimensional polymeric chains, which are reinforced by the O-(HO)-O-... hydrogen bonds and π(sac)(...)π(py) interactions to generate a three-dimensional supramolecular network. The coordination polymers 1 and 2 exhibit three- and four-coordinated silver(I) centers, respectively, and the intra-chain (AgAg)-Ag-... separations in 1 and 2 are 3.2988(4) and 4.1429(2) &ANGS;, respectively. © 2005 Elsevier SAS. All rights reserved.

Original languageEnglish
Pages (from-to)423-429
Number of pages7
JournalSolid State Sciences
Volume7
DOIs
Publication statusPublished - 2005

Keywords

  • saccharin
  • silver(I)
  • 2-pyridylmethanol
  • 2,6-pyridinedimethanol
  • coordination frameworks
  • CRYSTAL-STRUCTURES
  • COMPLEXES
  • SACCHARINATE
  • SILVER(I)
  • FRAMEWORKS
  • <M(C7H4NO3S)2(H2O)4>.2H2O
  • CONSTRUCTION
  • DIHYDRATE
  • MOLECULES
  • COPPER(I)

Cite this

@article{2a816bee38b5443f828a476f4cfeaa63,
title = "Silver(I)-saccharin coordination polymers with 2-pyridylmethanol and 2,6-pyridinedimethanol. Synthetic, spectroscopic, thermal and structural studies of [Ag(sac)(mu-mpy)](n) and [Ag(mu-sac)(dmpy)](n)",
abstract = "Two new coordination polymers of saccharinato-silver(I) complexes with 2-pyridylmethanol (mpy) and 2,6-pyridinedimethanol (dmpy), [Ag(sac)(&mu;-mpy)](n) (1) and [Ag(&mu;-sac)(dmpy)](n) (2), (sac = saccharinate), have been synthesized and structurally characterized by elemental analysis, IR, thermal analysis and single crystal X-ray diffraction. Crystal data: 1, monoclinic, P2(1)/c, with a = 13.3584(14) b = 8.3040(10) c = 13.0430(14) &ANGS;, &beta; = 106.227(3)&DEG;, Z = 4; 2, monoclinic, P2(1)/n, with a = 7.3538(1) &ANGS;, b = 13.0444(3) c = 15.7315(3) &ANGS;, &beta; 98.8976(13)&DEG;, Z = 4. In 1, [Ag-2(sac)(2)(mpy)(2)] building blocks are connected into a two-dimensional framework by bridging OH groups of mpy, and they are further stacked by O-(HO)-O-... hydrogen bonds, and weak &pi;(sac)(...)&pi;(py) and &pi;(py)(...)&pi;(py) interactions to form a three-dimensional supramolecular framework. In 2, [Ag-2(sac)(dmpy)] units are linked by the O-sulfonyl bridges of sac, leading to one-dimensional polymeric chains, which are reinforced by the O-(HO)-O-... hydrogen bonds and &pi;(sac)(...)&pi;(py) interactions to generate a three-dimensional supramolecular network. The coordination polymers 1 and 2 exhibit three- and four-coordinated silver(I) centers, respectively, and the intra-chain (AgAg)-Ag-... separations in 1 and 2 are 3.2988(4) and 4.1429(2) &ANGS;, respectively. &COPY; 2005 Elsevier SAS. All rights reserved.",
keywords = "saccharin, silver(I), 2-pyridylmethanol, 2,6-pyridinedimethanol, coordination frameworks, CRYSTAL-STRUCTURES, COMPLEXES, SACCHARINATE, SILVER(I), FRAMEWORKS, <M(C7H4NO3S)2(H2O)4>.2H2O, CONSTRUCTION, DIHYDRATE, MOLECULES, COPPER(I)",
author = "S Hamamci and Yilmaz, {V T} and Harrison, {W T A} and C Thone",
year = "2005",
doi = "10.1016/j.solidstatesciences.2005.01.004",
language = "English",
volume = "7",
pages = "423--429",
journal = "Solid State Sciences",
issn = "1293-2558",
publisher = "Elsevier Masson SAS",

}

TY - JOUR

T1 - Silver(I)-saccharin coordination polymers with 2-pyridylmethanol and 2,6-pyridinedimethanol. Synthetic, spectroscopic, thermal and structural studies of [Ag(sac)(mu-mpy)](n) and [Ag(mu-sac)(dmpy)](n)

AU - Hamamci, S

AU - Yilmaz, V T

AU - Harrison, W T A

AU - Thone, C

PY - 2005

Y1 - 2005

N2 - Two new coordination polymers of saccharinato-silver(I) complexes with 2-pyridylmethanol (mpy) and 2,6-pyridinedimethanol (dmpy), [Ag(sac)(&mu;-mpy)](n) (1) and [Ag(&mu;-sac)(dmpy)](n) (2), (sac = saccharinate), have been synthesized and structurally characterized by elemental analysis, IR, thermal analysis and single crystal X-ray diffraction. Crystal data: 1, monoclinic, P2(1)/c, with a = 13.3584(14) b = 8.3040(10) c = 13.0430(14) &ANGS;, &beta; = 106.227(3)&DEG;, Z = 4; 2, monoclinic, P2(1)/n, with a = 7.3538(1) &ANGS;, b = 13.0444(3) c = 15.7315(3) &ANGS;, &beta; 98.8976(13)&DEG;, Z = 4. In 1, [Ag-2(sac)(2)(mpy)(2)] building blocks are connected into a two-dimensional framework by bridging OH groups of mpy, and they are further stacked by O-(HO)-O-... hydrogen bonds, and weak &pi;(sac)(...)&pi;(py) and &pi;(py)(...)&pi;(py) interactions to form a three-dimensional supramolecular framework. In 2, [Ag-2(sac)(dmpy)] units are linked by the O-sulfonyl bridges of sac, leading to one-dimensional polymeric chains, which are reinforced by the O-(HO)-O-... hydrogen bonds and &pi;(sac)(...)&pi;(py) interactions to generate a three-dimensional supramolecular network. The coordination polymers 1 and 2 exhibit three- and four-coordinated silver(I) centers, respectively, and the intra-chain (AgAg)-Ag-... separations in 1 and 2 are 3.2988(4) and 4.1429(2) &ANGS;, respectively. &COPY; 2005 Elsevier SAS. All rights reserved.

AB - Two new coordination polymers of saccharinato-silver(I) complexes with 2-pyridylmethanol (mpy) and 2,6-pyridinedimethanol (dmpy), [Ag(sac)(&mu;-mpy)](n) (1) and [Ag(&mu;-sac)(dmpy)](n) (2), (sac = saccharinate), have been synthesized and structurally characterized by elemental analysis, IR, thermal analysis and single crystal X-ray diffraction. Crystal data: 1, monoclinic, P2(1)/c, with a = 13.3584(14) b = 8.3040(10) c = 13.0430(14) &ANGS;, &beta; = 106.227(3)&DEG;, Z = 4; 2, monoclinic, P2(1)/n, with a = 7.3538(1) &ANGS;, b = 13.0444(3) c = 15.7315(3) &ANGS;, &beta; 98.8976(13)&DEG;, Z = 4. In 1, [Ag-2(sac)(2)(mpy)(2)] building blocks are connected into a two-dimensional framework by bridging OH groups of mpy, and they are further stacked by O-(HO)-O-... hydrogen bonds, and weak &pi;(sac)(...)&pi;(py) and &pi;(py)(...)&pi;(py) interactions to form a three-dimensional supramolecular framework. In 2, [Ag-2(sac)(dmpy)] units are linked by the O-sulfonyl bridges of sac, leading to one-dimensional polymeric chains, which are reinforced by the O-(HO)-O-... hydrogen bonds and &pi;(sac)(...)&pi;(py) interactions to generate a three-dimensional supramolecular network. The coordination polymers 1 and 2 exhibit three- and four-coordinated silver(I) centers, respectively, and the intra-chain (AgAg)-Ag-... separations in 1 and 2 are 3.2988(4) and 4.1429(2) &ANGS;, respectively. &COPY; 2005 Elsevier SAS. All rights reserved.

KW - saccharin

KW - silver(I)

KW - 2-pyridylmethanol

KW - 2,6-pyridinedimethanol

KW - coordination frameworks

KW - CRYSTAL-STRUCTURES

KW - COMPLEXES

KW - SACCHARINATE

KW - SILVER(I)

KW - FRAMEWORKS

KW - <M(C7H4NO3S)2(H2O)4>.2H2O

KW - CONSTRUCTION

KW - DIHYDRATE

KW - MOLECULES

KW - COPPER(I)

U2 - 10.1016/j.solidstatesciences.2005.01.004

DO - 10.1016/j.solidstatesciences.2005.01.004

M3 - Article

VL - 7

SP - 423

EP - 429

JO - Solid State Sciences

JF - Solid State Sciences

SN - 1293-2558

ER -