Speciation of metals and metalloids in sediments with LTGC/ICP-MS

Eva Maria Krupp; R  Grumping; U R R  Furchtbar; A V  Hirner

Speciation of metals and metalloids in sediments with LTGC/ICP-MS

Eva Maria Krupp, R Grumping, U R R Furchtbar, A V Hirner

Chemistry

Research output: Contribution to journal › Article › peer-review

81 Citations (Scopus)

Abstract

Low temperature GC on-line coupled with an ICP/MS has been used as analytical device to detect organometallic and -metalloid compounds from various sediments of rivers and harbours in West Germany. The different species have been volatilized by derivatization with NaBH4 and cryofocussed in a trap. Different alkylated species of As, Sn and Sb have been identified, while only methylated compounds of the elements Ge, Se, Te, Hg and Bi could be detected.

Original language	English
Pages (from-to)	546-549
Number of pages	4
Journal	Fresenius’ Journal of Analytical Chemistry
Volume	354
Issue number	5-6
Publication status	Published - Mar 1996

Keywords

BUTYLTIN COMPOUNDS
NATURAL-WATERS
BIOGEOCHEMISTRY
BIOMETHYLATION
ENVIRONMENT
METHYLTIN
ANTIMONY
SELENIUM
TIN
SEA

Cite this

@article{7388b6500c564da8aa14cb333f28f0b2,

title = "Speciation of metals and metalloids in sediments with LTGC/ICP-MS",

abstract = "Low temperature GC on-line coupled with an ICP/MS has been used as analytical device to detect organometallic and -metalloid compounds from various sediments of rivers and harbours in West Germany. The different species have been volatilized by derivatization with NaBH4 and cryofocussed in a trap. Different alkylated species of As, Sn and Sb have been identified, while only methylated compounds of the elements Ge, Se, Te, Hg and Bi could be detected.",

keywords = "BUTYLTIN COMPOUNDS, NATURAL-WATERS, BIOGEOCHEMISTRY, BIOMETHYLATION, ENVIRONMENT, METHYLTIN, ANTIMONY, SELENIUM, TIN, SEA",

author = "Krupp, {Eva Maria} and R Grumping and Furchtbar, {U R R} and Hirner, {A V}",

year = "1996",

month = mar,

language = "English",

volume = "354",

pages = "546--549",

journal = "Fresenius{\textquoteright} Journal of Analytical Chemistry",

issn = "0937-0633",

publisher = "Springer Verlag",

number = "5-6",

}

TY - JOUR

T1 - Speciation of metals and metalloids in sediments with LTGC/ICP-MS

AU - Krupp, Eva Maria

AU - Grumping, R

AU - Furchtbar, U R R

AU - Hirner, A V

PY - 1996/3

Y1 - 1996/3

N2 - Low temperature GC on-line coupled with an ICP/MS has been used as analytical device to detect organometallic and -metalloid compounds from various sediments of rivers and harbours in West Germany. The different species have been volatilized by derivatization with NaBH4 and cryofocussed in a trap. Different alkylated species of As, Sn and Sb have been identified, while only methylated compounds of the elements Ge, Se, Te, Hg and Bi could be detected.

AB - Low temperature GC on-line coupled with an ICP/MS has been used as analytical device to detect organometallic and -metalloid compounds from various sediments of rivers and harbours in West Germany. The different species have been volatilized by derivatization with NaBH4 and cryofocussed in a trap. Different alkylated species of As, Sn and Sb have been identified, while only methylated compounds of the elements Ge, Se, Te, Hg and Bi could be detected.

KW - BUTYLTIN COMPOUNDS

KW - NATURAL-WATERS

KW - BIOGEOCHEMISTRY

KW - BIOMETHYLATION

KW - ENVIRONMENT

KW - METHYLTIN

KW - ANTIMONY

KW - SELENIUM

KW - TIN

KW - SEA

M3 - Article

VL - 354

SP - 546

EP - 549

JO - Fresenius’ Journal of Analytical Chemistry

JF - Fresenius’ Journal of Analytical Chemistry

SN - 0937-0633

IS - 5-6

ER -

Speciation of metals and metalloids in sediments with LTGC/ICP-MS

Abstract

Keywords

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