Abstract
Low temperature GC on-line coupled with an ICP/MS has been used as analytical device to detect organometallic and -metalloid compounds from various sediments of rivers and harbours in West Germany. The different species have been volatilized by derivatization with NaBH4 and cryofocussed in a trap. Different alkylated species of As, Sn and Sb have been identified, while only methylated compounds of the elements Ge, Se, Te, Hg and Bi could be detected.
| Original language | English |
|---|---|
| Pages (from-to) | 546-549 |
| Number of pages | 4 |
| Journal | Fresenius’ Journal of Analytical Chemistry |
| Volume | 354 |
| Issue number | 5-6 |
| Publication status | Published - Mar 1996 |
Keywords
- BUTYLTIN COMPOUNDS
- NATURAL-WATERS
- BIOGEOCHEMISTRY
- BIOMETHYLATION
- ENVIRONMENT
- METHYLTIN
- ANTIMONY
- SELENIUM
- TIN
- SEA
Cite this
Speciation of metals and metalloids in sediments with LTGC/ICP-MS. / Krupp, Eva Maria; Grumping, R ; Furchtbar, U R R ; Hirner, A V .
In: Fresenius’ Journal of Analytical Chemistry, Vol. 354, No. 5-6, 03.1996, p. 546-549.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Speciation of metals and metalloids in sediments with LTGC/ICP-MS
AU - Krupp, Eva Maria
AU - Grumping, R
AU - Furchtbar, U R R
AU - Hirner, A V
PY - 1996/3
Y1 - 1996/3
N2 - Low temperature GC on-line coupled with an ICP/MS has been used as analytical device to detect organometallic and -metalloid compounds from various sediments of rivers and harbours in West Germany. The different species have been volatilized by derivatization with NaBH4 and cryofocussed in a trap. Different alkylated species of As, Sn and Sb have been identified, while only methylated compounds of the elements Ge, Se, Te, Hg and Bi could be detected.
AB - Low temperature GC on-line coupled with an ICP/MS has been used as analytical device to detect organometallic and -metalloid compounds from various sediments of rivers and harbours in West Germany. The different species have been volatilized by derivatization with NaBH4 and cryofocussed in a trap. Different alkylated species of As, Sn and Sb have been identified, while only methylated compounds of the elements Ge, Se, Te, Hg and Bi could be detected.
KW - BUTYLTIN COMPOUNDS
KW - NATURAL-WATERS
KW - BIOGEOCHEMISTRY
KW - BIOMETHYLATION
KW - ENVIRONMENT
KW - METHYLTIN
KW - ANTIMONY
KW - SELENIUM
KW - TIN
KW - SEA
M3 - Article
VL - 354
SP - 546
EP - 549
JO - Fresenius’ Journal of Analytical Chemistry
JF - Fresenius’ Journal of Analytical Chemistry
SN - 0937-0633
IS - 5-6
ER -